scholarly journals Investigations on the fouling characteristic of humic acid and alginate sodium in capacitive deionization

Author(s):  
Huizhong Zhang ◽  
Jiayu Tian ◽  
Xiujuan Hao ◽  
Dongmei Liu ◽  
Fuyi Cui

Abstract Capacitive deionization (CDI) has been investigated for brackish water desalination, selective removal of ions, and water softening. We used humic acid (HA) and alginate sodium (SA) to simulate different kinds of natural organic matter to investigate the fouling phenomena during CDI operation. Adsorption amount and energy efficiency were studied. Results showed that both SA and HA could decrease the removal of NaCl during CDI operation. There existed a slight decrease of energy consumption in SA solutions which was opposite to that in HA solutions. HA can compete with ions adsorbed by electrodes and attach to electrodes adhesively, resulting in co-ion repulsion. SA is not sensitive to electrical field and its fouling is not obvious. The amount of adsorbed Mg2+ would increase from 0.927 mg/g to 1.508 mg/g in ten cycles' operation and the increment of Ca2+ was from 1.885 mg/g to 2.878 mg/g in SA solutions. This increase of adsorption was due to the complexation between SA and cations. Simultaneously, energy consumption was decreased. In HA solutions, energy consumption of Mg2+ and Ca2+ adsorption increased. In ten cycles' operations, both HA and SA could reduce the efficiency of CDI operation. The types of organic substances are important factors in fouling of CDI electrodes.

Membranes ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 231 ◽  
Author(s):  
Xin Zhang ◽  
Danny Reible

Water softening is desirable to reduce scaling in water infrastructure and to meet industrial water quality needs and consumer preferences. Membrane capacitive deionization (MCDI) can preferentially adsorb divalent ions including calcium and magnesium and thus may be an attractive water softening technology. In this work, a process model incorporating ion exclusion effects was applied to investigate water softening performance including ion selectivity, ion removal efficiency and energy consumption in a constant voltage (CV) mode MCDI. Trade-offs between the simulated Ca2+ selectivity and Ca2+ removal efficiency under varying applied voltage and varying initial concentration ratio of Na+ to Ca2+ were observed. A cut-off CV mode, which was operated to maximize Ca2+ removal efficiency per cycle, was found to lead to a specific energy consumption (SEC) of 0.061 kWh/mole removed Ca2+ for partially softening industrial water and 0.077 kWh/m3 removed Ca2+ for slightly softening tap water at a water recovery of 0.5. This is an order of magnitude less than reported values for other softening techniques. MCDI should be explored more fully as an energy efficient means of water softening.


2019 ◽  
Vol 7 (23) ◽  
pp. 18992-19004 ◽  
Author(s):  
Julio J. Lado ◽  
Rafael L. Zornitta ◽  
Inés Vázquez Rodríguez ◽  
Kamila Malverdi Barcelos ◽  
Luís A. M. Ruotolo

2016 ◽  
Vol 868 ◽  
pp. 43-49 ◽  
Author(s):  
Hai Bo Li ◽  
Sen Liang ◽  
Mang Mang Gao ◽  
Chang Yeoul Kim

Capacitive deionization (CDI) is a water desalination technique in which salt ions are removed from brackish water by flowing through a spacer channel with porous electrodes on each side. Upon applying a small voltage difference between the two electrodes, cations move to and are accumulated in electrostatic double layers inside the negatively charged cathode and the anions are removed by the positively charged anode. Therefore, one of the advanced merits of CDI is the low driven energy by compared to other desalination technologies. Inspired this, we have performed the calculation on energy consumption of activated carbon based CDI in different operation conditions. The results show that the energy consumptions are significantly related to cell voltage as well as solution concentration. Furthermore, the round trip efficiency as a vital indication in terms of energy consumption have been introduced and discussed as well.


Author(s):  
Sareh Vafakhah ◽  
Mohsen Saeedikhani ◽  
Shaozhuan Huang ◽  
Zhi Yi Leong ◽  
Ye Wang ◽  
...  

Owing to the favorable energy efficiency and environmental compatibility, capacitive deionization (CDI) has been greatly developed as a potential technology to overcome the ever-growing global water shortage. Herein, an effective...


