Study the Effect of Heat Treatment and Pressure on some the Optical Properties of the Pure PVA Nano Polymer

2021 ◽  
Vol 900 ◽  
pp. 16-25
Author(s):  
Tabarak Mohammed Awad ◽  
May A.S. Mohammed
Keyword(s):  
Heat Treatment ◽  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Absorption Coefficient ◽  
Polyvinyl Alcohol ◽  
Complex Dielectric Constant ◽  
Different Temperatures ◽  
German Origin ◽  
Increasing Temperature

In this study, some optical properties were studied of the pure vinyl polyvinyl alcohol (PVA) nanopolymer (German origin). Under the influence of different temperatures and pressures of PVA. Where 25 samples were prepared for the purpose of conducting the research. Which studied the study of these samples was done by recording the absorbance and transmittance spectra of the wavelengths (200-900) nm. From them, absorbance, transmittance, reflectivity, absorption coefficient, refractive index, extinction coefficient, complex dielectric constant were calculated. At different temperatures (25,40, 80, 120, 160)°C. And with different pressures within the range (7.5,8,8.5,9,9.5) MPa. The results are that the permeability of the polymer (PVA) at different temperatures for each pressure decreases with increasing temperature, and that all other calculated optical properties increase with increasing temperature.

scholarly journals Preparation and Studying the Optical Properties of (Sb2o3) Thin Films

2018 ◽  
Vol 26 (10) ◽  
pp. 249-256
Author(s):  
Waleed Khalid Kadhim
Keyword(s):  
Thin Films ◽  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Absorption Coefficient ◽  
Thermal Evaporation ◽  
Glass Slide ◽  
Antimony Trioxide ◽  
Hot Plate ◽  
Different Thickness

In this paper I present the preparation of (Sb2o3) thin films using thermal evaporation in vacuum, procedure with different thickness  (100 ,150 ,200 ,and 250) nm, by using ( hot plate) from Molybdenum matter at temperature in ( 9000c) and the period of time (15mint) ,the prepared in a manner thermal evaporation in a vacuum and precipitated on glass bases, pure Antimony Trioxide (sb2o3 ) thin films with various condition have been successfully deposited by (T.E.V) on glass slide substrates. The substrates temperature of about 100oC and the vacuum of about 10-6 torr, to investigated oxidation of evaporated, measure spectra for prepared films in arrange of wavelength (250 – 1100 nm). The following optical properties have been calculated: the absorption coefficient, the forbidden (Eg) for direct and indirect transitions "absorbance, refractive index,  extinction coefficient, real and imaginary parts" of the dielectric constant.

scholarly journals Annealing Effect on Some Optical Properties of Cr2O3 Thin Films Prepared by Spray Pyrolysis Technique

2011 ◽  
Vol 8 (2) ◽  
pp. 561-565
Author(s):  
Baghdad Science Journal
Keyword(s):  
Thin Films ◽  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Absorption Coefficient ◽  
Spray Pyrolysis ◽  
Annealing Temperature ◽  
Spray Pyrolysis Technique ◽  
Annealing Effect ◽  
Before And After

Cr2O3 thin films have been prepared by spray pyrolysis on a glass substrate. Absorbance and transmittance spectra were recorded in the wavelength range (300-900) nm before and after annealing. The effects of annealing temperature on absorption coefficient, refractive index, extinction coefficient, real and imaginary parts of dielectric constant and optical conductivity were expected. It was found that all these parameters increase as the annealing temperature increased to 550°C.

