scholarly journals Dielectric Properties of Polyvinyl Alcohol/ Polyacrylamide Blend Film Filled with Carbon Nanospheres

2021 ◽  
Author(s):  
Rashmi Adoor ◽  
Narasimha Ayachit ◽  
Kishor Upadhyaya ◽  
R.F. Bhajantri ◽  
Mallikarjun Anandalli
Keyword(s):  
Dielectric Properties ◽  
Polyvinyl Alcohol ◽  
Composite Films ◽  
Nanocomposite Films ◽  
Carbon Nanospheres ◽  
High Increase ◽  
Sem Images ◽  
Xrd Pattern ◽  
Solution Casting Method ◽  
Energy Storage Efficiency

Abstract Carbon nanosphere / Polyvinyl alcohol/Polyacrylamide (CNS/PVA/PAM) nanocomposite films prepared via a solution casting method were studied for their structural and dielectric properties. Scanning Electron Microscopy (SEM) images of the CNS/PVA/PAM blends reveal the formation of circular islands of CNS and uniform blending with PVA/PAM matrix. XRD pattern shows a higher value with increase in blending ratio of PVA with CNS. The interaction of the dispersed and preformed CNS particles with the PVA/PAM chain was confirmed by the corresponding vibrational signaturing of PVA/PAM through FTIR. The dielectric constant increased from [K = 134, 2K Hz, 305 Kelvin] to [K = 438, 2KHz, 333 Kelvin] and the composite films exhibited a high increase in the energy storage efficiency upto 75% (at 2KHz) in the case of 4%CNS /PVA/PAM 50:50 sample.

Influence of ZnO nanoadditives on the structural characteristics and dielectric properties of PVA

2021 ◽  
Author(s):  
E. Abdeltwab ◽  
A. Atta
Keyword(s):  
Dielectric Properties ◽  
Structural Characteristics ◽  
Composite Films ◽  
Polymer Nanocomposite ◽  
Nanocomposite Films ◽  
Energy Storage Devices ◽  
Scanning Calorimetry ◽  
Super Capacitor ◽  
Sem Images ◽  
Wide Range

In this study, different percentages of semiconducting zinc oxide nanoparticles (ZnONPs) are mixed with polyvinyl alcohol (PVA) to create flexible ZnO/PVA polymer nanocomposite films. The characteristics of the prepared films are investigated using differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. The XRD pattern shows that the ZnO/PVA composite films were successfully synthesized; while the SEM images show that the ZnONPs are homogeneously dispersed in the PVA polymer chain. Moreover, the DSC indicates an improvement in the thermal stability behavior with increased of ZnONPs concentration. The electrical conductivity, dielectric properties, electric modulus behavior, and the energy density efficiency of the pristine PVA and ZnO/PVA composite films are determined using an LCR meter in the frequency range 102–106 Hz. The dielectric constant of the composite film increased from 0.185 for pristine PVA to 1.389 for 9%ZnO/PVA, and the conductivity is improved from [Formula: see text] S/cm to [Formula: see text] S/cm. This work would open the road for utilizing ZnO/PVA flexible nanocomposite films for wide range of applications such as batteries, super-capacitor and energy storage devices.

Enhanced functional properties of biodegradable Polyvinyl alcohol /carboxymethyl cellulose (PVA/CMC) composite films reinforced with L-alanine surface modified CuO nanorods

2021 ◽  
Author(s):  
Yamanappagouda Amaregouda ◽  
Kantharaju Kamanna ◽  
Tilak Gasti ◽  
Vijay Kumbar
Keyword(s):  
Polyvinyl Alcohol ◽  
Carboxymethyl Cellulose ◽  
Food Packaging ◽  
Composite Films ◽  
Nanocomposite Films ◽  
Soil Burial ◽  
High Antibacterial Activity ◽  
Active Food Packaging ◽  
Surface Modified ◽  
Cuo Nanorods

