Partial oxidation of reactive dyestuffs and synthetic textile dye-bath by the O3 and O3/H2O2 processes

2001 ◽  
Vol 43 (2) ◽  
pp. 221-228 ◽  
Author(s):  
I. A. Balcioğlu ◽  
İ. Arslan
Keyword(s):  
Treatment Time ◽  
Textile Wastewater ◽  
Synthetic Wastewater ◽  
Textile Dye ◽  
Treatment Efficiency ◽  
Reactive Dyeing ◽  
Oxidation Rates ◽  
Ph Values ◽  
Dyeing Process ◽  
H2o2 Oxidation

Ozonation and O3/H2O2 oxidation of reactive dyestuffs and simulated textile dye-bath were investigated. Effects of reaction pH, initial dye concentration, H2O2 concentration and assisting chemicals on treatment efficiency were examined. We found considerable improvement in COD and colour removal rates at pH=11, that was almost the actual pH of the prepared textile wastewater, whereas in particular increasing the initial dyestuff concentration had an adverse effect upon oxidation rates. Removal of colour, COD and TOC were found to be fairly sensitive to the introduction of soda that is frequently applied as an auxiliary chemical during the reactive dyeing process. The addition of H2O2 had negligible effect on COD removal efficiency and decolorization rate compared to ozonation alone at different pH values. Accordingly it can be inferred that the theoretically expected effect of OH· radical scavengers (e.g. carbonate, chloride) present in the synthetic dye-bath as well as introduced radical formationpromoters (e.g. H2O22, OH–) were probably hidden due to the complexity of the synthetic wastewater matrix. Biodegradability of the ozonated dye-bath was accelerated by a factor of three corresponding to a 233% relative enhancement. The inhibition of the oxygen uptake rate decreased from 91% to 75% within only 5 min treatment time.

scholarly journals Comparing the Influence of the Drop Fill and Overflow Rinsing On the Reactive Dyeing Process in a Textile Dye House

2018 ◽  
Vol 460 ◽  
pp. 012023
Author(s):  
F. Filiz Yıldırım ◽  
Esra Gelgec ◽  
Saban Yumru ◽  
Sema Palamutcu ◽  
Mustafa Çörekcioğlu
Keyword(s):  
Textile Dye ◽  
Reactive Dyeing ◽  
Dyeing Process

scholarly journals Investigation into the color stripping of the pigment printed cotton fabric using the ozone assisted process: A study on the decolorization and characterization

2021 ◽  
Vol 16 ◽  
pp. 155892502199275
Author(s):  
Ajinkya Powar ◽  
Anne Perwuelz ◽  
Nemeshwaree Behary ◽  
Le vinh Hoang ◽  
Thierry Aussenac ◽  
...  
Keyword(s):  
Cotton Fabric ◽  
Photoelectron Spectroscopy ◽  
Treatment Time ◽  
Pilot Scale ◽  
Chemical Recycling ◽  
X Ray ◽  
Cellulosic Fibers ◽  
Dyeing Process ◽  
Cellulosic Textiles ◽  
Ozonation Process

Color stripping is one of the most convenient ways to rectify the various shade faults occurred during printing or dyeing process of textiles. But, the conventional chemical assisted process poses serious risk of the environmental pollution. Secondly, the chemical recycling of the cellulosic fibers may be disrupted due to the presence of the impurities like colorants, finishes, and the additives in the discarded textiles. So, there is a need to study ways to remove such impurities from the discarded cellulosic textiles in a sustainable manner. This work examines the decolorization of the pigment prints on cellulosic fabrics at pilot scale using an ozone-assisted process. The effect of varying pH, ozone concentration and the treatment time on the decolorization of the pigment prints was optimized using the response surface methodology technique. The effects of ozonation process parameters on the mechanical properties of cellulosic cotton fabric were measured. Decolorization of pigment printed samples was studied with respect to the surface effects by a scanning electron microscopy (SEM), and the chemical removal effects of ozonation treatment were studied using X-ray photoelectron spectroscopy. The possible mechanism regarding the action of ozone for the decolorization is discussed.

A constructed wetland model for synthetic reactive dye wastewater treatment by narrow-leaved cattails (Typha angustifolia Linn.)

