Quantum Dots Based Materials for Water Treatment

Quantum dot is a new class of nanomaterials having size in nanometers (˂10 nm). This material has excellent photo-catalytic activity towards dyes and pollutants with great absorbance and photoluminescence properties. It shows shifting of peak in UV-FL data which indicates the excitation dependent emission spectra means tunable properties in different wavelength and this property makes it a wonderful probe for sensing application for different heavy metals, pollutants present in water. In this chapter the synthesis, properties, types, application of quantum dots and focus on the research that has been done in field of water treatment with possible future outcomes is discussed.

Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5519
Author(s):  
Lorenzo Gontrani ◽  
Olivia Pulci ◽  
Marilena Carbone ◽  
Roberto Pizzoferrato ◽  
Paolo Prosposito

In this work, we investigate by ab initio calculations and optical experiments the sensitivity of graphene quantum dots in their use as devices to measure the presence, and concentration, of heavy metals in water. We demonstrate that the quenching or enhancement in the optical response (absorption, emission) depends on the metallic ion considered. In particular, two cases of opposite behaviour are considered in detail: Cd2+, where we observe an increase in the emission optical response for increasing concentration, and Pb2+ whose emission spectra, vice versa, are quenched along the concentration rise. The experimental trends reported comply nicely with the different hydration patterns suggested by the models that are also capable of reproducing the minor quenching/enhancing effects observed in other ions. We envisage that quantum dots of graphene may be routinely used as cheap detectors to measure the degree of poisoning ions in water.


2019 ◽  
Vol 7 (3) ◽  
pp. 234-245 ◽  
Author(s):  
Mohammed Asadullah Jahangir ◽  
Sadaf Jamal Gilani ◽  
Abdul Muheem ◽  
Mohammed Jafar ◽  
Mohammed Aslam ◽  
...  

Background: The amalgamation of biological sciences with nano stuff has significantly expedited the progress of biological strategies, greatly promoting practical applications in biomedical fields. Objective: With distinct optical attributes (e.g., robust photostability, restricted emission spectra, tunable broad excitation, and high quantum output), fluorescent quantum dots (QDs) have been feasibly functionalized with manageable interfaces and considerably utilized as a new class of optical probe in biological investigations. Method: In this review article, we structured the current advancements in the preparation methods and attributes of QDs. Furthermore, we extend an overview of the outstanding potential of QDs for biomedical research and radical approaches to drug delivery. Conclusion: Notably, the applications of QDs as smart next-generation nanosystems for neuroscience and pharmacokinetic studies have been explained. Moreover, recent interests in the potential toxicity of QDs are also apprised, ranging from cell investigations to animal studies.


2010 ◽  
Vol 32 (3) ◽  
pp. 12-17 ◽  
Author(s):  
Andrew M. Smith ◽  
Mary M. Wen ◽  
Shuming Nie

Semiconductor quantum dots (QDs) are tiny light-emitting particles that have emerged as a new class of fluorescent labels for biology and medicine. Compared with traditional fluorescent probes, QDs have unique optical and electronic properties such as size-tuneable light emission, narrow and symmetric emission spectra, and broad absorption spectra that enable the simultaneous excitation of multiple fluorescence colours.


Nanoscale ◽  
2022 ◽  
Author(s):  
Manila Ozhukil Valappil ◽  
Subbiah Alwarappan ◽  
Vijayamohanan K. Pillai

Phosphorene quantum dots (PQDs) belong to a new class of zero-dimensional functional nanostructures with unique physicochemical and surface properties in comparison with few-layer phosphorene and other 2D analogues.


Author(s):  
Victor Odhiambo Shikuku ◽  
Tome Sylvain

Geopolymers are amorphous aluminosilicates with some varied applications. However, the use of geopolymers in water treatment is a relatively new subject. This chapter discusses developments in synthesis, properties and applications of geopolymers and their composites for removal of heavy metals and dyes from water including reduction of hardness in water. The adsorption mechanisms and effects of various environmental conditions on adsorption efficiency are also highlighted. The chapter demonstrates that geopolymers are low cost and environmentally benign materials for wastewater treatment and offers opportunities as alternative adsorbents for sequestration of various pollutants from water subject to further investigations.


Author(s):  
Lorenzo Gontrani ◽  
Olivia Pulci ◽  
Marilena Carbone ◽  
Roberto Pizzoferrato ◽  
Paolo Prosposito

In this work, we investigate by ab initio calculations and optical experiments the sensitiv- ity of graphene quantum dots in their use as devices to measure the presence, and concentration, of heavy metals in water. We demonstrate that the quenching or enhancement in the optical response (absorption, emission) depends on the metallic ion considered. In particular, two test cases of opposite behaviour are considered: Cd 2+ , where we observe an increase in the optical response for increasing concentration, and Pb 2 whose emission spectra are quenched along the concentration rise. We envisage that quantum dots of graphene may be routinely used as cheap detectors to measure the degree of poisoning ions in water


Author(s):  
David Erickson ◽  
Baiyang Li ◽  
James R. Adleman ◽  
Saurabh Vyawahare ◽  
Stephen Quake ◽  
...  

Recent advancements in micro- and nanoscale fluidic manipulation have enabled the development of a new class of tunable optical structures which are collectively referred to as optofluidic devices. In this paper we will introduce our recent work directed towards the development of a spectrographic optofluidic memory. Data encoding for the memory is based on creating spectrographic codes consisting of multiple species of photoluminescent nanoparticles at discrete intensity levels which are suspended in liquids. The data cocktails are mixed, delivered and stored using a series of soft and hard-lithography microfluidic structures. Semiconductor quantum dots are ideally suited for this application due to their narrow and size tunable emission spectra and consistent excitation wavelength. Both pressure driven and electrokinetic approaches to spectral code writing have been developed and will be experimentally demonstrated here. Novel techniques for data storage and readout are also discussed and demonstrated.


2021 ◽  
Author(s):  
Xu Dan ◽  
Ruiyi Li ◽  
Qinsheng Wang ◽  
Yongqiang Yang ◽  
Haiyan Zhu ◽  
...  

The paper reports the synthesis of nickel-silver-graphene quantum dot-graphene hybrid. Histidine-functionalized graphene quantum dots (His-GQDs) were bonded to graphene oxide (GO) and then combined with Ni2+ and Ag+ to form...


2021 ◽  
Vol 26 ◽  
pp. 102101
Author(s):  
Vaishali Kale ◽  
Y.M. Hunge ◽  
Shalaka A. Kamble ◽  
Madhuri Deshmukh ◽  
S.V. Bhoraskar ◽  
...  

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