scholarly journals Growth and Characterization of an Organic Nonlinear Optical Crystal: 1-Iodo-3-Nitrobenzene (INB)

2016 ◽  
Vol 12 (9) ◽  
pp. 4364-4370
Author(s):  
S.Vijaya. Kumar ◽  
P. Srinivasan ◽  
S. Dinagaran ◽  
J. Balaji
Keyword(s):  
Nonlinear Optical ◽  
Grown Crystal ◽  
Visible Region ◽  
Dielectric Measurement ◽  
Cutoff Wavelength ◽  
X Ray Diffraction ◽  
Dsc Studies ◽  
Optical Applications ◽  
Nonlinear Optical Applications ◽  
Vicker’S Microhardness

The 1-Iodo-3-Nitrobenzene crystal was grown by the slow evaporation method from ethanol solvent. The crystalline structure was identified by powder X-ray diffraction (PXRD). The presence of various functional group of the title material was examined by FTIR analysis. The UV-Vis absorption was carried out which shows the fundamental cutoff wavelength around 390 nm and there is no absorption in the entire visible region 390 nm to 1100 nm. The mechanical strength of the grown crystal was measured by Vicker’s microhardness tester. The thermal toughness of the grown crystal was observed by TGA-DTA and DSC studies. The electrical conductivity of the grown crystal is confirmed by dielectric measurement. The nonlinear optical character was assessed by Kurtz-Perry powder technique. This would propose that 1-iodo-3-nitro benzene crystal is a potentially capable in nonlinear optical applications.

Synthesis, Growth and Optical Studies of Mn: α-LiIO3 Single Crystal

2012 ◽  
Vol 584 ◽  
pp. 3-7 ◽  
Author(s):  
R. Ashok Kumar ◽  
D. Rajan Babu ◽  
R. Ezhil Vizhi ◽  
N. Vijayan ◽  
G. Bhagavannarayana
Keyword(s):  
Single Crystal ◽  
Grown Crystal ◽  
Second Harmonic ◽  
Visible Region ◽  
X Ray Diffraction ◽  
X Ray ◽  
Optical Instruments ◽  
Optical Applications ◽  
Nonlinear Optical Applications ◽  
Mn Doped

Manganese doped alpha-lithium iodate have been synthesized and single crystals have been grown for nonlinear optical applications. The grown crystal has been subjected to single crystal X-ray diffraction to confirm the structure. The crystalline perfection was assessed by high-resolution X- ray diffractometer (HRXRD). Second harmonic generation (SHG) efficiency was found to be 71 times than that of KDP. The UV–Vis-NIR spectroscopic study revealed that the grown crystal has good optical transparency in the visible region clearly indicates that Mn doped α-LiIO3 crystals can be used as window material in optical instruments. Presence of dopant was confirmed by energy-dispersive spectrometry.

GROWTH AND CHARACTERIZATION OF GLYCINE HYDROBROMIDE SINGLE CRYSTAL FOR NONLINEAR OPTICAL APPLICATIONS

2008 ◽  
Vol 22 (21) ◽  
pp. 2035-2042 ◽  
Author(s):  
K. KIRUBAVATHI ◽  
K. SELVARAJU ◽  
N. VIJAYAN ◽  
S. KUMARARAMAN
Keyword(s):  
Single Crystal ◽  
Single Crystals ◽  
Nonlinear Optical ◽  
Grown Crystal ◽  
Visible Spectrum ◽  
Optical Quality ◽  
X Ray Diffraction ◽  
Optical Applications ◽  
Nonlinear Optical Applications

Single crystals of a new semi-organic nonlinear optical material glycine hydrobromide were grown from solution by slow evaporation at room temperature. Good optical quality single crystals with dimensions 17×8×5 mm3 were obtained. The grown crystal had been confirmed by single-crystal X-ray diffraction and the vibrational frequencies of various functional groups in the crystals had been derived from Fourier transform infrared spectrum. The optical quality of the grown crystals was analyzed by the Ultraviolet visible spectrum method. The mechanical behavior of the grown crystal was evaluated by Vickers' micro-hardness indentation method. The nonlinear optical property of the crystal was confirmed by the Kurtz powder technique using Nd : YAG laser as a source.

Growth and characterizations of L-methioninium picrate single crystal for nonlinear optical applications

2016 ◽  
Vol 25 (04) ◽  
pp. 1650052 ◽  
Author(s):  
A. Alexandar ◽  
P. Surendran ◽  
S. Sakthy Priya ◽  
A. Lakshmanan ◽  
P. Rameshkumar
Keyword(s):  
Single Crystal ◽  
Nonlinear Optical ◽  
Visible Region ◽  
Spectroscopic Properties ◽  
Optical Microscope ◽  
Solution Technique ◽  
X Ray Diffraction ◽  
Diamond Pyramid ◽  
Optical Applications ◽  
Nonlinear Optical Applications