2009 ◽  
Vol 60 (6) ◽  
pp. 1565-1574 ◽  
Author(s):  
S. Nilratnisakorn ◽  
P. Thiravetyan ◽  
W. Nakbanpote
Keyword(s):  
Wastewater Treatment ◽  
Constructed Wetland ◽  
Cell Structure ◽  
Salt Content ◽  
Textile Wastewater ◽  
Reactive Dye ◽  
Wastewater Management ◽  
Textile Dye ◽  
Dye Wastewater ◽  
Term Operation

Textile wastewater is contaminated by reactive dye causing unattractive levels of wastewater color, high pH and high salt content when discharged into public water systems. Decolorization of textile wastewater by plant, phytoremediation, is an alternative, sustainable method which is suitable for long term operation. Narrow-leaved cattails are one species of wetland plant with efficiency for decolorizing and remediating textile wastewater. In addition, chemical oxygen demand (COD) can be lowered and dye residue can be removed. The plant also showed a good salt tolerance even after being exposed to a salt solution for 15 days. The narrow-leaved cattails were set up in a constructed wetland model with a vertical flow system operating from bottom to top for synthetic reactive dye wastewater (SRDW) removal. Narrow-leaved cattails could achieve the removal of SRDW at approximately 0.8 gSRDW m−2 day−1. Decolorization of SRDW by this plant was approximately 60%. The advantage of this method is that it is suitable for textile wastewater management and improvement of wetland. These plants could lower COD, remove dye, sodium and total dissolved solids (TDS) whereas other biological and chemical methods could not remove TDS and dye in the same time. These results suggested that the spongy cell structure of this plant has the ability to absorb large amounts of water and nutrients. Physico-chemical analysis revealed increasing amounts of sulfur, silicon, iron and calcium in the plant leafs and roots after exposure to wastewater. Proteins or amide groups in the plant might help in textile dye removal. Regarding decolorization, this plant accumulates dye in the intercellular space and still grows in this SRDW condition. Hence, it can be noted here that narrow-leaved cattails are efficient for textile dye wastewater treatment.

The effect of the textile industry dye bath additive EDTMPA on colour removal characteristics by ozone oxidation

2007 ◽  
Vol 55 (10) ◽  
pp. 145-153 ◽  
Author(s):  
T. Ölmez ◽  
I. Kabdaşlı ◽  
O. Tünay
Keyword(s):  
Organic Matter ◽  
Textile Industry ◽  
Reaction Rates ◽  
Textile Dye ◽  
Pseudo First Order Reaction ◽  
Ozone Oxidation ◽  
Reactive Dyeing ◽  
First Order ◽  
Organic Matter Oxidation ◽  
Pseudo First Order

In this study, the effects of the phosphonic acid based sequestering agent EDTMPA used in the textile dye baths on colour and organic matter removal by ozone oxidation was experimentally investigated. Procion Navy HEXL dyestuff that has been commonly used for the reactive dyeing of cellulose fibers was selected as the model component. The organic matter oxidation by ozone was determined to obey the pseudo-first order kinetics as they are treated singly or in combination. COD removal rates obtained from pseudo-first order reaction kinetics showed that oxidation of Navy HEXL alone (0.0947 L/min) was faster than that of EDTMPA (0.0171 L/min) and EDTMPA with dye (0.0155 L/min) at pH 3.0. It was also found that reaction rates of single EDTMPA removal and EDTMPA and dye mixture removal increased as the reaction pH was increased from 3.0 to 10.5.

Laccase-catalyzed enzymatic dyeing of cotton fabrics

2021 ◽  
pp. 004051752110069
Author(s):  
Rıza Atav ◽  
Bürhan Buğdaycı ◽  
Ömer Bozkurt ◽  
Aylin Yıldız ◽  
Elçin Güneş ◽  
...  
Keyword(s):  
Experimental Studies ◽  
Uv Protection ◽  
Infrared Analysis ◽  
Synthetic Dyes ◽  
Protection Factor ◽  
Knitted Fabrics ◽  
Reactive Dyeing ◽  
Dyeing Process ◽  
Laccase Enzyme ◽  
Color Reproducibility

