scholarly journals Research on the Kinetics of Pyrolysis of Wood-Based Panels in Terms of Waste Management

Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3705 ◽  
Author(s):  
Jaworski ◽  
Kajda-Szcześniak

Currently, there is a lot of interest in implementing the idea of ​​a circular economy along with searching for optimal methods of waste management in terms of raw materials and energy. Waste wood-based floor panels are part of this discussion with regard to its management. The interest in this waste results from statistics and the prediction of its future quantities on the waste market. The separation and testing of individual layers of the waste floor panel was undertaken to answer the following question: Is it reasonable to mechanically separate the contaminated upper panel layer from the remaining part (which is suitable for material recycling) and subject it to thermal transformation methods? Thermogravimetric studies did not confirm the rationale of mechanical separation of layers for further management. Therefore, the use of pyrolysis was proposed as an alternative by showing the advantages of this process in the thermal transformation of the tested waste. The analyzed kinetics of this process included: mass loss, the influence of heating rate on the decomposition process, the impact of volatile parts in the substrate on the rate of mass loss, and the share of coke residue. Empirical formulas of the tested substrates in the molecular formula C–H–O–N (carbon-hydrogen-oxygen-nitrogen) were also proposed to assess its energy usefulness by entering the analyzed waste into a Van Krevelen diagram.

2021 ◽  
Vol 2021 (2) ◽  
pp. 76-85
Author(s):  
Oleksandr V. Kubatko ◽  
Oleksandra V. Kubatko ◽  
Tetyana I. Sachnenko ◽  
Odevole O. Oluwaseun

One of the most urgent environmental problems today is the pollution of the environment by emissions of harmful substances and industrial waste. The negative impact on the environment and people is becoming more widespread, and its disposal methods inhibit the development of the economic system. In a market economy, entrepreneurs are not interested in increasing environmental costs, which naturally lead to higher production costs and reduce profits. The impact on the environment is becoming more widespread every year and has led to an ecological crisis in some parts of the world. Waste recycling has been constantly discussed since a person “produces” more than 250 kg of household waste per year. At the enterprise, these figures reach 10 000 kg. In recent years, Ukraine has imported about 30-50 thousand tons of PET granulate, which is gradually accumulating in landfills in the form of packaging, bottles, films. Such hazardous pollutants affect the environment through soil and water. In contrast, Ukraine does not yet have successful experience in waste management. In our opinion, such behavior is the ignorance of the population about waste disposal and replacement of a particular product with a more environmentally friendly one. The functioning of enterprises and farms does not always have the equipment to dispose of waste, and there is no room for the disposal of unnecessary products and raw materials. However, the problem of lack of innovative equipment arises due to a lack of adequate funding. Therefore, the lack of possibilities for a comprehensive solution to the situation creates a barrier, which does not allow to take proper measures to eliminate and reduce the amount of garbage. Despite many regulations and legal frameworks for regulating waste management, there is no cost-effective policy, and there is no regional waste management program and plan for their proper disposal. It can be concluded that the recycling and disposal of waste will reduce the need for waste incineration, create conditions for improving the economic component of the region and the country as a whole with an account of environmental quality standards. The paper pays attention to the essence of waste disposal; identified ways to recycle garbage.


2010 ◽  
Vol 177 ◽  
pp. 342-345 ◽  
Author(s):  
Zhan Peng Zhang ◽  
Cheng Zhang ◽  
De Xing Huang ◽  
Dan Yu Jiang ◽  
Rong Juan Zhang ◽  
...  

Magnesium oxide is one of the most important raw materials in the refractory industry due to its high melting point (2800oC), corrosion resistance in the basic environment, and low cost. Nevertheless, magnesium oxide reacts easily with water to produce magnesium hydrate, which is followed by a large volumetric expansion, limiting its application in refractory industry. As the hydration of MgO is very important either in theory or in industrial production of magnesium, in this paper, the influence of temperature, residence time, as well as the impact of the solid content on MgO hydration and the kinetics of hydration reaction was evaluated to optimize the determination method of magnesium oxide hydration in refractory industry.


