Kinetics of pyrolysis mass loss from cured phenolic resin

10.2514/3.667 ◽  
1995 ◽  
Vol 9 (2) ◽  
pp. 352-358 ◽  
Author(s):  
Eric H. Stokes
Keyword(s):  
Mass Loss ◽  
Phenolic Resin ◽  
Kinetics Of

Porous Structure and Transport Properties of a Carbonized Phenolic Resin

1995 ◽  
Vol 60 (2) ◽  
pp. 172-187 ◽  
Author(s):  
Pavel Fott ◽  
František Kolář ◽  
Zuzana Weishauptová
Keyword(s):  
Porous Structure ◽  
Transport Properties ◽  
Phenolic Resin ◽  
Arrhenius Equation ◽  
Mercury Porosimetry ◽  
Micropore Volume ◽  
Microporous Structure ◽  
Wetting And Drying ◽  
Phenolic Resins ◽  
Kinetics Of

On carbonizing phenolic resins, the development of porous structure takes place which influences the transport properties of carbonized materials. To give a true picture of this effect, specimens in the shape of plates were prepared and carbonized at various temperatures. The carbonizates obtained were studied by adsorption methods, electron microscopy, and mercury porosimetry. Diffusivities were evaluated in terms of measuring the kinetics of wetting and drying. It was found out that the porous structure of specimens in different stages of carbonization is formed mostly by micropores whose volumes were within 0.06 to 0.22 cm3/g. The maximum micropore volume is reached at the temperature of 750 °C. The dependence of diffusivity on the carbonization temperature is nearly constant at first, begins to increase in the vicinity of 400 °C, and at 600 °C attains its maximum. The experimental results reached are in agreement with the conception of the development and gradual closing of the microporous structure in the course of carbonization. The dependence of diffusivity on temperature can be expressed by the Arrhenius equation. In this connection, two possible models of mass transport were discussed.

A model to predict the kinetics of mass loss in wood during thermo-vacuum modification

Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Ottaviano Allegretti ◽  
Ignazia Cuccui ◽  
Nasko Terziev ◽  
Laerte Sorini
Keyword(s):  
Mass Loss ◽  
Treatment Process ◽  
Linear Trend ◽  
Thermal Modification ◽  
Thermal Treatments ◽  
Temperature Profiles ◽  
Relative Area ◽  
Heat Power ◽  
Kinetics Of

AbstractMass loss (ML) of wood caused by thermal degradation is one of the most important features of the thermal treatments and referred to as an indicator of intensity and quality of the process. The ML is proportional to the quantity of the effective heat power exchanged during the treatment process, represented by the area of the temperature profile versus time during the process. In this paper a model for the ML prediction based on the relative area was discussed. The model proposed an analytical solution to take into account the non-linear trend of ML when plotted versus temperature and time as observed in isothermal experiments. The model was validated comparing calculated and measured final ML of samples treated during thermal modification tests with different temperature profiles. The results showed that the relative area calculated in a transformed time-temperature space improves the correlation with the measured ML.

scholarly journals Research on the Kinetics of Pyrolysis of Wood-Based Panels in Terms of Waste Management

Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3705 ◽  
Author(s):  
Jaworski ◽  
Kajda-Szcześniak
Keyword(s):  
Waste Management ◽  
Mass Loss ◽  
Raw Materials ◽  
Thermal Transformation ◽  
Molecular Formula ◽  
Empirical Formulas ◽  
Material Recycling ◽  
Transformation Methods ◽  
The Impact ◽  
Kinetics Of

Currently, there is a lot of interest in implementing the idea of ​​a circular economy along with searching for optimal methods of waste management in terms of raw materials and energy. Waste wood-based floor panels are part of this discussion with regard to its management. The interest in this waste results from statistics and the prediction of its future quantities on the waste market. The separation and testing of individual layers of the waste floor panel was undertaken to answer the following question: Is it reasonable to mechanically separate the contaminated upper panel layer from the remaining part (which is suitable for material recycling) and subject it to thermal transformation methods? Thermogravimetric studies did not confirm the rationale of mechanical separation of layers for further management. Therefore, the use of pyrolysis was proposed as an alternative by showing the advantages of this process in the thermal transformation of the tested waste. The analyzed kinetics of this process included: mass loss, the influence of heating rate on the decomposition process, the impact of volatile parts in the substrate on the rate of mass loss, and the share of coke residue. Empirical formulas of the tested substrates in the molecular formula C–H–O–N (carbon-hydrogen-oxygen-nitrogen) were also proposed to assess its energy usefulness by entering the analyzed waste into a Van Krevelen diagram.

Thermogravimetric Analysis on Global Mass Loss Kinetics of Rice Hull Pyrolysis

1997 ◽  
Vol 36 (9) ◽  
pp. 3974-3977 ◽  
Author(s):  
Hsisheng Teng ◽  
Hung-Chi Lin ◽  
Jui-An Ho
Keyword(s):  
Thermogravimetric Analysis ◽  
Mass Loss ◽  
Rice Hull ◽  
Kinetics Of

Cure kinetics of a composite friction material with phenolic resin/rubber compounds as organic binder

2021 ◽  
pp. 1-13
Author(s):  
Pablo Monreal-Perez ◽  
Laura Ciérvide ◽  
Raúl Orzanco ◽  
Maite Idareta ◽  
Isabel Clavería Ambroj
Keyword(s):  
Phenolic Resin ◽  
Cure Kinetics ◽  
Friction Material ◽  
Organic Binder ◽  
Rubber Compounds ◽  
Kinetics Of

scholarly journals Thermomechanical and Morphological Studies of CFRP Tested in Different Environmental Conditions

Materials ◽  
2018 ◽  
Vol 12 (1) ◽  
pp. 63 ◽  
Author(s):  
Claudia Barile ◽  
Caterina Casavola ◽  
Paramsamy Vimalathithan ◽  
Marco Pugliese ◽  
Vincenzo Maiorano
Keyword(s):  
Activation Energy ◽  
Thermal Degradation ◽  
Mass Loss ◽  
Environmental Conditions ◽  
Degradation Kinetics ◽  
Fiber Reinforced Polymers ◽  
Thermal Degradation Kinetics ◽  
Morphological Studies ◽  
Significant Difference ◽  
Kinetics Of

The present work describes the mechanical characterization combined with the thermal degradation kinetics of Carbon Fiber Reinforced Polymers (CFRP). The thermal degradation kinetics of CFRP have never been studied in the past. In that regard, the present work focuses on studying the thermal degradation kinetics of CFRP tested mechanically at different environmental conditions. Tensile tests were performed on the specimens with different lay-ups at room temperature, elevated temperature (71 °C), and cryogenic conditions (−54 °C), and the same specimens were used for thermal degradation kinetic studies. Mechanical tests show different responses respect to the different environmental conditions and different fibers orientation. On the other hand, the thermogravimetric results, mass loss, and derivative mass loss, show no significant difference in the degradation of CFRP tested at different temperatures. However, the thermal degradation kinetics shows more insight into the degradation pattern of the materials. The activation energy of degradation shows that the degradation of materials subjected to elevated conditions increases rapidly in the later stages of degradation, suggesting the formation of high char yield. The varying activation energy has been related to different degradation mechanisms. Lastly, the morphology of the materials was studied under SEM to understand the structural change in the material after tested in different weather conditions.

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