scholarly journals Release of nonexchangeable potassium from Finnish mineral soils

1967 ◽  
Vol 39 (2) ◽  
pp. 107-118
Author(s):  
Armi Kaila
Keyword(s):  
Clay Content ◽  
Clay Soils ◽  
Silty Clay ◽  
Clay Loam ◽  
Exchangeable Potassium ◽  
Surface Samples ◽  
Heavy Clay ◽  
The Mean ◽  
Mineral Soils ◽  
Nonexchangeable Potassium

Release of nonexchangeable potassium by treatment with 1 N HCI at 50°C was studied on basis of a material consisting of 330 samples of Finnish mineral soils. The results ranged from 1 to 830mg K/100g. The mean content of nonexchangeable acid-soluble potassium was in the surface samples of sand and fine sand soils 95±26 mg/100 g, in loam soils 165±31 mg/100 g, in silt soils 195±52 mg/100 g, in clay loam soils 258±32 mg/100 g, in silty clay soils 283±43 mg/100 g, and in heavy clay soils 345±126 mg/100 g. In the subsoil samples of loam, clay loam, silty clay and heavy clay soils the mean content was significantly higher than in the surface samples, or 283±51 mg/100 g, 404±56 mg/100 g, 535±53 mg/100 g, and 580±37 mg/100 g, respectively. The results seem to be high as compared with data reported from Sweden, Norway and Germany. The content of nonexchangeable potassium released by acid was to some extent connected with the clay content: the correlation coefficient in the whole material was r = 0.74***, but only about 0.5*** both in the separate groups of the 178 nonclay samples and the 152 clay samples. There was only a very low correlation between the contents of nonexchangeable acid-soluble potassium and readily exchangeable potassium. A somewhat higher correlation, r = 0.65***, was found for the relationship between the former and fixation of added potassium under »wet» conditions, but it was markedly decreased by the elimination of the effect of the clay content. Nonexchangeable acid-soluble potassium usually represented a lower part of the total potassium in the surface samples than in the subsoil samples, and also the proportion tended to be higher in the clay soils than in the coarser soils. It varied from 0.2 to 26.3 per cent in the small material studied. In most cultivated soils less nonexchangeable potassium was released from the samples of plough layer than from samples of deeper layers. In a podsol profile the minimum content of nonexchangeable and exchangeable potassium and the maximum of fixation of added potassium was found in the A2 horizon; in a brown podsolic soil all these test values decreased fairly regularly with depth. From some silt and silty clay soils incubated for three months at room temperature a large part, even more than 40 per cent of the added potassium was not recovered by the acid extraction. Ammonium acetate extracted from 9 to 85 per cent of the potassium applied before incubation, and the part of added potassium found as nonexchangeable acid-soluble form varied from 5 to 53 per cent. The equilibrium between the different potassium fractions in soil was discussed. It was supposed that differences in the ability of plants to utilize nonexchangeable potassium may partly depend on the level to which plant roots are able to decrease potassium concentration in the solution around the minerals.

scholarly journals Fixation of potassium in Finnish soils

1965 ◽  
Vol 37 (2) ◽  
pp. 116-126
Author(s):  
Armi Kaila
Keyword(s):  
Ammonium Acetate ◽  
Clay Soil ◽  
Silty Clay ◽  
Clay Loam ◽  
Surface Soils ◽  
Mean Values ◽  
Surface Samples ◽  
Sandy Clay ◽  
Heavy Clay ◽  
The Mean

