scholarly journals A strategy for constructing highly efficient Co3O4-C@SiO2 nanofibers catalytic membrane for NOx-SCR and dust removal

2021 ◽  
Author(s):  
Huixian Zhou ◽  
Yutang Kang ◽  
Hui zhong ◽  
Bin Chen ◽  
Shuanglu Ma ◽  
...  
Keyword(s):  
High Performance ◽  
Gas Permeability ◽  
Catalytic Performance ◽  
Filtration Efficiency ◽  
Co3o4 Nanoparticles ◽  
Catalytic Membrane ◽  
Nh3 Scr ◽  
Nanofiber Membranes ◽  
And Performance

The strategy of constructing catalytic membrane has a significant influence on its structure and performance. In this work, Co3O4-Cx@SiO2 nanofiber membranes (NFMs) were fabricated by an in-situ growth–pyrolysis–oxidation strategy. The Co3O4-Cx catalyst derived from ZIF-67 was wrapped around nanofibers, which helps to maintain a stable membrane structure, then suppressing the reduction of gas permeability. Among the Co3O4-Cx catalyst, the carbon skeleton can prevent the agglomeration of Co3O4 nanoparticles, obtaining an ultra-fine Co3O4 nanoparticles with high dispersibility, redox property and surface area. The obtained Co3O4-C300@SiO2 NFM exhibits excellent filtration efficiency and low pressure drop for PM2.5 (99.99% and 55 Pa) and outstanding catalytic performance with T90 of 245 °C for NH3-SCR, which is 40.3% higher than that of Co3O4@SiO2 NFM. This work might provide a universal strategy for the preparation of catalytic membrane with high-performance.

scholarly journals The Study of C3H6 Impact on Selective Catalytic Reduction by Ammonia (NH3-SCR) Performance over Cu-SAPO-34 Catalysts

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1327
Author(s):  
Yingfeng Duan ◽  
Lina Wang ◽  
Yagang Zhang ◽  
Wei Du ◽  
Yating Zhang
Keyword(s):  
Reaction Rate ◽  
Catalytic Reduction ◽  
Catalytic Performance ◽  
Coke Deposition ◽  
In Situ Drifts ◽  
Nh3 Scr ◽  
Nox Conversion ◽  
Temperature Ranges ◽  
And Performance

In present work, the catalytic performance of Cu-SAPO-34 catalysts with or without propylene during the NH3-SCR process was conducted, and it was found that the de-NOx activity decreased during low temperature ranges (<350 °C), but obviously improved within the range of high temperatures (>350 °C) in the presence of propylene. The XRD, BET, TG, NH3-TPD, NOx-TPD, in situ DRIFTS and gas-switch experiments were performed to explore the propylene effect on the structure and performance of Cu-SAPO-34 catalysts. The bulk characterization and TG results revealed that neither coke deposition nor the variation of structure and physical properties of catalysts were observed after C3H6 treatment. Generally speaking, at the low temperatures (<350 °C), active Cu2+ species could be occupied by propylene, which inhibited the adsorption and oxidation of NOx species, confining the SCR reaction rate and causing the deactivation of Cu-SAPO-34 catalysts. However, with the increase of reaction temperatures, the occupied Cu2+ sites would be recovered and sequentially participate into the NH3-SCR reaction. Additionally, C3H6-SCR reaction also showed the synergetic contribution to the improvement of NOx conversion at high temperature (>350 °C).

In situ growth of ultrathin Ni–Fe LDH nanosheets for high performance oxygen evolution reaction

2017 ◽  
Vol 4 (7) ◽  
pp. 1173-1181 ◽  
Author(s):  
Haidong Yang ◽  
Sha Luo ◽  
Yun Bao ◽  
Yutong Luo ◽  
Jun Jin ◽  
...  
Keyword(s):  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Copper Foil ◽  
Catalytic Performance ◽  
In Situ Growth ◽  
Ultrathin Nanosheet

The ultrathin Ni70Fe30LDH nanosheets were successfullyin situgrown on anodic polarized copper foil, denoted as u-Ni70Fe30LDHs/a-CF. Benefiting from the ultrathin nanosheet structure, the catalyst exhibits remarkable catalytic performance for OER in 1 M KOH solution.

In situ growth of Co3O4 nanoparticles on α-MnO2 nanotubes: a new hybrid for high-performance supercapacitors

2014 ◽  
Vol 2 (22) ◽  
pp. 8465-8471 ◽  
Author(s):  
Dongbo Yu ◽  
Jianfeng Yao ◽  
Ling Qiu ◽  
Yufei Wang ◽  
Xinyi Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Physical Mixture ◽  
Co3o4 Nanoparticles ◽  
In Situ Growth

A new MnO2@Co3O4 hybrid with small-sized Co3O4 nanoparticles grown on α-MnO2 nanotubes exhibited much improved capacitive performances than those of pristine α-MnO2 nanotubes and a physical mixture of α-MnO2 nanotubes and Co3O4 nanoparticles.

scholarly journals Development of the “High Pressure Repair Dome” system for in-situ high performance repair of aeronautic structures

2018 ◽  
Vol 188 ◽  
pp. 04004
Author(s):  
Nicola Gallo ◽  
Silvio Pappadá ◽  
Umberto Raganato ◽  
Stefano Corvaglia
Keyword(s):  
High Pressure ◽  
High Performance ◽  
Stress Transfer ◽  
Cost Effective ◽  
Reliable Technique ◽  
Structural Repair ◽  
Aerospace Applications ◽  
And Performance ◽  
Curing Cycle

