Competitive mechanism of ammonia, iron and manganese for dissolved oxygen using pilot-scale biofilter at different dissolved oxygen concentrations

2015 ◽  
Vol 16 (3) ◽  
pp. 766-774 ◽  
Author(s):  
Qingfeng Cheng

In this study, the competitive mechanism of ammonia, iron and manganese for dissolved oxygen (DO) in a biofilter was investigated, and a new start-up method of a biofilter for ammonia, iron and manganese removal was approved, which can effectively shorten the start-up period from 3–4 months to 51 days. The results demonstrated that when DO was sufficient (about 8 mg · L−1), ammonia, iron and manganese could be completely removed. When DO decreased from 6.5 to 4 mg · L−1, the concentration of ammonia in the effluent increased accordingly, though iron and manganese were removed efficiently. When DO was as low as 3 mg · L−1, only iron was removed, whereas most of the ammonia and manganese still existed in the effluent. In addition, the oxidizing rates of the pollutants were not affected significantly with DO decrease. Turbidity removal in the biofilter was also investigated, and the results demonstrated that the turbidity decreased to less than 0.5 NTU at 0.4 m depth of the filter.

Author(s):  
Yingming Guo ◽  
Ben Ma ◽  
Jianxiong Huang ◽  
Jing Yang ◽  
Ruifeng Zhang

Abstract The iron and manganese oxide filter film (MeOx) were used to research the simultaneous removal of bisphenol A (BPA), manganese (Mn2+) and ammonium (NH4+) in a pilot-scale filter system. We found that 0.52 mg/L of BPA could be removed while consuming 5.44 mg/L of dissolved oxygen (DO). Since the oxidation process of NH4+ and BPA both consume the DO in water, the presence of NH4+ can hinder the removal of BPA. The presence of Mn2+ in water had a synergy effect on the BPA removal. The filter film was characterized by SEM, XRD and XPS. Some substances were generated to block the pores of the oxide film, and a small amount of film was found to crack and fall off. The elemental composition of C and O were both increased by about 9%, the composition of Mn was decreased from 63.48% to 44.55%, and the reduced manganese substance might affect the activity of the oxide film. The main chemical forms of MeOx are Mn6O12·3H2O, MnFe2O4 or Mn3O4. The decrease in the removal efficiency of BPA was mainly due to the C-containing intermediate [−CH2C − H(OH)]n covering the surface of the oxide film and blocking the pore size of the film.


2010 ◽  
Vol 113-116 ◽  
pp. 1316-1319 ◽  
Author(s):  
Hui Ping Zeng ◽  
Dong Li ◽  
Jie Zhang

“aged” biofilter media was adopted as the inoculum to accelerate the maturation of biofilter for iron and manganese removal in the start-up of filter column. morphology of “aged” biofilter media and new quartz sand was observed with SEM. The results indicate that the “aged” biofilter media coated by a large quantity of bacteria which reduces the start-up time to 30 daysand affords strong Mn-removal efficiency at the beginning of the process. This method probably can be used for the start-up of new filters when there are well-established biofilters around.


Author(s):  
Huiping Zeng ◽  
Can Yin ◽  
Jie Zhang ◽  
Dong Li

In recent years, biological purification technology has been widely developed in the process of iron and manganese removal from groundwater. The cultivation and maturation of the biological filter layer are key for biological iron and manganese removal processes. The time needed for maturation varies significantly with the water quality, filter and filter media conditions and operation parameters; sometimes it takes only one or two months, sometime more than half a year. In this paper, the feasibility of adopting an intermittent operation for the cultivation of biofilter was investigated with productive filters in a groundwater treatment plant, and the comparative test of the filter column was conducted. The results showed that the intermittent operation had little effect on the cultivation of the biofilter because dissolved oxygen would be gradually exhausted during the filter-suspension process, making the filter layer anaerobic, thus possibly inhibiting the growth and reproduction of IMOB (Iron and Manganese Oxidizing Bacteria). At the same time, the test shows that when the mature biological filter needs the suspension operation, the emptying method should be considered to avoid the destruction of the biological layer.


2017 ◽  
Vol 66 (3) ◽  
pp. 157-165 ◽  
Author(s):  
Qingfeng Cheng ◽  
Lichao Nengzi ◽  
Linlin Bao ◽  
Yijing Wang ◽  
Jianxing Yang ◽  
...  

1988 ◽  
Vol 23 (4) ◽  
pp. 568-577
Author(s):  
Harold S. Bailey

Abstract The water quality of the upper 110 kilometres of the St. Croix River is considered to be pristine. A major industrial discharge renders the lower 14 kilometres of the river a water quality limited segment. Prior to 1970 the Georgia-Pacific Pulp and Paper Mill at Woodland, Maine, discharged untreated effluent directly into the river causing dissolved oxygen concentrations to drop well below 5 mg/L, the objective chosen in the interest of restoring endemic fish populations. Since 1972, the Mill has installed primary and secondary treatment, regulated river discharge rate and effluent composition which has greatly improved the summer dissolved oxygen regime. By 1980, dissolved oxygen concentrations were generally above 5.0 mg/L and restocking the river with Atlantic Salmon (Salmo salar) was initiated.


1992 ◽  
Vol 26 (7-8) ◽  
pp. 1769-1778 ◽  
Author(s):  
S.-I. Lee ◽  
B. Koopman ◽  
E. P. Lincoln

Combined chemical flocculation and autoflotation were examined using pilot scale process with chitosan and alum as flocculants. Positive correlation was observed between dissolved oxygen concentration and rise rate. Rise rate depended entirely on the autoflotation parameters: mixing intensity, retention time, and flocculant contact time. Also, rise rate was influenced by the type of flocculant used. The maximum rise rate with alum was observed to be 70 m/h, whereas that with chitosan was approximately 420 m/h. The efficiency of the flocculation-autoflotation process was superior to that of the flocculation-sedimentation process.


2021 ◽  
Vol 105 (3) ◽  
pp. 1041-1050
Author(s):  
Luqiang Jia ◽  
Teng Li ◽  
Yixuan Wu ◽  
Chunsen Wu ◽  
Huaxiang Li ◽  
...  

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