scholarly journals The simultaneous removal of bisphenol A, manganese and ammonium from groundwater by MeOx: The role of chemical catalytic oxidation for bisphenol A

2021 ◽  
Author(s):  
Yingming Guo ◽  
Ben Ma ◽  
Jianxiong Huang ◽  
Jing Yang ◽  
Ruifeng Zhang
Keyword(s):  
Oxide Film ◽  
Bisphenol A ◽  
Dissolved Oxygen ◽  
Oxidation Process ◽  
Pilot Scale ◽  
Simultaneous Removal ◽  
Chemical Forms ◽  
Synergy Effect ◽  
Iron And Manganese

Abstract The iron and manganese oxide filter film (MeOx) were used to research the simultaneous removal of bisphenol A (BPA), manganese (Mn2+) and ammonium (NH4+) in a pilot-scale filter system. We found that 0.52 mg/L of BPA could be removed while consuming 5.44 mg/L of dissolved oxygen (DO). Since the oxidation process of NH4+ and BPA both consume the DO in water, the presence of NH4+ can hinder the removal of BPA. The presence of Mn2+ in water had a synergy effect on the BPA removal. The filter film was characterized by SEM, XRD and XPS. Some substances were generated to block the pores of the oxide film, and a small amount of film was found to crack and fall off. The elemental composition of C and O were both increased by about 9%, the composition of Mn was decreased from 63.48% to 44.55%, and the reduced manganese substance might affect the activity of the oxide film. The main chemical forms of MeOx are Mn6O12·3H2O, MnFe2O4 or Mn3O4. The decrease in the removal efficiency of BPA was mainly due to the C-containing intermediate [−CH2C − H(OH)]n covering the surface of the oxide film and blocking the pore size of the film.

Competitive mechanism of ammonia, iron and manganese for dissolved oxygen using pilot-scale biofilter at different dissolved oxygen concentrations

2015 ◽  
Vol 16 (3) ◽  
pp. 766-774 ◽  
Author(s):  
Qingfeng Cheng
Keyword(s):  
Dissolved Oxygen ◽  
Pilot Scale ◽  
Turbidity Removal ◽  
Manganese Removal ◽  
Start Up ◽  
Competitive Mechanism ◽  
Iron And Manganese ◽  
Oxygen Concentrations

In this study, the competitive mechanism of ammonia, iron and manganese for dissolved oxygen (DO) in a biofilter was investigated, and a new start-up method of a biofilter for ammonia, iron and manganese removal was approved, which can effectively shorten the start-up period from 3–4 months to 51 days. The results demonstrated that when DO was sufficient (about 8 mg · L−1), ammonia, iron and manganese could be completely removed. When DO decreased from 6.5 to 4 mg · L−1, the concentration of ammonia in the effluent increased accordingly, though iron and manganese were removed efficiently. When DO was as low as 3 mg · L−1, only iron was removed, whereas most of the ammonia and manganese still existed in the effluent. In addition, the oxidizing rates of the pollutants were not affected significantly with DO decrease. Turbidity removal in the biofilter was also investigated, and the results demonstrated that the turbidity decreased to less than 0.5 NTU at 0.4 m depth of the filter.

scholarly journals Solar-driven free chlorine advanced oxidation process for simultaneous removal of microcontaminants and microorganisms in natural water at pilot-scale

Chemosphere ◽  
2021 ◽  
pp. 132493
Author(s):  
Isaac Sánchez-Montes ◽  
Irene Salmerón ◽  
José M. Aquino ◽  
María Inmaculada Polo-López ◽  
Sixto Malato ◽  
...  
Keyword(s):  
Natural Water ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Advanced Oxidation ◽  
Pilot Scale ◽  
Free Chlorine ◽  
Simultaneous Removal

Titanium and zirconium oxidation under argon irradiation in the low MeV range

2013 ◽  
Vol 1514 ◽  
pp. 81-85 ◽  
Author(s):  
Dominique Gorse-Pomonti ◽  
Ngoc-Long Do ◽  
Nicolas Bérerd ◽  
Nathalie Moncoffre ◽  
Gianguido Baldinozzi
Keyword(s):  
Oxide Film ◽  
Oxidation Process ◽  
Stopping Power ◽  
Projectile Energy ◽  
Oxidation Peak ◽  
Irradiation Effects ◽  
Nuclear Stopping ◽  
Dry Air ◽  
Argon Ions

ABSTRACTWe studied the irradiation effects on Ti and Zr surfaces in slightly oxidizing environment (rarefied dry air, 500°C) using multi-charged argon ions in the low MeV range (1 – 9 MeV) to the aim of determining the respective role of the electronic and nuclear stopping power in the operating oxidation process under irradiation. We have shown that ballistic collisions contribute significantly to the enhanced Ti and Zr oxidation under MeV argon bombardment. We have also shown that the projectile energy plays a significant role in the overall process.A significant oxide film thickening is visible on titanium under irradiation, taking the form of a well-defined oxidation peak between 1 and 4 MeV, as a result of the Nuclear Backscattering Spectroscopy and Spectroscopic Ellipsometry studies.A significant oxide film thickening is also visible on zirconium under same irradiation conditions, at 4 and 9 MeV, as a result of the NBS study. Work is in progress in order to determine how the modified oxidation process depends in this case on the projectile energy.

Simultaneous removal of bisphenol A and phosphate in zero-valent iron activated persulfate oxidation process

2016 ◽  
Vol 303 ◽  
pp. 458-466 ◽  
Author(s):  
Li Zhao ◽  
Yuefei Ji ◽  
Deyang Kong ◽  
Junhe Lu ◽  
Quansuo Zhou ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Oxidation Process ◽  
Zero Valent Iron ◽  
Simultaneous Removal ◽  
Persulfate Oxidation ◽  
Activated Persulfate

Effect of Physicochemical Variables on Algal Autoflotation

1992 ◽  
Vol 26 (7-8) ◽  
pp. 1769-1778 ◽  
Author(s):  
S.-I. Lee ◽  
B. Koopman ◽  
E. P. Lincoln
Keyword(s):  
Dissolved Oxygen ◽  
Oxygen Concentration ◽  
Retention Time ◽  
Contact Time ◽  
Pilot Scale ◽  
Dissolved Oxygen Concentration ◽  
Physicochemical Variables ◽  
Rise Rate ◽  
Mixing Intensity ◽  
Maximum Rise

Combined chemical flocculation and autoflotation were examined using pilot scale process with chitosan and alum as flocculants. Positive correlation was observed between dissolved oxygen concentration and rise rate. Rise rate depended entirely on the autoflotation parameters: mixing intensity, retention time, and flocculant contact time. Also, rise rate was influenced by the type of flocculant used. The maximum rise rate with alum was observed to be 70 m/h, whereas that with chitosan was approximately 420 m/h. The efficiency of the flocculation-autoflotation process was superior to that of the flocculation-sedimentation process.

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