The fixation of potassium in Finnish soils was studied on the basis of a material consisting of 265 samples from various parts of the country. A »wet method» was employed in which 2.5 me K was added per 100 g soil, and the fixation against the extraction with neutral N ammonium acetate was determined after a period of contact of one hour. The average fixation in the 135 samples of surface soils was 0.38 ± 0.03 me K/100 g soil, and in the 130 subsoil samples 0.77 ± 0.09 me/100 g soil, or about 15 and 30 per cent of the added potassium, respectively. In the groups of the surface samples the mean values increased with the increasing content of clay from 0.25 ± 0.04 me K/100 g soil in the finesand soils to 0.56 ± 0.03 me K/100 g soil in the samples of heavy clay containing at least 60 per cent of the fraction < 2 μ. In the groups of the subsoil samples the corresponding mean values were 0.33 ± 0.24 and 1.04 ± 0.15 me K/100 g soil. In the surface soils the results ranged from 0.09 me K/100 g in a finesand soil to 1.27 me K/100 g in a clay loam, and in the subsoil samples from 0 in a sandy clay soil to 1.80 me K/100 g in one sample of clay loam and one sample of silty clay. The fixation was positively correlated with the contents of finer clay

scholarly journals Basic exchangeable cations in Finnish mineral soils

1972 ◽  
Vol 44 (3) ◽  
pp. 164-170
Author(s):  
Armi Kaila
Keyword(s):  
Clay Content ◽  
Fine Sand ◽  
Degree Of Saturation ◽  
Clay Soils ◽  
Exchangeable Ca ◽  
Significant Difference ◽  
Heavy Clay ◽  
The Mean ◽  
Mineral Soils ◽  
Plough Layer

The content of exchangeable Ca, Mg, K and Na replaced by neutral ammonium acetate was determined in 470 samples of mineral soils from various parts of Finland, except from Lapland. The amount of all these cations tended to increase with an increase in the clay content, but variation within each textural class was large, and the ranges usually overlapped those of the other classes. The higher acidity of virgin surface soils was connected with a lower average degree of saturation by Ca as compared with the corresponding textural classes of cultivated soils. No significant difference in the respective contents of other cations was detected. The samples of various textural groups from deeper layers were usually poorer in exchangeable Ca and K than the corresponding groups of plough layer. The mean content of exchangeable Mg was equal or even higher in the samples from deeper layers than in the samples from plough layer, except in the group of sand soils. The percentage of Mg of the effective CEC increased, as an average, from 9 in the sand and fine sand soils of plough layer to 30 in the heavy clay soils; in the heavy clay soils from deeper layers its mean value was 38 ± 4 %. In the samples of plough layer, the mean ratio of Ca to Mg in sand and fine sand soils was about 9, in silt and loam soils about 6, in the coarser clay soils about 4, and in heavy clay about 2.

scholarly journals Calcium, magnesium and potassium in mineral soils from the southern half of Finland

1973 ◽  
Vol 45 (3) ◽  
pp. 254-261
Author(s):  
Armi Kaila
Keyword(s):  
Clay Content ◽  
Total Content ◽  
Fine Sand ◽  
Clay Soils ◽  
Surface Layers ◽  
Surface Soils ◽  
Exchangeable Ca ◽  
Heavy Clay ◽  
Southern Half ◽  
Mineral Soils

210 samples of mineral soils from the southern half of Finland with mainly an acid precambrian bedrock, were analysed for the total contents of Ca, Mg and K, and for the portion of these nutrients which could be exchanged by N NH4OAc (pH 7), dissolved by 0.1 N HCI at room temperature, or released by N HCI at 50° C. The total content of Ca was lowest in samples of heavy clay, 0.78±0.14 % in the surface soils and 0.92±0.10 % in the deeper layers. The mean content in the groups of other soils was at least about 1.1 %. The total content of Mg increased with an increase in the clay content (r = 0.81***). It ranged from 0.6±0.1 % in the sand and fine sand samples to 1.53±0.19 % in the heavy clay soils of the surface layers and to 1.89±0.12 % in those of the deeper layers. Also in the groups of loam and silt soils and of the coarser clay soils, respectively, the Mg content was in the deeper layers higher than in the surface soils. The total content of K also increased with the clay content (r=0.73***) from 1.7±0.1 % in the sand and fine sand soils to 2.74±0.21 % in the heavy clay soils of the surface layers and to 3.10±0.07 % in those of the deeper layers. The portion of exchangeable Ca was relatively high: in the groups of surface soils from more than one tenth to one third of the total amount. The corresponding average amounts released by even the more drastic treatment with acid were not markedly higher. Only a few per cents of total Mg were exchangeable and slightly higher amounts were dissolved by 0.1 N HCI, whereas the treatment with N HCI at 50° C released about half of the total Mg. Exchangeable K and K dissolved by 0,1 N HCI did not exceed 1 % of the total K, except slightly in the heavy clay soils; the average amounts released by N HCI ranged from 5 to 18 % of the total K. The plant availability of these nutrients was discussed.

