scholarly journals The role of nanotechnology for improving crop production

2019 ◽  
Vol 14 (4) ◽  
pp. 297-305
Author(s):  
Amir Lakzian ◽  
Maryam Bayat ◽  
Anvar Gadzhikurbanov ◽  
Meisam Zargar
Keyword(s):  
Crop Production ◽  
Bacterial Species ◽  
Chemical Properties ◽  
Cost Effective ◽  
Seed Vigor ◽  
Biological Synthesis ◽  
Synthesis Of Nanoparticles ◽  
Disease Diagnostics ◽  
And Chemical Properties

Today, green nanotechnology has great importance due to the presence of different modes of restrictive action against various pathogens such as fungi and bacterial species. The use of nanomaterials has recently increased in agriculture and plant-tissue culture thanks to their unique different properties such as; magnetic, electrical, mechanical, optical, and chemical properties. Optimum use of iron increases protein content in the wheat grain. They also enhance plant growth by improving disease resistance and increase stability of the plants by anti-bending and deeper rooting of crops. It has been reported by many researchers that Nano-fertilizers significantly influenced the seed germination which demonstrated the effect of Nano fertilizers on seed and seed vigor. Chemical methods have been used for the synthesis of nanoparticles. Developing Nano-biotechnology is generating interests in research towards eco-friendly, cost effective and biological synthesis of nanoparticles. Nanoparticles systems have been combined into plant fungal disease controlpractices. Using nanoparticles as biosensors in plant disease diagnostics is also illustrated.

The Nature of S-N Bonding in Sulfonamides and Related Compounds: Insights into π-Bonding Contributions from Sulfur K-Edge XAS

2020 ◽  
Author(s):  
Tulin Okbinoglu ◽  
Pierre Kennepohl
Keyword(s):  
Density Functional ◽  
Chemical Properties ◽  
Functional Theory ◽  
Rotational Barriers ◽  
Td Dft ◽  
Nitrogen Bonds ◽  
X Ray Absorption ◽  
Related Compounds ◽  
And Chemical Properties

Molecules containing sulfur-nitrogen bonds, like sulfonamides, have long been of interest due to their many uses and chemical properties. Understanding the factors that cause sulfonamide reactivity is important, yet their continues to be controversy regarding the relevance of S-N π bonding in describing these species. In this paper, we use sulfur K-edge x-ray absorption spectroscopy (XAS) in conjunction with density functional theory (DFT) to explore the role of S<sub>3p</sub> contributions to π-bonding in sulfonamides, sulfinamides and sulfenamides. We explore the nature of electron distribution of the sulfur atom and its nearest neighbors and extend the scope to explore the effects on rotational barriers along the sulfur-nitrogen axis. The experimental XAS data together with TD-DFT calculations confirm that sulfonamides, and the other sulfinated amides in this series, have essentially no S-N π bonding involving S<sub>3p</sub> contributions and that electron repulsion and is the dominant force that affect rotational barriers.

scholarly journals Synthesis and Conductivity Studies of Poly(Methyl Methacrylate) (PMMA) by Co-Polymerization and Blending with Polyaniline (PANi)

Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1939
Author(s):  
Helyati Abu Hassan Shaari ◽  
Muhammad Mahyiddin Ramli ◽  
Mohd Nazim Mohtar ◽  
Norizah Abdul Rahman ◽  
Azizan Ahmad
Keyword(s):  
Methyl Methacrylate ◽  
Mechanical Stability ◽  
Chemical Properties ◽  
Cost Effective ◽  
Poly Methyl Methacrylate ◽  
Conducting Materials ◽  
Potential Applications ◽  
Polymerization Condition ◽  
Physical And Chemical ◽  
And Chemical Properties

Poly(methyl methacrylate) (PMMA) is a lightweight insulating polymer that possesses good mechanical stability. On the other hand, polyaniline (PANi) is one of the most favorable conducting materials to be used, as it is easily synthesized, cost-effective, and has good conductivity. However, most organic solvents have restricted potential applications due to poor mechanical properties and dispersibility. Compared to PANi, PMMA has more outstanding physical and chemical properties, such as good dimensional stability and better molecular interactions between the monomers. To date, many research studies have focused on incorporating PANi into PMMA. In this review, the properties and suitability of PANi as a conducting material are briefly reviewed. The major parts of this paper reviewed different approaches to incorporating PANi into PMMA, as well as evaluating the modifications to improve its conductivity. Finally, the polymerization condition to prepare PMMA/PANi copolymer to improve its conductivity is also discussed.