2019 ◽  
Vol 26 (1) ◽  
pp. 175-188
Author(s):  
Paweł Stolarek ◽  
Stanisław Ledakowicz ◽  
Radosław Ślęzak

Abstract Thermogravimetry (TG) is the fast and reliable method for characterization of thermal decomposition of any material and in particular to determine the kinetics of pyrolytic decomposition of sewage sludge. Two types of sewage sludge with and without addition of lime were investigated from kinetic point of view. For TG analysis samples of selected sewage sludge were heated under the inert atmosphere of argon with constant heating rate from 303 to 1273 K; the three heating rate β = 5, 10 and 20 K/min were chosen. The iso-conversion methods of Friedman and Ozawa-Flynn-Wall were employed for analysis of TG results. As the sewage sludge decomposition is very complex process it cannot be described by a simple stoichiometric equation, therefore the so called lumping of reactions in the selected temperature ranges were used with detailed principles arising from visual analysis of DTG curve. The deconvolution of DTG curves performed according to Fraser-Suzuki asymmetric profile allowed the identification of number of lumps and their contribution to the overall mass loss. So the decomposition of sewage sludge with lime addition could be described with five groups of reactions while the one without lime by means of six lumps. The thermal decomposition of sewage sludge was assumed to proceed according to the scheme of parallel concurrent independent reactions of n-th order. The values of the apparent activation energies at different constant values of conversion degrees were determined by the iso-conversion analysis. To estimate the kinetic parameters the non-linear regression with Levenberg-Marquart optimization procedure was used. The kinetic parameters such as activation energy, pre-exponential factor, reaction order and fraction of total mass loss associated with a given reaction were determined. The impact of sewage sludge liming revealed in essential differences of pyrolysis products and pyrolysis kinetics of limed sludge and without lime one was highlighted.


Author(s):  
Adel ALFoudery ◽  
Abdulrahman Abdullah Alkandari ◽  
Nayfah Mohsen Almutairi

<span lang="EN-US">The protection of society and environment from garbage accumulation and its polluting effects is carried by waste management companies, the services provided by these companies are improving life overall quality. By preserving raw materials, proper collecting and elimination of trash have reduced pollution and environmental impact. On the other hand, areas which are suffered from inappropriate negative service appreciate the garbage collector’s valuable efforts. Appropriate garbage collection and management facilities have made a recycling process improvement which caused a reduction in waste generation. Also controlling the released contaminators and pollutants has decreased the impact on landfills and protected the environment from the pollution negative effects. Using mobile and electronic technology to enable waste management companies to finish its work and make it easier for collecting trash in a simple and an easy way. We introduce Trash Sensor Android Application to help waste management companies detect trash levels to collect it and help citizens from undesired odours.</span>


Author(s):  
Emilda Emilda

The limitations of waste management in the Cipayung Landfill (TPA) causing a buildup of garbage up to more than 30 meters. This condition has a health impact on people in Cipayung Village. This study aims to analyze the impact of waste management at Cipayung Landfill on public health in Cipayung Village, Depok City. The research is descriptive qualitative. Data obtained by purposive sampling. Data was collected by interviews, observation and documentation. Based on interviews with 30 respondents, it was found that the most common diseases were diarrhea, then other types of stomach ailments, subsequent itching on the skin and coughing. This is presumably because the environmental conditions in the form of unhealthy air and water and clean and healthy living behaviors (PHBS) have not become the habit of the people. The results indicated that there were no respondents who had implemented all of these criteria. In general respondents have implemented  3 criteria, namely maintaining hair hygiene, maintaining skin cleanliness, and maintaining hand hygiene. While maintaining clean water storage is the most often overlooked behavior. To minimize this health impact, improvements in waste management in Cipayung landfill are needed along with continuous socialization and education to develop PHBS habits and the importance of maintaining a clean environment.