scholarly journals Effective cation-exchange capacity in Finnish mineral soils

1971 ◽  
Vol 43 (3) ◽  
pp. 178-186
Author(s):  
Armi Kaila
Keyword(s):  
Soil Ph ◽  
Mineral Soil ◽  
Sandy Soils ◽  
Clay Content ◽  
Clay Soils ◽  
Partial Regression Coefficient ◽  
Organic C ◽  
Mean Values ◽  
Surface Samples ◽  
The Mean

Effective CEC of 230 mineral soil samples was estimated as sum of (Ca + Mg) and (AI + H) displaced by N KCI. The mean values as me/100 g of soil were, in the surface samples, 15.9 ± 2.0 in 46 clay soils, 8.9 ± 1.3 in 21 silt and loam soils, and 8.3 ± 1.1 in 39 sandy soils. In samples from the deeper layers the corresponding means were 16.3 ± 2.3 in 54 clay soils, 5.6 ± 0.9 in 21 silt and loam soils, and 2.5 ± 0.5 in 49 sandy soils. In surface samples of clay soils the mean effective CEC was about two thirds, in sandy soils of deeper layers about one third, and in all other groups about one half of the corresponding average potential CEC determined by neutral ammonium acetate. In the total material in which clay content ranged from 0 to 95%, organic C from 0.1 to 8.7 %, soil pH from 3.3 to 7.5, and oxalate soluble Al from 1.4 to 47.9 mmol/100 g, the »effective CEC» depended mostly on clay content: the partial correlation coefficient r = 0.90***, and the standard partial regression coefficient β = 0.84. The corresponding coefficients for the relationship between the »effective CEC» and the content of organic C were r = 0.55*** and β = 0.29, soil pH r = 0.35*** and β = 0.16, and oxalate soluble Al r = –0.13 and β = –0.06. The positive effect of liming on effective CEC, particularly, in coarser textured acid soils high in organic matter was emphasized.

scholarly journals Base-neutralizing capacity of Finnish mineral soils

1986 ◽  
Vol 58 (2) ◽  
pp. 43-46
Author(s):  
Helinä Hartikainen
Keyword(s):  
Soil Ph ◽  
Soil Acidity ◽  
Clay Content ◽  
Soil Samples ◽  
Clay Soils ◽  
Organic C ◽  
Neutralizing Capacity ◽  
Heavy Clay ◽  
Mineral Soils

The base-neutralizing capacity, BMC7 (OH- as meq kg-1 needed to raise soil pH to 7), was determined graphically from curves obtained in KOH titration (at a constant ionic strength of I = 0.1). In 84 soil samples, BMC7 amounted to 0—316 meq kg-1, being highest in the heavy clay soils and lowest in the non-clay soils. In different textural groups, BMC7 seemed most markedly to be dependent on the initial soil pH, followed by organic C or oxalate soluble Al, in the coarser clays also on clay content. The results evidence that in determination of lime requirement, attention should be paid to the capacity of soil acidity. In routine soil testing, detailed lime recommendations for various soil types are needed.