Transportation pathways of pesticides in two major watersheds of Istanbul, Turkey

2004 ◽  
Vol 49 (3) ◽  
pp. 165-172 ◽  
Author(s):  
M. Yazgan ◽  
A. Tanik
Keyword(s):  
Chemical Properties ◽  
Surface Flow ◽  
Priority List ◽  
Pesticide Pollution ◽  
Consumption Values ◽  
Annual Consumption ◽  
Agricultural Areas ◽  
Physical And Chemical ◽  
And Chemical Properties

The study covers the investigation of pesticides in terms of consumption, toxicological classification and various intrinsic physical and chemical properties like DT50, KOC, GUS, solubility that describe the important mechanisms prevailing in soil, namely persistence and mobility. These mechanisms help to estimate the transportation pathways of pesticides on soil till they reach the receiving water after being applied on land. Classification is done in three groups, those likely to appear in surface flow, those that appear in groundwater and those that present transient conditions. Such an approach that also takes into account toxicological levels and annual consumption values of pesticides will act as a tool to prepare the priority list of pesticides that need special care during their transportation. The fate of pesticides is a difficult task to solve, however, such a methodology, puts forth a rough estimate on their behavior in spite of uncertainties in many of the parameters describing mechanisms like persistence and mobility. The agricultural areas of two watersheds of Istanbul are selected as target areas to describe the approach, which is also checked with another approach estimating pesticide pollution potential that considers various other properties of pesticides. Almost similar findings are depicted with 85% proximity. The methodology presented in the paper illustrates and emphasizes the significant role of pesticide properties in determining their fate in soil after being applied.

Exploring the role of dosing procedure and chemical properties in in vitro assays using a fish gill cell line

2009 ◽  
Vol 153 (2) ◽  
pp. S89
Author(s):  
Kristin Schirmer ◽  
Katrin Tanneberger ◽  
Nynke I. Kramer ◽  
Frans J.M. Busser ◽  
Joop L.M. Hermens ◽  
...  
Keyword(s):  
Cell Line ◽  
Chemical Properties ◽  
In Vitro Assays ◽  
Fish Gill ◽  
Gill Cell ◽  
And Chemical Properties

scholarly journals Impact of Bush Burning on Chemical Properties of Some Soil in Igboora, Oyo State, Nigeria

2021 ◽  
Vol 7 (2) ◽  
Author(s):  
M. A. Adejumobi
Keyword(s):  
Crop Production ◽  
Chemical Properties ◽  
Soil Chemical Properties ◽  
Rooting Depth ◽  
Physical And Chemical Properties ◽  
Land Clearing ◽  
Two Samples ◽  
Burnt Soil ◽  
Physical And Chemical ◽  
And Chemical Properties

Soil is used in agriculture as an anchor and primary nutrient base for plants, and the types of soil and available moisture determine the species of plants that can be cultivated. Bush burning, whether as result of a wildfire or a controlled burning, affects not only the appearance of the landscape, but the quality of the soil. Bush burning method of land clearing is a traditional farming system used as a means of land clearing for crop production. This method of land clearing has both beneficial and detrimental effects on soil physical and chemical properties. Therefore, this study investigated the effects of bush burning on soil chemical properties at different soil depth of 0-30 cm and 30-60 cm respectively base on the rooting depth of crop planted. The experiment was carried out in six selected farms in Igboora, Ibarapa central Local Governmental, Oyo State. The soil sampled were collected from burnt and unburnt experimental soil and analyzed using USDA standard methods for soil analysis for the selected chemical characteristics (pH, Ca2+, Mg2+ Na+. TN and P). Two samples were taken from each burnt and un-burnt locations at depth of 0-30 and 30-60 cm. Paired t-test was used to compare means value of soil chemical properties determined from burnt and un-burnt soil. ANOVA was used for significance difference between soil from burnt and un-burnt soil. pH increased from moderately acidic to slightly acidic, phosphorus content of the soil increased greatly from un-burnt soil to burnt soil at 0-30 cm and 30-60 cm depths from 6.64 to 22.21 ppm and 3.53 to 24.95 ppm, respectively. Similarly, potassium increased from 0.27 to 0.40ppm at 0-30cm depth but decreased from 0.23 to 0.17 ppm at 30-60 cm depth. Nitrogen reduced at both depths from 0.80 to 0.76% and 0.72 to 0.68% respectively. Magnesium also increased from 1.3 cmol/kg to 2.00 cmol/kg and 1.65 to 1.75 cmol/kg at both 0-30 cm and 30-60 cm depth respectively. Whereas calcium showed a reduction from 3.17 to 2.85 cmol/kg and 1.65 to 1.45 cmol/kg at both depths. The variations observed between burnt and un-burnt soil for Ca, Mg, exchangeable acidity, pH, Nitrogen, potassium was significant at p<0.05 probability level. This indicates that bush burning has an impact on soil physical and chemical properties which may affect the suitability of the soil for crop production. Based on this, there is need for environmental education for farmers in the area in order to know the implications of bush burning on soil properties for soil sustainability which will boost food production.