As some synthetic dyes are regarded to be toxic, mutagenic and carcinogenic, the search for eco-friendly alternatives for the synthesis of dyes and coloration has gained importance. For this reason, this study focused on finding new eco-friendly alternatives for coloring cotton. 100% cotton knitted fabrics were subjected to enzymatic coloration using a commercial laccase enzyme and various precursors. After determining the colors, the effect of pH on the enzymatic dyeing process was investigated. Then the optimization of reaction conditions was also realized statistically for the precursors giving the best results in terms of color. With the aim of obtaining further improvements in color-yield values obtained in enzymatic dyeings, the effect of the pretreatment process and the use of ultrasound were also investigated. Furthermore, the reaction pathways in enzymatic coloration were explained and results were confirmed by means of Fourier Transformed Infrared analysis. As a result of experimental studies, red and lilac colors could be successfully obtained on cotton for the first time in the literature. In this way, the theoretical basis of enzymatic dye synthesis and dyeing of cotton was clarified comprehensively. Furthermore, technical (color reproducibility; washing, rubbing, light and perspiration-fastness values; and UV protection factor), economical (chemical, energy and water consumption required for dyeing (including aftertreatments) of 1 kg fabric) and ecological aspects of enzymatic dyeings were compared with reactive dyeing. According to the experimental results it was found that biological treatment alone was enough for wastewater of enzymatic coloring, while chemical treatment will also be needed in reactive dyeing wastewater. Furthermore, color reproducibility, evenness and UV protection properties of dyed samples were comparable with that of reactive dyeings. However, in terms of the fastness levels achieved, the enzymatic coloring was far behind the reactive dyeing.

Treatment of raw sewage in a temperate climate using a UASB reactor and the hanging sponge cubes process

1997 ◽  
Vol 36 (6-7) ◽  
pp. 433-440 ◽  
Author(s):  
Lalit K. Agrawal ◽  
Yasuhiro Ohashi ◽  
Etsuo Mochida ◽  
Hiroyuki Okui ◽  
Yasuko Ueki ◽  
...  
Keyword(s):  
Ammonia Oxidation ◽  
Upflow Anaerobic Sludge Blanket ◽  
Uasb Reactor ◽  
Temperate Climate ◽  
Anaerobic Sludge ◽  
Treatment Efficiency ◽  
Oxidation Rates ◽  
Air Intake ◽  
Anaerobic Sludge Blanket ◽  
Digested Sewage Sludge

The treatability of raw sewage in a temperate climate (wintertime around 10–20°C) using an upflow anaerobic sludge blanket (UASB) reactor and the hanging sponge cubes process was evaluated. After being seeded with digested sewage sludge, a 47.1 L UASB reactor was continuously operated for more than 2 years by feeding raw sewage, which had average COD around 300 mg/L (41% soluble). During summertime at an HRT of 7 h, effluent COD approximately 70 mg/L total, 50 mg/L soluble and BOD5 20 mg/L total, 12 mg/L soluble was obtained. During wintertime also, treatment efficiency and process stability was good. With the hanging sponge cubes process using the effluent of the UASB reactor treating raw sewage, the following results were obtained. The ammonia oxidation rates of 1.9 and 3.5 g NH4-N·m−2·d−1 in a downflow hanging sponge cubes biofilter, under natural air intake only were obtained during wintertime and summertime, respectively. With post-denitrification and an external carbon source, 84% in average N (NO3+NO2) was removed with an HRT of less than 1 hour and in the temperature range of 13 to 30°C using an upflow submerged hanging sponge bed bioreactor, under anaerobic conditions. The overall system using a UASB reactor and the hanging sponge cubes process could be quite an attractive treatment alternative.

scholarly journals Screening the six plant species for phytoremediation of synthetic textile dye waste water

2020 ◽  
Author(s):  
Navjeet Kaur ◽  
Jyotsna Kaushal ◽  
Pooja Mahajan ◽  
Arun Lal Srivas
Keyword(s):  
Plant Species ◽  
Synthetic Wastewater ◽  
Contaminated Sites ◽  
Textile Dye ◽  
Dye Wastewater ◽  
Active Growth ◽  
Synthetic Dye ◽  
Hibiscus Rosa Sinensis ◽  
Chrysanthemum Indicum ◽  
Tagetes Erecta L