An organic nonlinear optical (NLO) single crystal of L-methioninium picrate (LMP) has been grown by slow evaporation solution technique (SEST) at a constant temperature of [Formula: see text]C. Formation of nucleation and growth kinetics of the crystal were observed using an optical microscope for different durations and it was found that the shape of nucleation is similar to the grown large size single crystals of the same material. The characterization techniques such as powder X-ray diffraction (PXRD) analysis, UV–Vis NIR, Vickers microhardness, piezoelectric d[Formula: see text] coefficient, photoconductivity and etching studies have been performed. The crystal system and lattice parameters of the grown crystal were determined by PXRD analysis. The spectroscopic properties of the synthesized compound were confirmed by Fourier transform infrared (FTIR) analysis. The UV–Vis NIR analysis was performed on the grown single crystal to find the optical absorption in the entire visible region. Attempts have been made to investigate the mechanical properties of LMP crystal using Vickers diamond pyramid indenter. In addition piezoelectric, photoconductivity and etching studies were carried out to study the d[Formula: see text] coefficient, photoconducting nature and surface properties respectively.

scholarly journals Structural, Microhardness, Photoconductivity, and Dielectric Properties of Tris(thiourea) Cadmium Sulphate Single Crystals

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
A. P. Arthi ◽  
M. Sumithra Devi ◽  
K. Thamizharasan
Keyword(s):  
Single Crystals ◽  
Nonlinear Optical ◽  
Grown Crystal ◽  
Nonlinear Optical Property ◽  
X Ray Diffraction ◽  
Third Order ◽  
X Ray ◽  
Self Focusing ◽  
System Cell ◽  
Vicker’S Microhardness

Semiorganic nonlinear optical tris(thiourea) cadmium sulphate (TTCS) single crystals were grown by slow evaporation method. The crystal system, cell parameter of the grown crystal, was identified by powder X-ray diffraction study. The self-focusing Z-scan technique has been employed to observe the third-order nonlinear optical property of the grown crystal. The mechanical property of the grown crystal was examined by using Vicker’s microhardness test. Chemical etching studies were made on the TTCS crystal using water as an etchant. The dark current and photocurrent properties of the crystal were estimated by using photoconductivity study. The dielectric constant of grown crystal was studied in different temperature by varying applied frequencies.

scholarly journals Growth and characterization of 4-(((4-aminophenyl)sulfonyl)oxy)-2,3-dihydroxy-4-oxobutanoic acid with Ce3+: for semiorganic nonlinear optical application

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
E. Vinoth ◽  
S. Vetrivel ◽  
S. Gopinath ◽  
R. Aruljothi ◽  
T. Suresh ◽  
...  
Keyword(s):  
Diffraction Study ◽  
Nonlinear Optical ◽  
Grown Crystal ◽  
Laser Source ◽  
Cutoff Wavelength ◽  
X Ray Diffraction ◽  
X Ray ◽  
Oxobutanoic Acid ◽  
Crystalline System

Abstract This work aims at the growth and characterization of novel semi-organometallic nonlinear optical (NLO) crystal 4-(((4-aminophenyl) sulfonyl) oxy)-2,3-dihydroxy-4-oxobutanoic acid (ASODA) with ammonium ceric (II) sulfate dehydrate (ACS). The crystal 4-(((4-aminophenyl) sulfonyl) oxy)-2,3-dihydroxy-4-oxobutanoic acid with Ce3+ (STA) was grown by slow evaporation solution growth technique using deionized water as a solvent. Crystalline system of the grown STA crystal was identified by a single crystal X-ray diffraction study and confirmed as monoclinic crystalline system with non-centrosymmetric space group P21/C. The powder X-ray diffraction study confirmed the purity and crystallinity of the crystal. The presence of functional groups and hydrogen bonds (–O–H–O–) was confirmed by FT-IR spectroscopy. UV-Vis spectra showed that the grown crystal had a low cutoff wavelength at 219 nm. The position of protons and carbons were determined by structural studies based on NMR technique. The grown crystal was thermally stable up to 130 °C and its melting point was 163 °C. The SHG studies were performed by Quanta Ray Model laser source using Kurtz powder technique. The NLO efficiency of the STA crystal was 0.5 times greater than that of standard KDP. The dielectric constant and dielectric loss of the grown crystal were studied at different temperatures. The surface morphology and the particle size of the crystal were determined by FE-SEM technique. From the mechanical studies, it was found that the grown crystal is a soft material.

scholarly journals Experimental and computational investigation with Hirshfeld surface analysis of bis(glycine) strontium dichloride trihydrate

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Anbarasan Radhakrishnan ◽  
Anna Lakshmi Muppudathi ◽  
Kalyana Sundar Jeyaperumal
Keyword(s):  
Surface Analysis ◽  
Grown Crystal ◽  
Visible Region ◽  
Hirshfeld Surface ◽  
Intramolecular Interactions ◽  
Hirshfeld Surface Analysis ◽  
Frontier Molecular Orbital ◽  
Cutoff Wavelength ◽  
X Ray Diffraction ◽  
X Ray

Abstract Good-quality semiorganic single crystals of bis(glycine) strontium dichloride trihydrate (GSC) were grown by slow evaporation technique. The lattice parameters of the grown crystal were verified through single crystal X-ray diffraction. Besides, the crystallinity of the material was analyzed with powder X-ray diffraction. The fingerprint of functional groups of this material was analyzed by FT-IR technique. The UV transparency cutoff wavelength of GSC was found to be 240 nm and the crystal exhibited 80 % transmission in the entire visible region. All intermolecular and intramolecular interactions of the grown crystal were interpreted by Hirshfeld surface analysis, and the strength of the interactions was graphically illustrated by fingerprint graphs. The intramolecular charge transfers of the crystal were assessed through frontier molecular orbital analysis.

