scholarly journals Research on the effects of ferric salt added into aeration tank for phosphorus removal on biochemical system

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xie Jingliang ◽  
Sun Yuanjie ◽  
Peng Anran ◽  
Faris Kateb ◽  
Hooreya Mohamed Ahmed Aldeeb

Abstract In this paper, two iron salts, ferrous chloride (FeCl2) and ferric chloride (FeCl3), are directly added into an aeration tank for phosphorus removal, and their effects on the biochemical system are studied; the water quality parameters such as pH and alkalinity are also investigated. The extent of influence of the added iron salts on the pH and alkalinity of aerated solutions is demonstrated to be FeCl3 > FeCl2. When the dosage of iron ions is 20 mg/L, the decrease in pH and alkalinity caused by FeCl3 is 0.5 and 65 mg/L, which is higher than FeCl2 by 2% and 26%. The initial phosphorus removal effect of FeCl2 is worse than that of FeCl3, but after continued aeration and oxidation, the phosphorus removal effect of FeCl2 can be improved; however, the final phosphorus removal effect is basically the same as that of FeCl3 added directly. The results show that FeCl2 is preferred when iron salt is added directly into the aeration tank to remove phosphorus. The proposed scheme can reduce the effect of iron salts on the alkalinity of the biochemical system on the premise of ensuring the phosphorus removal effect of the system, and is conducive to ensuring the stable operation of the biochemical system.

1984 ◽  
Vol 224 (3) ◽  
pp. 761-767 ◽  
Author(s):  
J M C Gutteridge

Hydroxyl radicals (OH.) can be formed in aqueous solution by a superoxide (O2.−)–generating system in the presence of a ferric salt or in a reaction independent of O2.- by the direct addition of a ferrous salt. OH. damage was detected in the present work by the release of thiobarbituric acid-reactive material from deoxy sugars, nucleosides and benzoate. The carbohydrates deoxyribose, deoxygalactose and deoxyglucose were substantially degraded by the iron(II) salt and the iron(III) salt in the presence of an O2.− –generating system, whereas deoxyinosine, deoxyadenosine and benzoate were not. Addition of EDTA to the reaction systems producing radicals greatly enhanced damage to deoxyribose, deoxyinosine, deoxyadenosine and benzoate, but decreased damage to deoxygalactose and deoxyglucose. Further, OH. scavengers were effective inhibitors only when EDTA was present. Inhibition by catalase and desferrioxamine confirmed that H2O2 and iron salts were essential for these reactions. The results suggest that, in the absence of EDTA, iron ions bind to the carbohydrate detector molecules and bring about a site-specific reaction on the molecule. This reaction is poorly inhibited by most OH. scavengers, but is strongly inhibited by scavengers such as mannitol, glucose and thiourea, which can themselves bind iron ions, albeit weakly. In the presence of EDTA, however, iron is removed from these binding sites to produce OH. in ‘free’ solution. These can be readily intercepted by the addition of OH. scavengers.


1985 ◽  
Vol 17 (11-12) ◽  
pp. 297-298 ◽  
Author(s):  
Takao Murakami ◽  
Atsushi Miyairi ◽  
Kazuhiro Tanaka

In Japan various biological phosphorus removal processes have recently been researched by laboratory or pilot plant scale studies and most of them have shown good results. Based on these results, the Japan Sewage Works Agency has conducted a full scale study of the biological phosphorus removal process from June 1982 until February 1983, which was the first full scale operation of this process in Japan. The main purpose of the study was to evaluate phosphorus removal efficiency and also nitrogen removal efficiency of the process and in addition, to ascertain the important operating factors of the process. For the study a treatment train of a large scale sewage treatment plant was remodelled. The aeration tank of 3.825 m3 volume was divided into four equal cells. The whole train including return sludge line was operated entirely independently of the other trains. During the experiment the train was operated under two different modes, Mode 1 and Mode 2. In Mode 1, the train was operated as an A/O process, the first cell of the aeration tank being anaerobic and the other cells oxic. In Mode 2, the train was operated as a Modified Phoredox process. In this case, the first cell was anaerobic, but the second cell was anoxic and nitrified liquor was returned to it from the end of the oxic cells. Mode 1 and Mode 2 were further divided into many ‘runs' and the flow rate varied between 12,550 m3 d−1 and 25,270 m3 d−1 , corresponding to retention times of 7.3 hours and 3.6 hours, respectively. Throughout the experimental period the mean value of influent (primary effluent) total-P concentration was 3.38 mg 1−1 , and that of the final effluent was 0.47 mg 1−1 . A cumulated frequency curve of the data showed that about 93% of measured effluent total-P was below 1.0 mg l−1 . Therefore, it can be concluded that with these influent total-P levels, biological phosphorus removal processes can sufficiently satisfy the effluent standard of 1 mg 1−1 total-P. Even when the process was operated as a Modified Phoredox Process, no obstruction to phosphorus removal because of nitrification was observed and phosphorus removal remained good. However, since the sewage treatment plant treated influent from a combined sewerage system, phosphorus removal was sometimes affected by heavy rainfalls. In such cases phosphorus release in the anaerobic cell was insufficient because of increased influent NOx concentration and accordingly increased denitrification level in the anaerobic cell. Therefore, as a result, enhanced phosphorus uptake in the following cells could not be observed. Higher process stability can be expected if an effective countermeasure to high influent NOx concentration can be made. Influence of flow rate fluctuation on the process was also studied. The treatment train was operated for a week under a daily flow rate fluctuation pattern which ranged between 460 m3 hr−1 and 820 m3 hr−1 . Nevertheless, the effluent total-P concentration showed no increase and stayed constantly lower than 0.5 mg 1−1. The oxidation reduction potential (ORP) was an effective control index to evaluate the degree of phosphorus release in the anaerobic cell. Water temperature did not affect phosphorus release and uptake rates.