Influence of Various Soil Properties on the Adsorption and Desorption of ICIA-0051 in Five Soils

1992 ◽  
Vol 6 (3) ◽  
pp. 583-586 ◽  
Author(s):  
John S. Wilson ◽  
Chester L. Foy
Keyword(s):  
Sandy Loam ◽  
Clay Content ◽  
Silty Clay ◽  
Silt Loam ◽  
Clay Loam ◽  
Soil Factors ◽  
Silty Clay Loam ◽  
Freundlich Equation ◽  
General Order ◽  
Highly Correlated

The soil organic matter and/or humic matter fraction was highly correlated with the adsorption of ICIA-0051 herbicide onto five soils; clay content and other soil factors were less correlated. The Freundlich equation was used to describe the adsorption of ICIA-0051 by the various soils. Based on the K constants, the general order for adsorption for each soil was Hyde silty clay loam > Frederick silt loam > Davidson clay = Bojac sandy loam > Appling loamy sand. Across all soils, 25 to 50% of the amount adsorbed was removed by two desorptions. Appling, Bojac, and Davidson soils retained less herbicide after two desorptions than did Frederick and Hyde.

EXCHANGEABLE AND WATER-SOLUBLE POTASSIUM IN SOILS AND DEGREE OF SATURATION IN RELATION TO TOMATO YIELDS

1959 ◽  
Vol 39 (2) ◽  
pp. 129-135 ◽  
Author(s):  
R. L. Halstead ◽  
H. B. Heeney
Keyword(s):  
Sandy Loam ◽  
Clay Content ◽  
Field Trials ◽  
Water Soluble ◽  
Degree Of Saturation ◽  
Yield Response ◽  
Clay Loam ◽  
Exchangeable Potassium ◽  
Potassium Fertilizer ◽  
Prince Edward County

In 33 field trials on soils varying in texture from sandy loam to clay loam in Prince Edward County, Ontario, exchangeable potassium, per cent potassium saturation, and water-soluble potassium were significantly correlated with yield response of tomatoes to potassium fertilizer on the sandy loam soils, but there was no correlation within the loam and clay loam groups. The mean c1 value in the modified Mitscherlich equation relating exchangeable potassium to yield response within the sandy loam group was 0.00555 and the coefficient of variation was 19.8 per cent. The corresponding coefficients for c1 values based on per cent potassium saturation and water-soluble potassium were of greater magnitude. The amounts of potassium soluble in boiling 1 N HNO3 were not related to yield response.Exchangeable potassium and the non-exchangeable form soluble in boiling 1 N HNO3 increased, whereas water-soluble potassium decreased with increasing clay content of the samples. Water-soluble potassium was significantly correlated with per cent potassium saturation within the sandy loam and loam groups.

scholarly journals Fixation of potassium by soil samples under various conditions

1965 ◽  
Vol 37 (3) ◽  
pp. 195-206
Author(s):  
Armi Kaila
Keyword(s):  
Room Temperature ◽  
Ammonium Acetate ◽  
Clay Fraction ◽  
Soil Samples ◽  
Soil Reaction ◽  
Soil Drying ◽  
Exchangeable Potassium ◽  
Heavy Clay ◽  
Mineral Soils ◽  
Total Potassium

The fixation of added potassium under various conditions was studied using soil samples collected from three layers of ten mineral soils. The type of soil ranged from finesand to heavy clay, the soil reaction from pH 3.3 to pH 6.4 (in 0.01 M CaCl2), and the total potassium content from 1.99 to 3.41 per cent. The fixation against an extraction with neutral ammonium acetate distinctly depended on the conditions used for the application of potassium: on the average, without drying the samples fixed during one hour somewhat more than 80 per cent of the amount fixed during 18 hours, when the samples were treated with KCI-solutions corresponding to 2.5 me K/100 g soil. Drying the suspension at 80°C resulted in a fixation 1.2 to 4.1 times as high as that under the »wet» conditions within one hour. The results of these two methods were not particularly closely correlated (r = 0.73***). The results of the »dry» method were found to be of the same order as the fixation of potassium in samples incubated for three months at room temperature. The results of the »dry» fixation were positively correlated with the pH (r = 0.75***) and negatively correlated with the contents of organic carbon (r = —0.63***) and exchangeable potassium (r = —0.40*), but they were not correlated with the contents of clay or the acid soluble potassium. Under the »wet» conditions the relative fixation generally decreased with an increase in the application of potassium, but there were samples which fixed a rather low but almost equal portion of all the applications from 0.625 to 40 me K/100 g soil. The fixation from the highest addition was correlated with the clay fraction

