scholarly journals Synthesis Emission Spectra of (LIPS) Technique for Cu, Ag Nanoparticles and their Antibacterial Activity

2021 ◽  
Vol 32 (3) ◽  
pp. 49
Author(s):  
Hadeel K. Nasif ◽  
Baida M. Ahmed ◽  
Kadhim A. Aadim

A spectroscope presents the optical emission spectroscopy (OES) technique on laser-produced copper and silver plasmas. The optical emission spectrum technique was used to analyzes the spectrum arising from the Cu, Ag Laser Nd: YAG plasmas with a wavelength of (1064) nm, a span of (10) ns, and a focal length of (10) cm in the energy range (300-800) mJ. The electron temperature (Te) was determined while the Saha-Boltzmann equation was used to measure the electron density (ne). Other plasma parameters, (λD), (fp), (ND), were also measured. For various energies, the plasma spectrum was registered copper and silver. Q-switched Nd: YAG liquid laser ablation technique (PLAL) was used to produce nanoparticles (NPs), silver, and copper particles using distilled water at room temperature at different energies (300-600-800) mJ. With a constant wavelength (1064nm). At a constant frequency (6Hz), 300 laser pulses were used to ablate the target placed in distilled water to study the effect of these materials in inhibiting bacteria. Bacteria were used (Staphylococcus). This study showed that (Ag-NPs) and (Cu-NPs) that are synthesized by laser ablation have a great effect on Staphylococcus (antibiotic-resistant) bacteria.

2020 ◽  
pp. 1665-1671
Author(s):  
Madyan A. Khalaf ◽  
Baida M. Ahmed ◽  
Kadhim A. Aadim

In this work, the optical emission spectrum technique was used to analyze the spectrum resulting from the CdO:Sn plasma produced by laser Nd:YAG with a wavelength of (1064) nm, duration of (9) ns, and a focal length of (10) cm in the range of energy of 500-800 mJ. The electron temperature (Te) was calculated using the in ratio line intensities method, while the electron density (ne) was calculated using Saha-Boltzmann equation. Also, other plasma parameters were calculated, such as plasma (fp), Debye length (λD) and Debye number (ND). At mixing ratios of X=0.1, 0.3 and 0.5, the CdO1-X :SnX plasma spectrum was recorded for different energies. The changes in electron temperature and the densities were studied as a function of the laser energies. Outcome measure value of the electron temperature at the ratio of  X = 0.1 was (1.079-1.054) eV, while at  X=0.3 the Te range was (0.952- 0.921) eV and at X=0.5 it was (0.928-0.906) eV.


2021 ◽  
pp. 2948-2955
Author(s):  
Maryam M. Shehab ◽  
Kadhim A. Aadim

      In this paper, the optical emission spectrum (OES) technique was used to analyze the spectrum resulting from the (CdO:CoO)  plasma in air, produced by Nd:YAG laser with λ=1064 nm, τ=10 ns, a focal length of 10 cm, and a range of energy of 200-500 mJ. We identified laser-induced plasma parameters such as electron temperature (Te) using Boltzmann plot method, density of electron (ne), length of Debye (λD), frequency of plasma (fp), and number of Debye (ND), using two-Line-Ratio method. At a mixing ratio of X= 0.5, the (CdO:CoO) plasma spectrum was recorded for different energies. The results of plasma parameters caused by laser showed that, with the increase in laser energy, the values of Te, ne and fp were increased, while the value of λD was decreased. The calculated electron temperature value was in the range of 0.449-0.619 eV at ratio X=0.5


2021 ◽  
Author(s):  
Lorenzo Pino ◽  
Matteo Brogi ◽  
Jean-Michel Désert ◽  
Emily Rauscher

<p>Ultra-hot Jupiters (UHJs; T<sub>eq</sub> ≥ 2500 K) are the hottest gaseous giants known. They emerged as ideal laboratories to test theories of atmospheric structure and its link to planet formation. Indeed, because of their high temperatures, (1) they likely host atmospheres in chemical equilibrium and (2) clouds do not form in their day-side. Their continuum, which can be measured with space-facilities, can be mostly attributed to H- opacity, an indicator of metallicity. From the ground, the high spectral resolution emission spectra of UHJs contains thousands of lines of refractory (Fe, Ti, TiO, …) and volatile species (OH, CO, …), whose combined atmospheric abundances could track planet formation history in a unique way. In this talk, we take a deeper look to the optical emission spectrum of KELT-9b covering planetary phases 0.25 - 0.75 (i.e. between secondary eclipse and quadrature), and search for the effect of atmospheric dynamics and three-dimensionality of the planet atmosphere on the resolved line profiles, in the context of a consolidated statistical framework. We discuss the suitability of the traditionally adopted 1D models to interprete phase-resolved observations of ultra-hot Jupiters, and the potential of this kind of observations to probe their 3D atmospheric structure and dynamics. Ultimately, understanding which factors affect the line-shape in UHJs will also lead to more accurate and more precise abundance measurements, opening a new window on exoplanet formation and evolution.</p>


1988 ◽  
Vol 117 ◽  
Author(s):  
Kenji Ebihara ◽  
Seiji Kanazawa ◽  
Sadao Maeda

AbstractProcessing plasmas generated by three types of discharges are diagnosed spectroscopically in order to estimate the quantitative relationship between plasma parameters and electrical and optical properties of deposited materials. An rf discharge is capacitively produced by a 13.56 MHz rf oscillator. A microwave generator operating at 2.45 GHz is used to supply power to a discharge cavity. Further a pulsed plasma which is inductively generated by pulsed current ( 70 kA peak ) is applied to study dissociation process in the transient plasma and possibility of a novel processing system. The gases used are methane for amorphous carbon formation and silane for amorphous silicon deposition. Measurements of optical emission spectrum are performed to estimate the processing plasma state by the relative spectral intensity method and the Doppler-broadening method.