2010 ◽  
Vol 59 (1) ◽  
pp. 99-108 ◽  
Author(s):  
M. Takács ◽  
Gy. Füleky

The Hot Water Percolation (HWP) technique for preparing soil extracts has several advantages: it is easily carried out, fast, and several parameters can be measured from the same solution. The object of this study was to examine the possible use of HWP extracts for the characterization of soil organic matter. The HPLC-SEC chromatograms, UV-VIS and fluorescence properties of the HWP extracts were studied and the results were compared with those of the International Humic Substances Society (IHSS) Soil Humic Acid (HA), IHSS Soil Fulvic Acid (FA) and IHSS Suwannee Natural Organic Matter (NOM) standards as well as their HA counterparts isolated by traditional extraction methods from the original soil samples. The DOM of the HWP solution is probably a mixture of organic materials, which have some characteristics similar to the Soil FA fractions and NOM. The HWP extracted organic material can be studied and characterized using simple techniques, like UV-VIS and fluorescence spectroscopy.


1996 ◽  
Vol 34 (9) ◽  
pp. 157-164 ◽  
Author(s):  
Kim C.-H. ◽  
M. Hosomi ◽  
A. Murakami ◽  
M. Okada

Effects of clay on fouling due to organic substances and clay were evaluated by model fouling materials and kaolin. Model fouling materials selected were protein, polysaccharide, fulvic acid, humic acid and algogenic matter (EOM:ectracellular organic matter, microbial decomposition products) and kaolin was selected as the clay material. Polysulfone membrane (MWCO(Molecular Weight Cut-Off) 10,000, 50,000 and 200,000) was used as an ultrafiltration membrane. In particular, the flux measurement of solutions containing algogenic matter used an ultrafiltration membrane of MWCO 50,000. The flux of protein and polysaccharide with coexistence of kaolin increased in the case of the ratio of MW/MWCO being greater than one, but did not increase in the case of the MW/MWCO ratio being below one. In contrast, the flux of fulvic acid and humic acid with coextence of kaolin decreased regardless of the ratio of MW/MWCO. The addition of dispersion agent and coagulant in the organic substances and kaolin mixture solution changed the size distribution of kaolin, and resulted in a change of the flux. EOM and microbial decomposition products decreased with the increase of the fraction of organic matter having molecular weight more than MWCO of membrane. The flux of the algogenic organic matter with coexistence of kaolin decreased with the increase of the amount of kaolin. It was suggested that the decline of the flux with coexistence of kaolin was due to the change of the resistance of the kaolin cake layer corresponding to the change in kaolin size distribution with charge.


2020 ◽  
Vol 14 ◽  
Author(s):  
M. Sivaram ◽  
V. Porkodi ◽  
Amin Salih Mohammed ◽  
S. Anbu Karuppusamy

Background: With the advent of IoT, the deployment of batteries with a limited lifetime in remote areas is a major concern. In certain conditions, the network lifetime gets restricted due to limited battery constraints. Subsequently, the collaborative approaches for key facilities help to reduce the constraint demands of the current security protocols. Aim: This work covers and combines a wide range of concepts linked by IoT based on security and energy efficiency. Specifically, this study examines the WSN energy efficiency problem in IoT and security for the management of threats in IoT through collaborative approaches and finally outlines the future. The concept of energy-efficient key protocols which clearly cover heterogeneous IoT communications among peers with different resources has been developed. Because of the low capacity of sensor nodes, energy efficiency in WSNs has been an important concern. Methods: Hence, in this paper, we present an algorithm for Artificial Bee Colony (ABC) which reviews security and energy consumption to discuss their constraints in the IoT scenarios. Results: The results of a detailed experimental assessment are analyzed in terms of communication cost, energy consumption and security, which prove the relevance of a proposed ABC approach and a key establishment. Conclusion: The validation of DTLS-ABC consists of designing an inter-node cooperation trust model for the creation of a trusted community of elements that are mutually supportive. Initial attempts to design the key methods for management are appropriate individual IoT devices. This gives the system designers, an option that considers the question of scalability.


2015 ◽  
Vol 8 (1) ◽  
pp. 206-210 ◽  
Author(s):  
Yu Junyang ◽  
Hu Zhigang ◽  
Han Yuanyuan

Current consumption of cloud computing has attracted more and more attention of scholars. The research on Hadoop as a cloud platform and its energy consumption has also received considerable attention from scholars. This paper presents a method to measure the energy consumption of jobs that run on Hadoop, and this method is used to measure the effectiveness of the implementation of periodic tasks on the platform of Hadoop. Combining with the current mainstream of energy estimate formula to conduct further analysis, this paper has reached a conclusion as how to reduce energy consumption of Hadoop by adjusting the split size or using appropriate size of workers (servers). Finally, experiments show the effectiveness of these methods as being energy-saving strategies and verify the feasibility of the methods for the measurement of periodic tasks at the same time.


Sign in / Sign up

Export Citation Format

Share Document