As the use of composites for high-performance structures for aerospace applications is constantly increasing, together with the complexity and scale of such structures, an increasingly effort is carried out for the development of advanced techniques for composites structural repair. Mechanical loads and environmental conditions often cause composite damages. If material damage is not extensive, structural repair is the most cost-effective solution. Composite patches can be mechanically fastened, adhesively bonded or co-cured. Bonding or co-curing process provides enhanced stress transfer mechanisms, joint efficiencies and aerodynamic performance. In this paper an innovative and reliable technique to repair damaged composite aeronautical components, named High Pressure Repair Dome (HPRD), is shown. The innovative aspect of this solution is the possibility to bond or co-cure a composite prepreg patch under a pressurized dome, thus using a prepreg compatible with the composite structure. HPRD was developed to allow in-situ repairing on full-scale structures, with the possibility of an accurate control of the parameters of the curing cycle. The advantages and performance of HPRD approach will be discussed and compared with traditional techniques, describing the results achieved and the activity on-course for the full industrialization of this system.

In situ encapsulated and well dispersed Co3O4 nanoparticles as efficient and stable electrocatalysts for high-performance CO2 reduction

2020 ◽  
Vol 8 (31) ◽  
pp. 15675-15680 ◽  
Author(s):  
Hengpan Yang ◽  
Xinyao Yu ◽  
Jie Shao ◽  
Jingxuan Liao ◽  
Guodong Li ◽  
...  
Keyword(s):  
High Performance ◽  
Co2 Reduction ◽  
Co3o4 Nanoparticles

A space-confined Co/CNT catalyst was utilized for CO2 electroreduction with excellent efficiency and stability.

scholarly journals Preparation and Performance of Cerium-Based Catalysts for Selective Catalytic Reduction of Nitrogen Oxides: A Critical Review

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 361
Author(s):  
Ming Cai ◽  
Xue Bian ◽  
Feng Xie ◽  
Wenyuan Wu ◽  
Peng Cen
Keyword(s):  
Nitrogen Oxides ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Surface Acidity ◽  
Catalytic Performance ◽  
Synthesis Methods ◽  
Preparation Methods ◽  
Nh3 Scr ◽  
Nox Control ◽  
And Performance

Selective catalytic reduction of nitrogen oxides with NH3 (NH3-SCR) is still the most commonly used control technology for nitrogen oxides emission. Specifically, the application of rare earth materials has become more and more extensive. CeO2 was widely developed in NH3-SCR reaction due to its good redox performance, proper surface acidity and abundant resource reserves. Therefore, a large number of papers in the literature have described the research of cerium-based catalysts. This review critically summarized the development of the different components of cerium-based catalysts, and characterized the preparation methods, the catalytic performance and reaction mechanisms of the cerium-based catalysts for NH3-SCR. The purpose of this review is to highlight: (1) the modification effect of the various metal elements for cerium-based catalysts; (2) various synthesis methods of the cerium-based catalysts; and (3) the physicochemical properties of the various catalysts and clarify their relations to catalytic performances, particularly in the presence of SO2 and H2O. Finally, we hope that this work can give timely technical guidance and valuable insights for the applications of NH3-SCR in the field of NOx control.

High-performance polyimide nanofiber membranes prepared by electrospinning

2018 ◽  
Vol 31 (4) ◽  
pp. 438-448 ◽  
Author(s):  
Bo Yi ◽  
Yuntao Zhao ◽  
Enling Tian ◽  
Jing Li ◽  
Yiwei Ren
Keyword(s):  
Mechanical Properties ◽  
High Performance ◽  
Decomposition Temperature ◽  
Filtration Efficiency ◽  
Gas Filtration ◽  
Promising Candidate ◽  
Initial Decomposition Temperature ◽  
Hot Gas ◽  
Filtration Performance ◽  
Nanofiber Membranes

Polyimide (PI) nanofiber membranes were successfully prepared from a PI/N-methyl-2-pyrrolidone (NMP) solution via electrospinning. This technique simply and facilely produced efficient high-performance PI fibers. The morphology, surface wettability, thermal stability, mechanical properties, and filtration performance of the as-prepared PI nanofiber membranes were characterized in detail. The membranes exhibited smooth and hydrophobic surfaces. The nanofibers were well distributed in the membranes with fiber diameters in the range of 140–400 nm. All the PI nanofiber membranes showed excellent thermostability, and their initial decomposition temperature ( Td) and heat resistance temperature ( THRI) exceeded 544.4°C and 198.8°C, respectively. The PI nanofiber membranes also possessed reasonable mechanical properties with a tensile strength and a Young’s modulus reaching 10.5 and 927.6 MPa, respectively. Regarding the filtration performance, the developed nanofiber membranes achieved the best filtration efficiency of 90.4%. Such electrospun PI nanofiber membranes can be a promising candidate for hot gas filtration.

Co3O4 nanoparticles grown on N-doped Vulcan carbon as a scalable bifunctional electrocatalyst for rechargeable zinc–air batteries

RSC Advances ◽  
2015 ◽  
Vol 5 (92) ◽  
pp. 75773-75780 ◽  
Author(s):  
Tao An ◽  
Xiaoming Ge ◽  
T. S. Andy Hor ◽  
F. W. Thomas Goh ◽  
Dongsheng Geng ◽  
...  
Keyword(s):  
High Performance ◽  
Bifunctional Catalysts ◽  
Co3o4 Nanoparticles ◽  
Bifunctional Electrocatalyst ◽  
Vulcan Carbon ◽  
Zinc Air Batteries

Balancing the loading of in situ grown Co3O4 nanoparticles with the N-doped Vulcan carbon underneath is essential to produce scalable high-performance bifunctional catalysts of Co3O4/NVC for rechargeable Zn–air batteries.

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