2021 ◽  
pp. 2565-2570
Author(s):  
Neean F. Majeed ◽  
Maysaa R. Naeemah ◽  
Alyaa H. Ali ◽  
Sabah N. Mazhir

     In the current study, the emission spectra generated from clove were measured under normal atmospheric pressure with different laser energies. Clove is used as a source of essential oil in herbal medicine, in particular as a dynamic analgesic oil in dental and other diseases. For aromatherapy, Antiseptic, antiviral, and antimicrobial agents are also packaged with cloves. Compounds that reduce inflammation tend to battle sore throats, cold, and cough as they display so many advantages. The measured spectrum reveals distinctive lines of clove’s chemical elements. X-ray fluorescent (XRF) and atomic absorption spectrometry (AAS) were used to measure the spectrum generated or absorbed by detecting the presence of various elements and their ratios in the cloves, for different energy the electron temperature varies between 0.043 and 0.073 eV and the number of electron varied between 2.074 and 2.287) x1014 cm-3 for clove.


2020 ◽  
pp. 110-113

In this research the diagnostic of optical emission spectroscopy from exploding copper wires have done for different current. By using Boltzman plot can be calculated the plasma electron temperature , and by using Stark broadening can be evaluated the electron density for different current of (75, 100 and 150)A with diameter 0.25 mm in deionized water. It was observed that the electron density decrease with an increasing the current from 75 A to 150 A while the electron temperatures increase for the same current. The plasma has a peak 652 nm corresponding to Hα line for .hydrogen .atoms which obtained from .optical emission spectrum (OES), the peaks belong to atomic copper lines. The plasma electron temperature related with emission line intensity and number .density with the formed copper nanoparticles size was studied.


2018 ◽  
Vol 15 (35) ◽  
pp. 142-147
Author(s):  
Hammad R. Humud

This work aims to study the exploding copper wire plasma parameters by optical emission spectroscopy. The emission spectra of the copper plasma have been recorded and analyzed The plasma electron temperature (Te), was calculated by Boltzmann plot, and the electron density (ne) calculated by using Stark broadening method for different copper wire diameter (0.18, 0.24 and 0.3 mm) and currentof 75A in distilled water. The hydrogen (Hα line) 656.279 nm was used to calculate the electron density for different wire diameters by Stark broadening. It was found that the electron density ne decrease from 22.4×1016 cm-3 to 17×1016 cm-3 with increasing wire diameter from 0.18 mm to 0.3 mm while the electron temperatures increase from 0.741 to 0.897 eV for the same wire diameters. The optical emission spectrum (OES) emitted from the plasma have Hα line, small peak at 590 nm corresponding to sodium and others peaks belong to Cu I. The relationship between the plasma electron temperature, emission line intensity and number density with the formed copper nanoparticles size and concentration were studied. It was found that the nanoparticles concentration increase with emission line intensity while its size decrease. It can be conclude the existence of a controlled relationship between the plasma parameters and the formed nanoparticles concentration and size.


2006 ◽  
Vol 24 (2) ◽  
pp. 311-320 ◽  
Author(s):  
RAJ K. THAREJA ◽  
A.K. SHARMA

We report on the pulsed laser ablation of aluminum (Al) plasma in presence of ambient nitrogen to understand the formation of aluminum nitride (AlN). Formation of carbon nitride (CN) and titanium oxide (TiO) by pulsed laser-ablation of graphite and titanium targets in presence of ambient nitrogen and oxygen is also compared. We discuss the dynamics of plasma expansion based on existing models, shock and drag models, and the plasma gas interface distortion, Rayleigh-Taylor instability at various ambient pressures of nitrogen. Since Rayleigh-Taylor instability may give rise to self-generated magnetic field in the plasma, an attempt is made to understand the mechanism of generation as well as the estimation of this field near the focal spot using the information from the images of the expanding plasma. This is the first time images of the expanding plume are used to estimate self generated magnetic fields. At the irradiance level used in the experiment the field is high very close to the target surface therefore we expect splitting of the energy levels thus giving rise to emissions that may be anisotropic in nature. We discuss the extent of anisotropy by measuring the degree of polarization using emission intensity in optical emission spectrum of selected Al III transition 4s2S1/2–4p2P3/2oat 569.6 nm using both nanosecond and picosecond pulses.


2021 ◽  
Vol 03 (02) ◽  
pp. 52-61
Author(s):  
Hadeel K. NASIF ◽  
Kadhim A. AADIM ◽  
Baida M. AHMED

this article a spectroscopic research on laser-produced Tin and Zinc plasmas using the optical emission spectroscopy (OES) technique. Plasmas can be produced from a solid tin and zinc targets irradiated with a pulsed laser in room environments. The spectrum is recorded for the Sn, Zn laser plasma Nd: YAG with a wavelength of (1064) nm, a duration of (9) ns, and a frequency of (6) Hz and a focal length of (10) cm within the energy range (300-800)mj. By using the ratio line strength formula, the electron temperature (Te) can be calculated and the result is for Zinc (Zn) plasma (2.11 ev) and tin (Sn) plasma (1,227 ev). The Saha-Boltzmann equation will be used to calculate electron density (ne) in this method and the values for zinc (Zn) (3.3 cm-3)and tin (Sn) (2.1 cm-3). The plasma parameters, such as plasma (fp), Debye duration (λD), and Debye number (ND), were calculated in the proposed document.


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