1938 ◽  
Vol 67 (2) ◽  
pp. 259-265 ◽  
Author(s):  
P. F. Hahn ◽  
G. H. Whipple

In experimental anemia in dogs due to blood loss the term "available iron" as determined by the dipyridyl test has no physiological significance. Iron salts (100 per cent available by dipyridyl) given in optimum dose (560 mg. per 2 weeks) will cause a net production of 50 to 55 gm. hemoglobin above the control base line in anemic dogs. This means that an iron salt which is rated as 100 per cent available by the dipyridyl test is only 35 per cent physiologically available. The term "available iron (dipyridyl)" simmers down to iron not in the form of hematin compounds. The absorption of this "available iron" is conditioned by a great variety of factors, many unknown at this time. Iron is indeed an elusive sprite whose "availability" or comings and goings cannot be determined in dogs by dipyridyl—perhaps only in part by studies of absorption and excretion. Liver contains "available iron (dipyridyl)" but also organic factors influencing hemoglobin regeneration in anemia as liver ash contains only about 50 per cent the potency of the whole liver. One can readily dissociate the iron from other potent factors in various tissues. Fractions of heart, liver, spleen, and kidney may contain very little iron yet cause much hemoglobin regeneration in anemic dogs. No investigator has reported any condition of copper deficiency in man or dog. In fact, in anemias copper is usually above normal concentration in the liver. It is unlikely, therefore, that in experimental anemia in dogs and in the various anemias of man, any significance attaches to the intake of copper.


2014 ◽  
Vol 955-959 ◽  
pp. 1895-1898
Author(s):  
Su Chen ◽  
Lei Chao ◽  
Ning Chen ◽  
Lin Shan Wang ◽  
Xue Shao ◽  
...  

The inoculated sludge in this experimental system is from the end of aeration tank of the wastewater treatment plant. Under stable operation, the system’s treatments of COD and NH4+-N are all in line with Level One Urban Sewage Discharge stipulated by Pollutant Discharge Standards for Urban Sewage Treatment Plants (GB 18918-2002). The removal rates of COD and NH4+-N are 94.27% and 91.03%. By gradually improving the method of salinity acclimation, the salt tolerant sludge with outstanding performance can be successfully acclimated, and each gradual increase in salinity scope is controlled at around 4 g/L. When the salinity is 1%, the removal rates of COD and NH4+-N reach to 92.09% and 70.13%. The salinity has significant impacts on microbial activity. With the increase in salinity, the dehydrogenase activity gradually decreases. Salinity has significant effects on protozoa. Paramecia and nematodes can be taken as the biological indicator of outflow water quality of brine waste.


1977 ◽  
Vol 75 (2) ◽  
pp. 327-328 ◽  
Author(s):  
R. E. J. DYBALL ◽  
R. J. WRIGHT

A. R. C. Institute of Animal Physiology, Babraham, Cambridge, CB2 4AT (Received 12 April 1977) Both electrical stimulation with steel microelectrodes and injection of iron salts into the preoptic area lead to an increased concentration of luteinizing hormone (LH) in the plasma and ovulation (Everett & Radford, 1961; Dyer & Burnet, 1976). Initially, iron salts were thought to excite nerve cells but Fe2+ and Fe3+ ions, like most cations, when applied to nerve cells by micro-iontophoresis, inhibit firing (Dyer & Burnet, 1976). Dyer & Burnet (1976) proposed a number of alternative explanations for the electrochemical stimulation of ovulation. They suggested that ferrous or ferric ions might kill or damage some neurones and the resulting cell disruption might lead in turn to the liberation of a sufficient quantity of luteinizing hormone releasing hormone (LH-RH) into the hypophysial portal vessels to cause a surge of LH. Alternatively, ovulation might be stimulated by


2001 ◽  
Vol 36 (4) ◽  
pp. 659-685 ◽  
Author(s):  
Janique Bergeron ◽  
Michael Paice