Optical properties of the different tapered silicon nanowires based on KK relation

2014 ◽  
Vol 23 (04) ◽  
pp. 1450049 ◽  
Author(s):  
Zhongyi Guo ◽  
Keya Zhou ◽  
Anjun Zhang ◽  
Jung-Ho Lee
Keyword(s):  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Silicon Nanowires ◽  
Complex Refractive Index ◽  
Complex Dielectric Constant ◽  
Reflection Spectra ◽  
Complex Dielectric Function ◽  
Concrete Material ◽  
Material Parameters

The optical properties of the various types of tapered silicon nanowires (SiNWs) have been investigated by the phase retrieving method of utilizing the experimental reflection spectra with the aid of the Kramers–Kronig (KK) relation. The effective refractive index (n) and the extinction coefficient (K) of each tapered SiNWs and combined silicon nanowires and microwires (CNMW) array samples can be obtained from concrete simulation by the KK relation. At the same time, we can also obtain the real part (ε′) and imaginary part (ε″) of the effective complex dielectric constant from the relation between the refractive index and the complex dielectric constant of samples. And the simulated results show that the relative material parameters (effective complex refractive index, effective complex dielectric function) can be modulated from a concrete material processing.

scholarly journals Effect of Annealing on the Optical Properties of (PVA-CuCl) Composites

2016 ◽  
Vol 63 ◽  
pp. 98-105 ◽  
Author(s):  
Sabah A. Salman ◽  
Nabeel A. Bakr ◽  
Marwa R. Jwameer
Keyword(s):  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Absorption Coefficient ◽  
Optical Constants ◽  
Energy Gap ◽  
Copper Chloride ◽  
Chloride Salt ◽  
Casting Technique ◽  
Transmission And Absorption

Films of polymer (polyvinyl alcohol (PVA)) doped with CuCl salt at different concentrations (2 and 10) wt% were prepared using casting technique. The optical properties of the films were studied after annealing. The transmission and absorption spectra have been recorded in the wavelength range of (300-1100) nm. The effect of annealing on the optical properties for (PVA-CuCl) films with different concentrations (2 and 10) wt% of copper chloride salt shows that the transmittance decreased after annealing for all the films. The optical constants (absorption coefficient, refractive index, extinction coefficient, real and imaginary parts of dielectric constant) for all the films are affected by annealing. The energy gap (Eg) of all the films decreased after annealing.

scholarly journals The Effect of Thickness on Some Optical Properties of Sb2S3 Thin Films Prepared by Chemical Bath Deposition

2010 ◽  
Vol 7 (1) ◽  
pp. 168-173
Author(s):  
Baghdad Science Journal
Keyword(s):  
Thin Films ◽  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Absorption Coefficient ◽  
Chemical Bath Deposition ◽  
Wavelength Range ◽  
Imaginary Part ◽  
Extinction Coefficient ◽  
Dielectric Constant Increase

Sb2S3 thin films have been prepared by chemical bath deposition on a glas sub Absorbance and transmittance spectra were recorded in the wavelength range (30-900) nm. The effects of thickness on absorption coefficient, reflectance, refractive index, extinction coefficient, real and imaginary parts of dielectric constant were estimated. It was found that the reflectivity, absorption coefficient , extinction coefficient, real part of dielectric constant and refractive index, all these parameters decrease as the thickness increased, while the imaginary part of the dielectric constant increase as the thickness increased.

scholarly journals Reduced Graphene Oxide/Polyvinyl Alcohol Nanofibers Fabricated by Electrospinning Technique as An Ideal Candidate for Organic Solar Cell Devices

2021 ◽  
Vol 6 (1) ◽  
pp. 10-18
Author(s):  
Asriani Asriani ◽  
◽  
Iman Santoso ◽  
Keyword(s):  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Solar Cell ◽  
Ftir Spectroscopy ◽  
Organic Solar Cell ◽  
Chemical Reduction ◽  
Complex Refractive Index ◽  
Complex Dielectric Constant ◽  
Electrospinning Technique