scholarly journals Acid-neutralizing capacity of Finnish mineral soils

1985 ◽  
Vol 57 (4) ◽  
pp. 279-283
Author(s):  
Helinä Hartikainen
Keyword(s):  
Clay Soils ◽  
Acid Neutralizing Capacity ◽  
Significant Variable ◽  
Exchange Reactions ◽  
Organic C ◽  
Neutralizing Capacity ◽  
Heavy Clay ◽  
Mineral Soils ◽  
The Relationship ◽  
Soil Groups

The acid-neutralizing capacity (ANC) was determined graphically from curves obtained in HCI titration (at a constant ionic strength I = 0.1) and was expressed as a quantity of acid (meq kg-1) needed to reduce the soil pH to 3.8. The relationship between ANC3.8 g and soil characteristics was studied statistically. In 84 soil samples, ANC3.8 ranged from 12 to 184 meq kg-1. The average ANC3.8 was highest in the heavy clay soils and lowest in the non-clay soils, but the differences between the various textural soil groups were not significant. In all soil groups the initial pHCaCl2 was relatively the most important factor explaining the variation in ANC3.8. Organic C was also a significant variable; this was considered to indicate the importance of cation exchange reactions of organic matter in acid-buffering. With the exception of heavy clay soils, oxalate-soluble Al significantly explained the variation in ANC3.8, suggesting that dissolution of Al hydroxides acted as a sink for H+ ions and contributed to the neutralizing capacity at the reference pH of 3.8.

scholarly journals Measurements of Texture of Soils Formed from Glaciolimnic Sediments by Areometric Method, Pipette Method and Laser Diffraction Method

2014 ◽  
Vol 65 (2) ◽  
pp. 72-79 ◽  
Author(s):  
Mirosław Orzechowski ◽  
Sławomir Smó;lczyński ◽  
Jacek Długosz ◽  
Paweł Pozniak
Keyword(s):  
Clay Fraction ◽  
Diffraction Method ◽  
Laser Diffraction ◽  
Silt Loam ◽  
Strongly Correlated ◽  
Clay Loam ◽  
Fine Silt ◽  
North Eastern ◽  
Heavy Clay ◽  
The Mean

Abstract The aim of the research was to compare the results of texture analyses of glaciolimnic sediments deposited in the basins of ice-dammed lakes origin in north eastern Poland. The study was carried out using aerometric method, pipette method and laser diffraction method. The studied soils were classified as Haplic and Mollic Vertisol, Vertic Cambisol, and Gleyic Chernozem. The soils were formed from clayey (clay, heavy clay), loamy (loam, clay loam, sand clay loam) and silty (silt loam, clay loam) deposits. The studied soils did not contain fractions > 2.0 mm. The amounts of clay fraction (< 0.002 mm) measured by areometric and pipette methods were similar and strongly correlated. In comparison to laser diffraction method, these amounts were 3-4-fold higher. The sub-fraction of fine silt (0.02-0.002 mm) predominated in soil formations analyzed by laser diffraction method. In comparison to areometric or pipette method, the amounts of fine silt were 2-4 fold higher. Basing on the calculated sedimentological indices, it was stated that the examined soils were well sorted and the mean grain diameter (GSS) was very low and did not exceed 0.005 mm in areometric and pipette methods, and 0.011 mm in laser diffraction method for clay sediments.

Sign in / Sign up

Export Citation Format

Share Document