Abstract Herein, we described novel biogenic preparation of the CuO nanorods and its surface modification with L-alanine amino acid accelerated by microwave irradiation. The effect of surface functionalized CuO nanorods on the polyvinyl alcohol/carboxymethyl cellulose film physico-mechanical properties were investigated through various characterization techniques. The tensile strength was improved from 28.58 ± 0.73 MPa to 43.40 ± 0.93 MPa, UV shielding ability and barrier to the water vapors were highly enhanced when PVA/CMC matrices filled with 8 wt% of CuO-L-alanine. In addition, the prepared films exhibited acceptable overall migration limit and readily undergoes soil burial degradation. Nevertheless, CuO-L-alanine incorporated films showed potent antioxidant activity against DPPH radicals and had high antibacterial activity against Staphylococcus aureus and Escherichia coli, and antifungal activity against Candida albicans and Candida tropicalis. Furthermore, the nanocomposite films showed negligible cytotoxic effect on HEK293 and Caco-2 cell lines. In these contexts, the developed nanocomposite films can be implementing as an active food packaging material.

Enhanced dielectric properties of homogeneous Ti3C2Tx MXene@SiO2/polyvinyl alcohol composite films

2020 ◽  
Vol 46 (9) ◽  
pp. 13862-13868 ◽  
Author(s):  
Wei Wan ◽  
Meizhen Tao ◽  
Hailin Cao ◽  
Yuqing Zhao ◽  
Junrong Luo ◽  
...  
Keyword(s):  
Dielectric Properties ◽  
Polyvinyl Alcohol ◽  
Composite Films

Thermally stable polyimide nanocomposite films from electrospun BaTiO3 fibers for high-density energy storage capacitors

RSC Advances ◽  
2015 ◽  
Vol 5 (56) ◽  
pp. 44749-44755 ◽  
Author(s):  
Yun-Hui Wu ◽  
Jun-Wei Zha ◽  
Zhi-Qiang Yao ◽  
Fang Sun ◽  
Robert K. Y. Li ◽  
...  
Keyword(s):  
Energy Storage ◽  
Dielectric Properties ◽  
Dispersion Polymerization ◽  
Composite Films ◽  
High Density ◽  
Nanocomposite Films ◽  
Thermally Stable ◽  
Polyimide Nanocomposite ◽  
Polymerization Method

PI composite films with electrospun BT fibers were fabricated using the in situ dispersion polymerization method. The microstructures, thermal and dielectric properties of the BT fibers and composite films were investigated.

scholarly journals Effect of TiO2 Concentration on Thermal Stability and Dielectric Properties of (PANI)1-x(TiO2)x Nanocomposites

2019 ◽  
Vol 31 (4) ◽  
pp. 855-859
Author(s):  
Ajay Kumar Sharma ◽  
Praveen Kumar Jain ◽  
Rishi Vyas ◽  
Vipin Kumar Jain
Keyword(s):  
Thermal Stability ◽  
Dielectric Properties ◽  
Optoelectronic Devices ◽  
Chemical Properties ◽  
Rutile Phase ◽  
Sem Images ◽  
Xrd Pattern ◽  
The Matrix ◽  
Structural Surface ◽  
And Chemical Properties

The current paper deals with investigation of (PANI)1-x(TiO2)x nanocomposites to explore possible material for optoelectronic devices. To investigate the effect of TiO2 concentration on structural, surface morphology and chemical properties of PANI, samples were characterized by XRD, FTIR, SEM and Raman spectroscopy. The XRD pattern evidence the presence of a blend of anatase and rutile phase of TiO2 within the PANI matrix which shows amorphous nature of the matrix. FTIR and Raman spectra confirm the formation of PANI/TiO2 nanocomposites. SEM images show the appearance of lumps into smooth PANI samples with addition of TiO2 nanoparticles. The thermal and dielectric properties were studied using TGA and Impedance analyzer, respectively. The results showed that the addition of TiO2 improves the thermal stability, which clearly shows its potential application in optoelectronic devices.

scholarly journals Crystallization and Dielectric Properties of MWCNT /Poly(1-Butene) Composite Films by a Solution Casting Method

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 755
Author(s):  
Lingfei Li ◽  
Qiu Sun ◽  
Xiangqun Chen ◽  
Yongjun Xu ◽  
Zhaohua Jiang
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Dielectric Loss ◽  
Breakdown Strength ◽  
Composite Films ◽  
Conductive Filler ◽  
Interfacial Polarization ◽  
Solution Casting ◽  
Casting Method ◽  
Solution Casting Method