Functionalization of rGO that previously obtained by chemical reduction using hydrazine hydrate, has been done by changing its morphology into nanofiber with electrospinning technique and using PVA as a polymer matrix. The rGO nanofibers that had been formed were then characterized using Fourier Transformation-Infra Red (FTIR) spectroscopy, Scanning Electron Microscopy (SEM), and UV-Vis Spectrophotometer. FTIR spectroscopy confirmed the presence of C – C group and C = O group in nanofibers. SEM showed the change of nanofibers morphology which is marked by the increasing of fibres diameter and the hollow fibres become brighter. Furthermore, the effect of rGO concentration to nanofiber optical properties was confirmed by UV-Vis spectrophotometer. According to this characterization, the absorbance of rGO/PVA nanofiber is decreased due to increased rGO concentration. The detail of optical properties of rGO is studied through complex refractive index and dielectric constant in which Kramers-Kronig transformation is then employed to calculate complex refractive index and complex dielectric constant. From the data, the optical properties of rGO/PVA nanofibers indicating that rGO/PVA nanofibers can be applied as transparent electrode an organic solar cell devices.

scholarly journals Characteristics of Poly(vinyl Alcohol) (PVA) Based Composites Integrated with Green Synthesized Al3+-Metal Complex: Structural, Optical, and Localized Density of State Analysis

Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1316
Author(s):  
Shujahadeen B. Aziz ◽  
Muaffaq M. Nofal ◽  
Hewa O. Ghareeb ◽  
Elham M. A. Dannoun ◽  
Sarkawt A. Hussen ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Refractive Index ◽  
Metal Complex ◽  
Band Gap ◽  
Optical Band Gap ◽  
Complex Dielectric Constant ◽  
Poly Vinyl Alcohol ◽  
Optical Parameters ◽  
Dispersion Energy ◽  
Casting Technique

The influence of dispersing Al-metal complex on the optical properties of PVA was investigated using UV–visible spectroscopy. Polymer composite films with various Al3+-complex amounts in the PVA matrix were arranged by solution casting technique by means of distilled water as a widespread solvent. The formation of Al3+-metal complex was verified through Ultraviolet–visible (UV-Vis) and Fourier-transform infrared spectroscopy (FTIR) examinations. The addition of Al-complex into the polymer matrix led to the recovery of the optical parameters such as dielectric constant (εr and εi) and refractive index (n). The variations of real and imaginary parts of complex dielectric constant as a function of photon wavelength were studied to calculate localized charge density values (N/m*), high-frequency dielectric constant, relaxation time, optical mobility, optical resistivity, and plasma angular frequency (ωp) of electrons. In proportion with Al3+-complex content, the N/m* values were amplified from 3.68 × 1055 kg−1 m−3 to 109 × 1055 kg−1 m−3. The study of optical parameters may find applications within optical instrument manufacturing. The optical band gap was determined from Tauc’s equation, and the type of electronic transition was specified. A remarkable drop in the optical band gap was observed. The dispersion of static refractive index (no) of the prepared composites was analyzed using the theoretical Wemple–DiDomenico single oscillator model. The average oscillator energy (Eo) and oscillator dispersion energy (Ed) parameters were estimated.

Effect of non-annealed and annealed ZnO on the optical properties of PVC/ZnO nanocomposite films

2021 ◽  
pp. 089270572110386
Author(s):  
Ali F Al-Shawabkeh ◽  
Ziad M Elimat ◽  
Khaleel N Abushgair
Keyword(s):  
Dielectric Constant ◽  
Refractive Index ◽  
Optical Properties ◽  
Zno Nanoparticles ◽  
Oscillator Strengths ◽  
Nanocomposite Films ◽  
Optical Parameters ◽  
Zno Nanoparticle ◽  
Dispersion Energy ◽  
Optical Susceptibility