Epitaxial Multilayers of (Sr,Ba)Nb2O6 and Conducting Films on (001) Mgo Substrates

1995 ◽  
Vol 388 ◽  
Author(s):  
T. F. Huang ◽  
K. E. Youden ◽  
S. Schwyn Thöny ◽  
L. Hesselink ◽  
J. S. Harris
Keyword(s):  
Epitaxial Growth ◽  
Nonlinear Optical ◽  
X Ray Diffraction ◽  
X Ray ◽  
Force Microscopy ◽  
Atomic Force ◽  
Electro Optic ◽  
Optical Applications ◽  
Nonlinear Optical Applications ◽  
Epitaxial Multilayers

Abstract(Sr,Ba)Nb2O6 (SBN) is a very promising material for nonlinear optical applications because of its high electro-optic and nonlinear optical coefficients. For these applications, SBN requires ferroelectric poling along the optical axis. Conducting layers such as Pt or YBCO must therefore be deposited to provide electrodes above and below the SBN film.We have investigated the epitaxial growth of multilayers of Sr0.61Ba0.39Nb2O6/Pt and Sr0.61Ba0.39Nb2O6/YBCO thin films on (001) MgO substrates by pulsed laser deposition. X-ray diffraction 2θ scans indicate epitaxial growth of SBN/Pt/MgO and SBN/YBCO/MgO heterostructures with their c-axes perpendicular to the substrate plane. X-ray phi scans indicate single crystal Pt and YBCO growth with one in plane orientation. atomic Force Microscopy shows surface roughness of 2.19 nm, and no evidence of particles is observed.

scholarly journals Growth and Characterization of Adipic Acid Doped Potassium Hydrogen Phthalate: A Nonlinear Optical Single Crystal

2019 ◽  
Vol 32 (1) ◽  
pp. 79-83
Author(s):  
R. Manimekalai ◽  
S. Chidambaram
Keyword(s):  
Single Crystal ◽  
Adipic Acid ◽  
Nonlinear Optical ◽  
Grown Crystal ◽  
Cutoff Wavelength ◽  
Potassium Hydrogen Phthalate ◽  
Hydrogen Phthalate ◽  
X Ray Diffraction ◽  
X Ray ◽  
Potassium Hydrogen

Adipic acid doped potassium hydrogen phthalate (AAKHP) and pure potassium hydrogen phthalate single crystals were grown by slow evaporation method. Single crystal X-ray diffraction analysis was carried out to determine the lattice parameters in a = 6.47 Å, b = 9.59 Å, c = 13.25 Å and space group of Pca21. This confirms the grown AAKHP belongs to the orthorhombic system. Various diffracting planes of the grown crystal were indexed using powder X-ray diffraction study. Fourier-transform infrared studies confirm the presence of various functional groups in the grown crystal. The transmittance spectrum shows that the lower cutoff wavelength is around 290 nm. The nonlinear optical property of the grown crystal has been studied by Kurtz powder second harmonic generation (SHG) analysis. EDAX analysis confirms the presence of various elements in the AAKHP crystal. Vickers micro-hardness studies are used for the analysis of mechanical behaviour of the grown crystal. The paramagnetic nature of the grown crystal was confirmed by vibration spectrum magnetometer technique.

Crystal growth, structural, spectral, optical and mechanical studies of zinc (tris) thiourea sulphate (ZTS) single crystals: A semiorganic non-linear optical material

2015 ◽  
Vol 2 (2) ◽  
pp. 5-8
Author(s):  
Selvapandiyan M ◽  
Arumugam J
Keyword(s):  
Second Harmonic Generation ◽  
Single Crystal ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Grown Crystal ◽  
Second Harmonic ◽  
Visible Spectrum ◽  
Uv Visible ◽  
Optical Applications ◽  
Nonlinear Optical Applications

Zinc-tris thiourea sulphate (ZTS) is one of the promising semiorganic nonlinear optical materials; it is useful for nonlinear optical applications. The grown crystals were subjected to single crystal Xray diffraction, UV-visible spectrum, FTIR, microhardness and SHG studies. Single crystal X- ray diffraction analysis revealed that the grown crystal belongs to orthorhombic system with space groupPca21 . Various functional groups present in the sample were identified by FTIR analysis. UV visible transmittance spectrum shows that the wide transmittance and lower cut-off wavelength. The mechanical property of the grown crystal has been analysed by Vickers microhardness test. Second harmonic generation was confirmed by using Nd: YAG laser. The second harmonic generation results confirmed that the crystal has better nonlinearity than KDP crystal.

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