Abstract Two five-litre activated sludge (AS) bioreactors were operated for several months to demonstrate potential mill applications of a four-assay set, which has been proposed as a tool for monitoring the health of the AS microbial population. The set consists of three specific oxygen uptake rate (SOUR) determinations at different substrate concentrations (SOURat, SOURnmax and SOURtox where at, nmax and tox are defined as aeration tank, near maximum, and toxic, respectively), and a specific adenosine triphosphate (SATP) assay. Two disturbances were applied at different times to an AS system treating kraft effluent. First, temperature was increased from 25 to 40°C, and second, a black liquor spill was simulated. The data before, during, and after these disturbances were statistically analyzed. From this analysis, we concluded that the four-assay set could be used as a microbial health characterization (MHC) tool. It allows an operator to correlate microbial changes with operating data over a mediumterm time scale. We compared the values obtained during periods of upset in the system treating the kraft effluent, to the baseline data set determined from stable operation periods. This demonstrated how the four-assay set could be used as a biological early warning (BEW) tool. It allows a treatment system operator to make appropriate adjustments immediately after detecting values that fall outside the baseline data range.


1993 ◽  
Vol 28 (10) ◽  
pp. 275-282 ◽  
Author(s):  
S. Marklund

The aeration tank in a small scale wastewater treatment plant was converted to a sequencing batch reactor (SBR) with a maximum volume of approx. 27 m3. The main purpose of this study was to examine low temperature biological phosphorus removal (BPR). The wastewater temperature varied during the study between 3 and 8°C, with a water temperature at or below 5°C during 7 months of the year. The SBR unit has been in operation from the end of 1989, the study period discussed here covered July 1991 - December 1992. SBR cycle time was varied between 6 and 12 hours, giving a total daily treatment capacity of between 18 and 36 m3. The influent biological oxygen demand - 7 days (BOD7) levels varied between 88 and 165 mg/l. Corresponding phosphorus levels were between 3.10 and 9.55 mg/l The mean effluent level of phosphorus was 1.57 mg/l and the BOD7 value was 23 mg/l. This gives a mean total phosphorus reduction of 74% and a BOD7 reduction of 81 %. During the study, mean supernatant suspended solids (SS) levels were quite high, at around 36 mg/l. This high SS level contributed a major part of both outlet phosphorus as well as BOD7 value. Effluent soluble values for phosphorus and BOD7 were 0.79 mg/l and 9 mg/l. The supernatant SS component of BOD7 and phosphorus increased at lower temperatures. It was not possible to reduce or balance this increase by increased cycle time or increased settling time within the maximum cycle time available (12 hours). Stable low supernatant phosphorus and BOD7 levels are thus to a large degree controlled by the effluent SS level. A maximum of 20 mg/l supernatant SS is necessary to reach target supernatant values of less than 1 mg/l of phosphorus and 15 mg/l of BOD7.


2021 ◽  
Author(s):  
Ramsey White ◽  
Simone Mulas ◽  
Pier Domini ◽  
Miguel Lopez ◽  
Faris Abusittah

Abstract The Modulated AC/DC Crude Desalting technology was successfully commissioned at several Saudi Aramco facilities. Enhancements to desalting performance and optimization of plant operating expenditures were realized. Benefits of the Modulated AC/DC Desalting technology, installation and operational best practices and a comparison to conventional AC technology is shared in the paper. The conventional AC desalting technology was replaced with the Modulated AC/DC Crude Desalting technology at some Saudi Aramco facilities. After the successful commissioning, the performance of the new units was tested in one of these facilities to identify operating limits, such as maximum water cut and minimum demulsifier injection at the production header, in which the stable operation is sustainable. A comparison of the performance of the technology compared to that of previous conventional AC desalting technology was conducted through analysis of grid/plate voltage stability, demulsifier injection rate, wash water rates and crude quality parameters. Some enhancements to the process were also introduced which resulted in realizing additional benefits. The technology resulted in several benefits, including: (1) A reduction in the required demulsifier injection rate during the testing period compared to the same time period from the previous year, leading to significant cost savings; (2) Ability to maintain normal operations beyond the design water cuts of the facility; (3) No major grid outages since installation; (4) Additional data that can be used to diagnose separation performance as each transformer provides a number of feedback signals to DCS that are good indicators of the separation process. Based on the observations and analysis, the Modulated AC/DC Crude Desalting Technology has several advantages over the conventional AC Crude Desalting Technology in regards to crude desalting performance and process stability. The Modulated AC/DC Crude Desalting technology at Saudi Aramco was the first installation in Saudi Arabia for Arab Light crude oil. The paper captures Saudi Aramco’s experience and best practices that other companies can find beneficial in their efforts to maintain crude quality and reduce operating expenditures.


2010 ◽  
Vol 44 (11) ◽  
pp. 3467-3475 ◽  
Author(s):  
Oriol Gutierrez ◽  
Donghee Park ◽  
Keshab R. Sharma ◽  
Zhiguo Yuan

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