The goal of this study was to investigate the optical properties of the prepared polyvinyl chloride (PVC)/zinc oxide (ZnO) nanocomposite films. The PVC/ZnO nanocomposite films consist of the addition of different concentrations with both non-annealed ZnO nanoparticles and ZnO nanoparticles annealed at temperature of 700°C. The PVC/ZnO nanocomposite films by weight concentrations of (0 wt.%, 2.5 wt.%, 5 wt.% and 10 wt.%) have been prepared by the casting method. The optical absorbance and transmittance values of the composites films were measured in the wavelength range between (250 to 1100 nm) at room temperature by using the UV-1800 Shimadzu spectrophotometer. The optical properties (absorption coefficient, dielectric constant, refractive index, and optical conductivity) have been investigated by the ultraviolet (UV) spectrophotometer. The optical parameters (direct optical energy gap, excitation energy for electronic transitions, the dispersion energy, static refractive index, static dielectric constant, optical oscillator strengths, the moments of optical spectrum, linear optical susceptibility, third-order nonlinear optical susceptibility, nonlinear refractive index, high-frequency dielectric constant, the carrier concentration to the effective mass ratio, the long wavelength refractive index and the plasma frequency) were calculated. The results showed that the optical properties behavior of the PVC/ZnO nanocomposite films was found to be dependent on the ZnO concentration, and photon wavelength. In addition, the results of the study show that the optical parameters can be influenced by alter the concentration of the nonannealed and annealed a ZnO nanoparticle in the PVC polymer matrix.

THEORETICAL MODEL FOR THE CALCULATION OF OPTICAL PROPERTIES OF GOLD NANOPARTICLES

2010 ◽  
Vol 19 (03) ◽  
pp. 427-436
Author(s):  
A. MENDOZA-GARCÍA ◽  
A. ROMERO-DEPABLOS ◽  
M. A. ORTEGA ◽  
J. L. PAZ ◽  
L. ECHEVARRÍA
Keyword(s):  
Gold Nanoparticles ◽  
Refractive Index ◽  
Optical Properties ◽  
Theoretical Model ◽  
Absorption Coefficient ◽  
Molecular System ◽  
Two Dimensional ◽  
Box Models ◽  
Solvent Environment ◽  
Absorption And Dispersion

We have developed an analytical method to describe the optical properties of nanoparticles, whose results are in agreement with the observed experimental behavior according to the size of the nanoparticle under analysis. Our considerations to describe plasmonic absorption and dispersion are based on the combination of the two-level molecular system and the two-dimensional quantum box models. Employing the optical stochastic Bloch equations, we have determined the system's coherence, from which we have calculated expressions for the absorption coefficient and refractive index. The innovation of this methodology is that it allows us to take into account the solvent environment, which induce quantum effects not considered by classical treatments.

scholarly journals Deposition Time induced Structural and Optical Properties of Lead Tin Sulphide Thin Films

2021 ◽  
pp. 455-458
Author(s):  
J. Damisa ◽  
J. O. Emegha ◽  
I. L. Ikhioya
Keyword(s):  
Thin Films ◽  
Refractive Index ◽  
Optical Properties ◽  
Absorption Coefficient ◽  
Tin Oxide ◽  
Deposition Time ◽  
Deposition Process ◽  
Structural And Optical Properties ◽  
X Ray ◽  
Prepared Material

Lead tin sulphide (Pb-Sn-S) thin films (TFs) were deposited on fluorine-doped tin oxide (FTO) substrates via the electrochemical deposition process using lead (II) nitrate [Pb(NO3)2], tin (II) chloride dehydrate [SnCl2.2H2O] and thiacetamide [C2H5NS] precursors as sources of lead (Pb), tin (Sn) and sulphur (S). The solution of all the compounds was harmonized with a stirrer (magnetic) at 300k. In this study, we reported on the improvements in the properties (structural and optical) of Pb-Sn-S TFs by varying the deposition time. We observed from X-ray diffractometer (XRD) that the prepared material is polycrystalline in nature. UV-Vis measurements were done for the optical characterizations and the band gap values were seen to be increasing from 1.52 to 1.54 eV with deposition time. In addition to this, the absorption coefficient and refractive index were also estimated and discussed.

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