Abstract Most of the dyes are carcinogenic and mutagenic in nature. Plants are potential candidates to remediate textile dye wastewater from contaminated sites. The present study aimed toscreen potential plant species for removal of synthetic dye solution of triarylmethane dye Methylene Blue (MB) and diazo dye Congo Red (CR). Six plant species were screened for their phytoremediation ability for the removal of dyes present in synthetic wastewater. Six plants selected for screening areTrachyspermum ammi L. (T. ammi), Tagetes erecta L. (T. erecta), Hibiscus rosa-sinensis L. (H. rosa- sinensis), Chrysanthemum indicum L. (C. indicum), Bryophyllum fedtschenkoi (B. fedtschenkoi), Catharanthus roseus L. (C. roseus). The phytotreatment of dyes was done up to 40 hfortwo different concentrations of dyes 10 mg L− 1 and 20 mg L− 1. Among these plants, the maximum decolouration was obtained from T. ammi plant followed by B. fedtschenkoi plant. Both of these plants showed active growth even after the phytoremediation process. T. ammi decolourised the MB dye 99% (10 mg L− 1) and 86% (20 mg L− 1) while the decolourisation of the CR dye solution was up to 95% (10 mg L− 1) and 84% (20 mg L− 1).T. ammi found to have maximum potential among screened plants for the removal of MB and CR dye from synthetic dye solution and can be used for decolouration of synthetic dye wastewater.

scholarly journals Removal of Sulphate and Manganese on Synthetic Wastewater in Sulphate Reducing Bioreactor Using Indonesian Natural Zeolite

2017 ◽  
Vol 17 (2) ◽  
pp. 203 ◽  
Author(s):  
Endah Retnaningrum ◽  
Wahyu Wilopo
Keyword(s):  
Natural Zeolite ◽  
Fluidized Bed Reactor ◽  
Synthetic Wastewater ◽  
Particle Analysis ◽  
Support Material ◽  
Scanning Electronic Microscopy ◽  
Electronic Microscopy ◽  
Manganese Removal ◽  
Ph Values ◽  
Reducing Bacteria

The present research was conducted to investigate sulphate and manganese removal from synthetic wastewater. The continuous laboratory scale of down-flow fluidized-bed reactor (DFBR) using sulphate reducing bacteria (SRB) consortium and Indonesian natural zeolite as a bacterial support material was designed. At 9 days operation, maximum sulphate and manganese removal was observed to be 23% and 15.4%, respectively. The pH values were also changed to neutral. The population of SRB increased which effect on the raising of their activity for removing sulphate and manganese. Using the scanning electronic microscopy (SEM), it was observed that natural zeolite possesses excellent physical characteristics as a bacterial support material in DFBR. The imaging SEM result of SRB consortium on zeolite surface clearly showed the developed SRB biofilm on that particle. Analysis result of EDX confirmed that manganese was precipitated as manganese–sulfides.

scholarly journals A new approach for the removal of unfixed dyes from reactive dyed cotton by Fenton oxidation

2019 ◽  
Vol 9 (2) ◽  
pp. 133-141
Author(s):  
Sana Islam ◽  
Irfan Ahmed Shaikh ◽  
Nabeela Firdous ◽  
Azhar Ali ◽  
Yumna Sadef
Keyword(s):  
Treatment Time ◽  
Color Difference ◽  
Quality Parameters ◽  
Water Levels ◽  
Fenton Oxidation ◽  
Color Strength ◽  
New Approach ◽  
Reactive Dyeing ◽  
The Difference ◽  
Day By Day

Abstract The use of fresh water in the textile wash-off process is becoming more expensive day by day due to declining water levels in the region. In this study, the potential of using Fenton oxidation in wash-off cotton reactive dyeing was investigated. The spent wash-off wastewater from one dyeing was first treated with Fenton oxidation, and then reused in several washing-offs employing widely used reactive dyes, C.I. Reactive Yellow 145, C.I. Reactive Blue 21, and C.I. Reactive Red 195. Experimental results showed that at acidic pH (3) using optimized quantities of FeSO4 and H2O2, Fenton process yielded a significant reduction (90–95%) of color in 30 minutes of treatment time. New washing-offs were then carried out in Fenton decolorized wash-off wastewater, and dyed cotton fabric samples were subjected to quality evaluations in terms of color difference properties (ΔL*, Δc*,Δb*, Δa*, ΔE*cmc) and wash fastness properties. This study concluded that after Fenton oxidation, treated liquor can be effectively reused subsequent washing-offs without compromising fabric quality parameters as ΔE*cmc was less than 1, and washing and crocking was also in the range of 4.5–5 which is commercially acceptable. Moreover, the difference in color strength in terms of k/s was also negligible.

Sign in / Sign up

Export Citation Format

Share Document