scholarly journals Interfacial Reaction Between Cast Steel and Olivine Sand or Silica Sand

Author(s):  
Koji TANI ◽  
Yoshisada UEDA ◽  
Shohei MORI
2013 ◽  
Vol 58 (3) ◽  
pp. 853-857
Author(s):  
M. Holtzer ◽  
A. Bobrowski ◽  
D. Drożyński ◽  
J. Mocek

Abstract High-manganese cast steels are characterised by a high abrasion resistance under friction conditions with a simultaneous influence of pressure and impacts. This cast steel is especially suitable for castings of excavator’s scoops, track links, streetcars crossovers, parts of crushers and mills for braking up of hard materials [1-4]. In order to obtain high quality castings of high-manganese cast steels in moulds on the high-silica sand matrices it is necessary to apply protective coatings, which prevent a direct contact between metal and matrix (SiO2). Manganese after being poured into a mould can undergo a partial oxidation forming MnO, which reacts with silica. As a result low-melting manganese silicates are formed, which in a form of a tight layer adhere to the casting surface, significantly increasing a labour input related to cleaning. Three kinds of protective coatings were tested: zirconium, corundum and magnesite. As a base moulding sands on high-silica sand matrices with three kinds of resol resins were applied. The quality of the obtained casting surface was assessed in dependence of the protective coating and resin kind and also in dependence of the metallostatic pressure value.


2013 ◽  
Vol 13 (1) ◽  
pp. 39-44 ◽  
Author(s):  
M. Holtzer ◽  
A. Bobrowski ◽  
D. Drożyński ◽  
J. Mocek

Abstract When cast steel castings are made in moulding sands on matrices of high-silica sand, which has a low fire resistance the problem of the so-called chemical penetration is distinctly visible. Whereas this effect appears to a small degree only when moulding sand matrices are of chromite, zircon or olivine sands. Therefore in case of making castings of high-manganese cast steel (e.g. Hadfield steel) sands not containing free silica should be applied (e.g. olivine sand) or in case of a high-silica matrix protective coatings for moulds and cores should be used. Two protective coatings, magnesite alcoholic (marked as coating 1 and coating 2) originated from different producers and intended for moulds for castings of the Hadfield steel, were selected for investigations. Examinations of the basic properties were performed for these coatings: viscosity, thermal analysis, sedimentation properties, wear resistance. In order to estimate the effectiveness of protective coatings the experimental castings were prepared. When applying coating 1, the surface quality of the casting was worse and traces of interaction between the casting material (cast steel) and the coating were seen. When protective coating 2 was used none interactions were seen and the surface quality was better.


Author(s):  
Richard S. Thomas ◽  
Prabir K. Basu ◽  
Francis T. Jones

Silicon tetrachloride, used in industry for the production of highest purity silicon and silica, is customarily manufactured from silica-sand and charcoal.SiCl4 can also be made from rice hulls, which contain up to 20 percent silica and only traces of other mineral matter. Hulls, after carbonization, actually prove superior as a starting material since they react at lower temperature. This use of rice hulls may offer a new, profitable solution for a rice mill byproduct disposal problem.In studies of the reaction kinetics with carbonized hulls, conversion of SiO2 to SiCl4 was found to proceed within a few minutes to a constant, limited yield which depended reproducibly on the ambient temperature of the reactor. See Fig. 1. This suggested that physical or chemical heterogeneity of the silica in the hull structure might be involved.


Author(s):  
Jiang Xishan

This paper reports the growth step pattern and morphology at equilibrium and growth states of (Mn,Fe)S single crystal on the wall of micro-voids in ZG25 cast steel by using scanning electron microscope. Seldom report was presented on the growth morphology and steppattern of (Mn,Fe)S single crystal.Fig.1 shows the front half of the polyhedron of(Mn,Fe)S single crystal,its central area being the square crystal plane,the two pairs of hexagons symmetrically located in the high and low, the left and right with a certain, angle to the square crystal plane.According to the symmetrical relationship of crystal, it was defined that the (Mn,Fe)S single crystal at equilibrium state is tetrakaidecahedron consisted of eight hexagonal crystal planes and six square crystal planes. The macroscopic symmetry elements of the tetrakaidecahedron correpond to Oh—n3m symmetry class of fcc structure,in which the hexagonal crystal planes are the { 111 } crystal planes group,square crystal plaits are the { 100 } crystal planes group. This new discovery of the (Mn,Fe)S single crystal provides a typical example of the point group of Oh—n3m.


1986 ◽  
Vol 84 ◽  
Author(s):  
M.D. Merz ◽  
F. Gerber ◽  
R. Wang

AbstractThe Materials Characterization Center (MCC) at Pacific Northwest Lab- oratory is performing three kinds of corrosion tests for the Basalt Waste Isolation Project (BWIP) to establish the interlaboratory reproducibility and uncertainty of corrosion rates of container materials for high-level nuclear waste. The three types of corrosion tests were selected to address two distinct conditions that are expected in a repository constructed in basalt. An air/steam test is designed to address corrosion during the operational period and static pressure vessel and flowby tests are designed to address corrosion under conditions that bound the condi ring the post-closure period of the repository.The results of tests at reference testing conditions, which were defined to facilitate interlaboratory comparison of data, are presented. Data are reported for the BWIP/MCC-105.5 Air/Steam Test, BWIP/MCC-105.1 Static Pressure Vessel, and BWIP/MC-105.4 Flowby Test. In those cases where data are available from a second laboratory, a statistical analysis of interlaboratory results is reported and expected confidence intervals for mean corrosion rates are given. Other statistical treatment of data include analyses of the effects of vessel-to-vessel variations, test capsule variations for the flowby test, and oven-to-oven variations for air/steam tests.


Author(s):  
W. Bussiere ◽  
D. Rochette ◽  
T. Latchimy ◽  
G. Velleaud ◽  
P. Andre
Keyword(s):  

1990 ◽  
Vol 45 (2) ◽  
pp. 231-244 ◽  
Author(s):  
H. A. Nasr-El-Din ◽  
K. C. Khulbe ◽  
V. Hornof ◽  
G. H. Neale

Alloy Digest ◽  
1965 ◽  
Vol 14 (5) ◽  

Abstract BOFORS 2RM2 is a hardenable stainless cast steel having good weldability, high mechanical strength and improved corrosion resistance. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness. It also includes information on low temperature performance and corrosion resistance as well as casting, forming, heat treating, machining, and joining. Filing Code: SS-169. Producer or source: Aktiebolaget Bofors.


Alloy Digest ◽  
1976 ◽  
Vol 25 (10) ◽  

Abstract Alloy Steel 1.8 Cu-1.0 Mn-1.2 Si is a low-carbon (0.20% max.) cast steel designed to provide intermediate tensile and yield strength. Copper lowers the ductility and toughness of cast steel but, for a given increase in tensile strength, the loss of ductility and toughness is less if copper is added than if carbon is increased. This steel has many uses such as booms, long shafting and gears. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on corrosion resistance as well as casting, heat treating, machining, and joining. Filing Code: SA-325. Producer or source: Alloy steel mills and foundries.


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