scholarly journals Polycyclic aromatic hydrocarbons and pesticides in soil of Vojvodina

2004 ◽  
pp. 93-100 ◽  
Author(s):  
Mira Pucarevic ◽  
Petar Sekulic

The paper deals with several groups of compounds that represent the most frequent pollutants of soil in the world. The paper also reviews results of long-term studies conducted at the Institute of Field and Vegetable Crops in Novi Sad on the residues of pesticides and polycyclic aromatic hydrocarbons (PAHs) in the soil of the Vojvodina Province. The analyzed samples have been found to contain residues of persistent pesticides and their metabolites lindane and its metabolites 6,20 ?g/kg, alachlor 3,56 ?g/kg, aldrin 2,3 ?g/kg, heptachlor epoxide 0,99 ?g/kg, chlordane 3,82 ?g/kg, DDT and its metabolites 10,77 ?g/kg, dieldrin 2,04 ?g/kg, endrin 3,57 ?g/kg and endrin aldehyde 1,36 ?g/kg. Soil samples from Novi Sad municipality contained 53,69 ?g/kg of DDT and its metabolites. The values of atrazine ranged from 0,0005 to 0,8 mg/kg. The values of PAHs were 6,64 mg/kg in industrial soil, 4,93 mg/kg in agricultural soil, and 4,55 mg/kg and 5,48 mg/kg in the Novi Sad municipality. The lowest value, 0.83 mg/kg, was found for nonagricultural/nonindustrial soils.

Chemosphere ◽  
2018 ◽  
Vol 200 ◽  
pp. 641-648 ◽  
Author(s):  
Michele Fabri de Resende ◽  
Taila Figueredo Brasil ◽  
Beata Emoke Madari ◽  
Annibal Duarte Pereira Netto ◽  
Etelvino Henrique Novotny

2019 ◽  
Vol 16 (7) ◽  
pp. 517
Author(s):  
Flavia De Nicola ◽  
Estefanía Concha-Graña ◽  
Enrica Picariello ◽  
Valeria Memoli ◽  
Giulia Maisto ◽  
...  

Environmental contextPolycyclic aromatic hydrocarbons (PAHs) are widespread organic pollutants that tend to accumulate in soil. We developed an environmentally friendly analytical method for PAHs to evaluate human health risks associated with their presence in soils. The method is feasible for the analysis of soils with widely varying PAH contamination levels, and is well suited to environmental monitoring studies of relevance to human health. AbstractA microwave-assisted extraction, with a dispersive solid-phase purification step followed by programmed temperature vaporisation–gas chromatography–tandem mass spectrometry, is proposed as an environmentally friendly, simple and cheap analytical method for polycyclic aromatic hydrocarbons (PAHs) in soil. Different extraction and clean-up operating variables were tested to achieve satisfactory analytical performances: trueness from 92 to 114%, limit of quantification (LOQ) from 0.4 to 2µgkg−1 for most PAHs and intermediate precision, calculated as relative standard deviation (RSD), below 10%. The method was validated using both Certified Reference Material and real soil samples collected at sites subjected to different human activities. PAH contents ranged from 0.11 (in holm oak forest soil) to 1mgkg−1 d.w. (in an industrial soil) according to the anthropic gradient. The soil PAH contents measured were used to estimate the risk to human health, which suggested the exposure to the PAHs in soil as a potential risk for human health, especially at the industrial site. The feasibility of the method for soils with different PAH contamination degrees makes it relevant in monitoring programs.


2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Sara Näslund Andréasson ◽  
Haile Mahteme ◽  
Bo Sahlberg ◽  
Helena Anundi

Objective. This study identified and quantified polycyclic aromatic hydrocarbons (PAHs) in electrocautery smoke during 40 peritonectomy procedures and investigated any correlations and/or differences between levels of PAHs and perioperative variables.Methods. PAHs were measured in personal and stationary sampling by 40 mm Millipore cassettes, for adsorption of both gaseous and particle-bound PAHs.Results. All 16 USEPA priority pollutant PAHs were detected during peritonectomy procedures, naphthalene being the most abundant. For the only two PAHs with Swedish occupational exposure limits (OELs), benzo[a]pyrene and naphthalene, limits were never exceeded. Amount of bleeding was the only perioperative variable that correlated with levels of PAHs.Conclusions. Low levels of PAHs were detected in electrocautery smoke during peritonectomy procedures, and an increased amount of bleeding correlated with higher levels of PAHs. For evaluation of long-term health effects, more studies are needed.


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