In this work, poly(1-butene) (PB-1) composite films with multi-walled carbon nanotubes (MWCNT) were prepared by a solution casting method. The relationship between the dielectric properties and the crystal transformation process of the films was investigated. It was indicated that there were two crystal forms of I and II of PB-1 during the solution crystallization process. With the prolongation of the phase transition time, form II was converted into form I. The addition of the conductive filler (MWCNT) accelerated the rate of phase transformation and changed the nucleation mode of PB-1. The presence of crystal form I in the system increased the breakdown strength and the dielectric constant of the films and reduced the dielectric loss, with better stability. In addition, the dielectric constant and the dielectric loss of the MWCNT/PB-1 composite films increased with the addition of MWCNT, due to the interfacial polarization between MWCNT and PB-1 matrix. When the mass fraction of the MWCNT was 1.0%, the composite film had a dielectric constant of 43.9 at 25 °C and 103 Hz, which was 20 times that of the original film.

Effect of dopant and DC bias potential on dielectric properties of polyvinyl alcohol (PVA)/PbTiO3 - composite films

2011 ◽  
Vol 11 (6) ◽  
pp. 1322-1325 ◽  
Author(s):  
Girish M. Joshi ◽  
S.M. Khatake ◽  
S. Kaleemulla ◽  
N. Madhusudhana Rao ◽  
Teresa Cuberes
Keyword(s):  
Dielectric Properties ◽  
Polyvinyl Alcohol ◽  
Composite Films ◽  
Bias Potential ◽  
Dc Bias

Dielectric Properties of CCTO/PVDF Composite Films

2013 ◽  
Vol 816-817 ◽  
pp. 276-279 ◽  
Author(s):  
Fang Fang Wang ◽  
Ya Jun Wang ◽  
Zhi Bo Ren
Keyword(s):  
Dielectric Constant ◽  
Dielectric Properties ◽  
Composite Films ◽  
Solution Casting ◽  
Casting Method ◽  
Impedance Analyzer ◽  
Composite Models ◽  
Solution Casting Method ◽  
Pvdf Matrix ◽  
Ccto Powder

To meet the requirement of microelectronic industry, ceramic/polymer composite films made of CaCu3Ti4O12(CCTO) powder as filler and PVDF copolymer as matrix were prepared by solution casting method. The dielectric properties (DP) and morphology of the films were studied by impedance analyzer and scanning electron microscope (SEM) respectively. The dielectric constant could reach 23.96 and loss 0.1082 when mass fraction of CCTO is 50% at 100 Hz. SEM results show that CCTO particles dispersed well in the PVDF matrix. At last, three composite models were used to predict the dielectric constant of the composite films and it is proved that Yamada model fits the experimental data well.

Preparation and Dielectric Property of Ag/PVDF Composite Film

2014 ◽  
Vol 989-994 ◽  
pp. 242-245 ◽  
Author(s):  
Ya Jun Wang ◽  
Jian Wen Zhai ◽  
Fang Fang Wang ◽  
Chang Gen Feng
Keyword(s):  
Dielectric Properties ◽  
Dielectric Property ◽  
Composite Film ◽  
Volume Fraction ◽  
Composite Films ◽  
Dielectric Constants ◽  
Pvdf Film ◽  
Conductive Particle ◽  
Sem Images ◽  
Nanosilver Particles

Conductive particle fillers could improve the dielectric properties of the polymer matrix. By solvent casting method, different volume fraction of nanosilver particles were added into the PVDF film to prepare Ag/PVDF composite film so as to increase the dielectric properties of the materials. SEM was used to analyze the microstructure of the films. SEM images show that nanoAg filler particles were uniformly distributed throughout the whole matrix of the composite films. Dielectric property tests show that with the increase of nanoAg content, the dielectric constants of the composites increase first and decrease later while the dielectric losses decrease first and increase later. In the case of the optimal 17vol% Ag content, the dielectric constant of the composite film is the highest (14.5 at 100 Hz) with lower dielectric loss, and the energy storage density is relatively high (0.340 J·cm−3).

Sign in / Sign up

Export Citation Format

Share Document