Shear Strength and Drainage Characteristics of Elastomeric Polyurethane Treated Coal-Fouled Ballast

The shear behavior and drainage characteristics of coal-fouled ballast when treated with elastomeric polyurethane are assessed by means of large-scale direct shear and permeability tests. The results from direct shear tests confirmed that the shear strength of both stabilized and unstabilized coal-fouled ballast was highly influenced by the extent of fouling (VCI: void contamination index). The performance index (PI) of elastomer-stabilized coal-fouled ballast (ESFB), determined as the fraction of shear strength of fouled ballast to the shear strength of fresh and unstabilized ballast, lies in the range of 1.23 to 0.84. Moreover, the performance of ESFB having VCI ≥30% was found to be either similar to or poorer than that of clean ballast without any treatment, thus indicating that the elastomer treatment may be provided only to ballast with VCI ≤30%. The results from constant head permeability tests indicate that the hydraulic conductivity of ballast ( k) is highly influenced by the presence of fouling materials but is only slightly reduced as a result of the elastomer stabilization. The k of ballast decreased from 43 to 0.18 mm/s as the VCI increased from 0 to 75%. For VCI ≥ 45% the k of ballast was found to be lower than that recommended for sub-ballast. On the other hand, the k of ballast reduced slightly from 43 to 37 mm/s because of the elastomer stabilization. Furthermore, an empirical relationship is established between k and e to determine the k of both stabilized and unstabilized fouled ballast.

Independent Variation of Reynolds Number, Wall Shear Stress and Flow Velocity for Cleaning Experiments: A Geometrically Flexible Parallel Plate Flow Cell

For a long time, determining the factors influencing the cleaning of technical surfaces in the food and beverage industry has been of significant interest. In this study, an innovative test setup with a newly designed parallel plate flow cell was implemented to assess the cleaning of soluble molecular fouling materials, which allows for the independent variation of flow parameters, such as the Reynolds number, velocity, and wall shear stress. The test setup used fluorescence spectroscopy; it was found to produce reliable measurements of cleaning, and the results were confirmed with the help of another fluorescent tracer. A comparison of cleaning times for both equipment revealed that the cleaning times tend to have a geometrically independent power-law relationship with the wall shear stress and velocity, and they were used to directly correlate the cleaning times of the used soluble fouling material. However, the Reynolds number showed a geometric dependence on cleaning times. Nevertheless, on dividing the Reynolds number with respective channel characteristic lengths, geometric independence was observed, and, therefore, a correlation was obtained. We also suggest that complex fouling materials should still be investigated to elucidate their cleaning mechanisms better and test for parameter influences on complex cleaning mechanisms.

Controlling Experimental Parameters to Improve Characterization of Biomaterial Fouling

Uncontrolled protein adsorption and cell binding to biomaterial surfaces may lead to degradation, implant failure, infection, and deleterious inflammatory and immune responses. The accurate characterization of biofouling is therefore crucial for the optimization of biomaterials and devices that interface with complex biological environments composed of macromolecules, fluids, and cells. Currently, a diverse array of experimental conditions and characterization techniques are utilized, making it difficult to compare reported fouling values between similar or different biomaterials. This review aims to help scientists and engineers appreciate current limitations and conduct fouling experiments to facilitate the comparison of reported values and expedite the development of low-fouling materials. Recent advancements in the understanding of protein–interface interactions and fouling variability due to experiment conditions will be highlighted to discuss protein adsorption and cell adhesion and activation on biomaterial surfaces.

Gill fouling in the economically important freshwater shrimp Macrobrachium rosenbergii (De Man, 1879) (Caridea: Palaemonidae)

The giant freshwater prawn, Macrobrachium rosenbergii (De Man, 1879), lives in freshwater environments of the Indo-West Pacific region and is commonly farmed. Males transition into three male morphotypes that differ in behavior and morphology. Small-clawed males (SM) molt into orange-clawed males (OC) that molt into the harvested and largest blue-clawed males (BC). Grooming behaviors can remove fouling such as sediment particles, bacteria, and other organisms, all of which are commonly found in the natural environment as well as in aquaculture environments. Because individuals of this species groom their bodies frequently, especially the gills, the objective of the study was to observe gills of male morphotypes and females and evaluate their fouling levels and types using light microscopy, bacterial counts, and scanning electron microscopy. The male morphotypes and females are fouled differently, with grooming behaviors being effective in removing sedimentary and bacterial fouling from the gills. Although their relative efficiencies in removing fouling materials from the gills were not statistically significant, OC and BC exhibited contrasting gill fouling patterns with higher bacterial than sedimentary fouling in the former but the opposite in the latter. This difference may be attributed to differential levels of fouling related to variation in behavioral priorities, grooming behaviors, and morphology. Control of bacterial and sedimentary fouling in aquaculture could have large implications on the quality and survival of harvested individuals.

TrimethylamineN-oxide–derived zwitterionic polymers: A new class of ultralow fouling bioinspired materials

Materials that resist nonspecific protein adsorption are needed for many applications. However, few are able to achieve ultralow fouling in complex biological milieu. Zwitterionic polymers emerge as a class of highly effective ultralow fouling materials due to their superhydrophilicity, outperforming other hydrophilic materials such as poly(ethylene glycol). Unfortunately, there are only three major classes of zwitterionic materials based on poly(phosphorylcholine), poly(sulfobetaine), and poly(carboxybetaine) currently available. Inspired by trimethylamineN-oxide (TMAO), a zwitterionic osmolyte and the most effective protein stabilizer, we here report TMAO-derived zwitterionic polymers (PTMAO) as a new class of ultralow fouling biomaterials. The nonfouling properties of PTMAO were demonstrated under highly challenging conditions. The mechanism accounting for the extraordinary hydration of PTMAO was elucidated by molecular dynamics simulations. The discovery of PTMAO polymers demonstrates the power of molecular understanding in the design of new biomimetic materials and provides the biomaterials community with another class of nonfouling zwitterionic materials.