scholarly journals Структурные и фотолюминесцентные свойства графитоподобного нитрида углерода

Author(s):  
А.В. Баглов ◽  
Е.Б. Чубенко ◽  
А.А. Гнитько ◽  
В.Е. Борисенко ◽  
А.А. Малашевич ◽  
...  

Abstract Interrelationship between the structure and optical properties of graphite-like semiconductor carbon nitride produced by the heat treatment of thiocarbamide in an oxygen-containing medium at temperatures in the range from 400°C to 625°C is established. It is found that the maximum of the photoluminescence band shifts from 417 to 494 nm and simultaneously broadens, as the temperature of synthesis is elevated to 625°C. This effect is attributed to doping with oxygen and to the formation of defects as a consequence of decomposition of the already synthesized material with increasing temperature.

2021 ◽  
Vol 900 ◽  
pp. 16-25
Author(s):  
Tabarak Mohammed Awad ◽  
May A.S. Mohammed

In this study, some optical properties were studied of the pure vinyl polyvinyl alcohol (PVA) nanopolymer (German origin). Under the influence of different temperatures and pressures of PVA. Where 25 samples were prepared for the purpose of conducting the research. Which studied the study of these samples was done by recording the absorbance and transmittance spectra of the wavelengths (200-900) nm. From them, absorbance, transmittance, reflectivity, absorption coefficient, refractive index, extinction coefficient, complex dielectric constant were calculated. At different temperatures (25,40, 80, 120, 160)°C. And with different pressures within the range (7.5,8,8.5,9,9.5) MPa. The results are that the permeability of the polymer (PVA) at different temperatures for each pressure decreases with increasing temperature, and that all other calculated optical properties increase with increasing temperature.


RSC Advances ◽  
2015 ◽  
Vol 5 (18) ◽  
pp. 14027-14033 ◽  
Author(s):  
Zhijun Huang ◽  
Fengbo Li ◽  
Bingfeng Chen ◽  
Guoqing Yuan

Nanostructured g-C3N4 with high surface area from heat treatment of guanidinium cyanurate exhibits better optical properties and enhanced photocatalytic activity.


RSC Advances ◽  
2021 ◽  
Vol 11 (14) ◽  
pp. 7779-7789 ◽  
Author(s):  
Asmat Ullah Khan ◽  
Rasheed Ahmad Khera ◽  
Naveed Anjum ◽  
Rao Aqil Shehzad ◽  
Saleem Iqbal ◽  
...  

DFT calculations are carried out to investigate nonlinear optical (NLO) properties of superhalogen (BCl4) and superalkali (NLi4) doped graphitic carbon nitride (GCN).


2021 ◽  
Vol 2 (18) ◽  
pp. 6083-6093
Author(s):  
Yuto Miyake ◽  
Goichiro Seo ◽  
Kotaro Matsuhashi ◽  
Noriyuki Takada ◽  
Kaname Kanai

Melem tetramer, the newly synthesized carbon nitride compound is composed of oligomers with four melem units, is stable in air, and has improved optical properties compared to melon.


2016 ◽  
Vol 4 (7) ◽  
pp. 2445-2452 ◽  
Author(s):  
Mohammad Ziaur Rahman ◽  
Jingrun Ran ◽  
Youhong Tang ◽  
Mietek Jaroniec ◽  
Shi Zhang Qiao

We introduce a three-step method (co-polymerization, surface activation and exfoliation) for the first time to synthesize sub-nanometer-thin carbon nitride nanosheets as highly efficient hydrogen evolution photocatalysts.


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