2008 ◽  
Vol 59 (2) ◽  
pp. 129-134
Author(s):  
Ion Teoreanu ◽  
Roxana Lucia Dumitrache ◽  
Stefania Stoleriu

Any change of the raw material sources for glazes, economically, ecologically motivated, and also from the glaze quality point of view, is conditioned by the molecular formula rationalization and by the variation limits of the molecular formula, respectively. The proper glaze compositions are placed within their limit variation intervals with optimized processing and utilization properties. For this purpose, the rationalization criteria and procedures of molecular formulas are summarized in the present paper, as well as the results referring to their rationalization obtained in the authors� previous work. Thus, one starts from a base of raw materials that are selected, usable and also accessible for the design and producing of the glazes. On these bases the groundwork and the design equation for the glaze recipes are developed, exemplified for a single glaze. For an easy access to results, computer programs are used for an easy access to results.


2018 ◽  
Vol 68 (12) ◽  
pp. 2941-2947
Author(s):  
George Ungureanu ◽  
Gabriela Ignat ◽  
elena Leonte ◽  
Carmen Luiza Costuleanu ◽  
Nicoleta Stanciu ◽  
...  

The problem associated with the household behavior on solid waste disposal site in today�s society is complex because of the large quantity and diverse nature of the wastes. Due increase the population, rapid development, global agricultural development has moved rapidly, limitations of financing, emerging limitations of both energy and raw materials and also add to the complexity of any waste management system, large quantities of wastes are being generated in different forms such as solid, liquid and gases. This research explored factors affecting the level of participation in solid waste segregation and recycling of households in Romania, as well as examining current Romania households waste management practices and their knowledge of waste management. This study investigated the solid waste situation and the organization of solid waste management in both urban and rural settings from the perspective of households. Solid waste management is a key component of public services which needs to serve the urban and rural municipalities in an efficient way in order to maintain a decent standard of public health.


This article presents the results of studying the impact of housing and feeding conditions on broiler chickens of Hubbard RedBro cross, as well as the quality of products obtained when using floor and cage content, in a farm. It established that when receiving a mixed feed of own production using feed raw materials grown on a farm without the use of pesticides, a statistically significant decrease in potentially dangerous substances for animal health is recorded. Compared with factory feed, it has reduced the content of pesticides by 14 times, and mercury and arsenic by 24 times, cadmium by five times, and lead by ten times. The results of the study of economic indicators of growing Hubbard RedBro cross broiler chickens, as well as the chemical composition and quality of carcasses, indicated that there was no significant difference between the floor and cell conditions of keeping. Still, the use of a diet based on eco-feeds contributed to a statistically significant decrease in the concentration of toxic metals in the muscles of the poultry of the experimental groups. As a result, it found that the use of the studied compound feed in the diets of broiler chickens increased the indicators of Biosafety and ensured the production of environmentally safe ("organic") poultry meat products.


Domiati cheese is the most popular brand of cheese ripened in brine in the Middle East in terms of consumed quantities. This study was performed to investigate the impact of the microbiological quality of the used raw materials, the applied traditional processing techniques and ripening period on the quality and safety of the produced cheese. Three hundred random composite samples were collected from three factories at Fayoum Governorate, Egypt. Collected samples represent twenty-five each of: raw milk, table salt, calf rennet, microbial rennet, water, environmental air, whey, fresh cheese, ripened cheese & swabs from: worker hands; cheese molds and utensils; tanks. All samples were examined microbiologically for Standard Plate Count (SPC), coliforms count, Staphylococcus aureus (S. aureus) count, total yeast & mould count, presence of E. coli, Salmonellae and Listeria monocytogenes (L. monocytogenes). The mean value of SPC, coliforms, S. aureus and total yeast & mould counts ranged from (79×102 CFU/m3 for air to 13×108 CFU/g for fresh cheese), (7×102 MPN/ cm2 for tank swabs to 80×106 MPN/ml for raw milk), (9×102 CFU/g for salt to 69×106 CFU/g for fresh cheese) and (2×102 CFU/cm2 for hand swabs to 60×104 CFU/g for fresh cheese), respectively. Whereas, E. coli, Salmonella and L. monocytogenes failed to be detected in all examined samples. There were significant differences in all determined microbiological parameters (p ≤0.05) between fresh and ripened cheese which may be attributed to different adverse conditions such as water activity, pH, salt content and temperature carried out to improve the quality of the product.


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