Basic Performance Research of Polymer Intercalation Clay

2012 ◽  
Vol 578 ◽  
pp. 183-186
Author(s):  
Xiao Chun Cao ◽  
Yi Qin ◽  
Yan Na Zhao ◽  
Kun Ke
Keyword(s):  
Drilling Fluid ◽  
Chemical Properties ◽  
Drilling Fluids ◽  
Technical Problems ◽  
Clay Particles ◽  
Polymer Properties ◽  
Physical And Chemical ◽  
Performance Research ◽  
And Chemical Properties

Using the preliminary research of the polymer properties, the different between the physical and chemical properties of new polymer-clays nanometer composites and clay have been studied. Different polymers are used to evaluate experiment. Based on a large number of lab experiments, the changes of rheological property and API filtration property of polymer-clay drilling fluids nanometer composites are studied. The results show that clay particles could become smaller and the composites drilling fluid have the role of controlling loss and enhancing cake quality. The prepared composites could be used to solve the technical problems in drilling fluid.

Role of lattice defects in catalytic activities of graphene clusters for fuel cells

2015 ◽  
Vol 17 (26) ◽  
pp. 16733-16743 ◽  
Author(s):  
Lipeng Zhang ◽  
Quan Xu ◽  
Jianbing Niu ◽  
Zhenhai Xia
Keyword(s):  
Fuel Cells ◽  
Electronic Structures ◽  
Chemical Properties ◽  
Lattice Defects ◽  
Physical And Chemical Properties ◽  
Catalytic Activities ◽  
Physical And Chemical ◽  
And Chemical Properties

Defects are common but important in graphene, which could significantly tailor the electronic structures and physical and chemical properties.

scholarly journals Zeolites application in terrestrial and space industry – a review

2020 ◽  
Vol 32 ◽  
pp. 209-223
Author(s):  
Adelina Miteva ◽  
Valeria Stoyanova
Keyword(s):  
Chemical Properties ◽  
Waste Materials ◽  
Ion Exchangers ◽  
Science And Engineering ◽  
Space Industry ◽  
Synthetic Zeolites ◽  
The Impact ◽  
And Chemical Properties

This brief overview presents an attempt to systematize some of the available historical and recent data on the impact of zeolite science and engineering on the progress of various areas of Earth and Space development. The basic structural and chemical properties of natural and synthetic zeolites are presented. Valuable applications of the zeolites, such as catalysts, gas adsorbers and ion exchangers are also included. The most commonly used methods for the synthesis of zeolites from different materials are presented, as well as some Bulgarian developments for the reuse of waste materials to zeolites. The important role of zeolites as an indispensable material for improving the quality of soil, fuels, water, air, etc., required for the needs of orbiting space stations and spacecrafts has been confirmed by typical examples.

scholarly journals Partial synthetic models of FeMoco with sulfide and carbyne ligands: Effect of interstitial atom in nitrogenase active site

2021 ◽  
Vol 118 (49) ◽  
pp. e2109241118
Author(s):  
Linh N. V. Le ◽  
Gwendolyn A. Bailey ◽  
Anna G. Scott ◽  
Theodor Agapie
Keyword(s):  
Active Sites ◽  
Chemical Properties ◽  
Metal Centers ◽  
Bridging Ligand ◽  
Reduction Potentials ◽  
Protein Active Sites ◽  
Physical And Chemical ◽  
Synthetic Models ◽  
And Chemical Properties

Nitrogen-fixing organisms perform dinitrogen reduction to ammonia at an Fe-M (M = Mo, Fe, or V) cofactor (FeMco) of nitrogenase. FeMco displays eight metal centers bridged by sulfides and a carbide having the MFe7S8C cluster composition. The role of the carbide ligand, a unique motif in protein active sites, remains poorly understood. Toward addressing how the carbon bridge affects the physical and chemical properties of the cluster, we isolated synthetic models of subsite MFe3S3C displaying sulfides and a chelating carbyne ligand. We developed synthetic protocols for structurally related clusters, [Tp*M’Fe3S3X]n−, where M’ = Mo or W, the bridging ligand X = CR, N, NR, S, and Tp* = Tris(3,5-dimethyl-1-pyrazolyl)hydroborate, to study the effects of the identity of the heterometal and the bridging X group on structure and electrochemistry. While the nature of M’ results in minor changes, the chelating, μ3-bridging carbyne has a large impact on reduction potentials, being up to 1 V more reducing compared to nonchelating N and S analogs.

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