scholarly journals Comparative Studied of Degradation of Textile Brilliant Reactive Red Dye Using H2O2, TiO2, UV and Sunlight

2019 ◽  
Vol 22 (1) ◽  
pp. 31-36
Author(s):  
Forqan Mohammed ◽  
Khalid M. Mousa

In this study sunlight and UV radiation were used to compare the efficiency of decolorization of textile wastewater containing brilliant reactive red dye K-2BP (λmax = 534 nm) by the advanced oxidation process (AOP) using (H2O2/sunlight, H2O2/UV, H2O2/TiO2/sunlight, and H2O2/TiO2/UV). The results studied the effect of solution pH, applied H2O2 concentration, TiO2 concentration (nanoparticle), and initial dye concentration were studied. The experimental results showed that decolorization percentage with H2O2/sunlight and TiO2/H2O2/sunlight under the following conditions: - reaction time 150 of minutes, [ 500 ppm] H2O2, [100 ppm] TiO2, pH=3, initial dye concentration =15 ppm and at ambient temperature were 95.7% and 98.42% respectively. For the same conditions using H2O2/UV, H2O2/TiO2 /UV, the percentage of decolorization were 97.85% and 96.33% respectively. The results also indicated that the sunlight is more economic and cost-effective than UV radiation.

1994 ◽  
Vol 30 (3) ◽  
pp. 265-274 ◽  
Author(s):  
Cheng-Nan Chang ◽  
Ruey-Fang Yu ◽  
Allen C. Chao ◽  
Seishu Tojo

On-line monitoring of the wastewater color and ORP values is used to carry out laboratory studies for collecting data to assist in formulating model equations that can be used to achieve better control and automation of the oxidation process for color removal from textile finish wastewaters. Laboratory studies show that the ORP value, the solution pH, the chemical dosage applied and the resulting color of the treated samples are well correlated by linear relationships. Additionally, the ORP value of the solution that is highly related to the color or the ADMI value of the sample being oxidized can be used as a control parameter of the oxidation process. Nernst equation is modified to generalize the findings and the reaction kinetics can be delineated by Ct = In (ADMIo/ADMIt). The term Ct is a function of ORP, pH and reaction time while ADMIt and ADMI, are the color of the raw wastewater and the treated effluent, respectively. Using the model, the dosage requirement, the color removal efficiency, and the time required to complete the oxidation reaction can be calculated. On-line monitoring and automatic control of the de-coloring process to achieve a more efficient and better cost-effective color removal can be made practical.


2018 ◽  
Vol 54 (4B) ◽  
pp. 64
Author(s):  
Nga Thi Dinh

This study investigated the Photo-Fenton process in textile wastewater treatment by using textile synthesis wastewater made of Symafix Red Dye solution. The aim of the study was to investegate the factors that influent to the photo-Fenton process such as contact time, pH, H2O2 and Fe2+conectrations, and UVexposure in order to research the optimum values of this process.Treatment of textile wastewater was carried out at ambient temperature in a batch reactor. As a result, the second-order is suitable for the reaction of removing color by using Photo –Fenton processes. The removal efficiencies decreased when we increased the concentration of Fe2+ from 7.162 mM to 14.162 mM. When we increased the H2O2 concentration from 0.037 mM to 0.11mM, the removal efficiencies slightly decreased. The optimum value of pH is pH = 3. At the optimum of pH value and minimum the concentration of Fe2+ and H2O2 the removal efficiency could reach up to 95.82 %. 


2017 ◽  
Vol 14 (3) ◽  
pp. 516-523
Author(s):  
Baghdad Science Journal

Decolorization of red azo dye (Cibacron Red FN-R) from synthetic wastewater has been investigated as a function of solar advanced oxidation process. The photocatalytic activity using ZnO as a photocatalysis has been estimated. Different parameters affected the removal efficiency, including pH of the solution, initial dye concentration and H2O2 concentration were evaluated to find out the optimum value of these parameters. The results proved that the optimal pH value was 8 and the most efficient H2O2 concentration was 100mg/L. Toxicity reduction percent for effluent solution was also monitored to assess the degradation process. This treatment method was able to strongly reduce the color and toxicity of reactive red dye-238 to about (99 and 80) % respectively. It can be concluded, from these experiments, that the using of ZnO as a photocatalysis was exhibited as economical and efficient treatment method to remove reactive red dye-238 from aqueous solution.


2019 ◽  
Author(s):  
Chem Int

The high energy radiation overcome the bonding of solute in a solution and H2O2 acts as an oxidizing agent and generates a free radical in the solution which results in photo-degradation by converting the solute in to simple form and resultantly, colored substance under the effect of photo-degradation becomes colorless. The photo-degradation of monoazo dye Blue 13 in an aqueous solution was investigated using a laboratory scale UV lamp in the presence of H2O2 and for maximum degradation of dye, the independent parameter UV power, UV exposure time, pH and H2O2 concentration were optimized. It was found that neither UV in the presence of H2O2 is able to degrade Blue 13 under optimum condition. The results revealed that the use of both UV and H2O2 have pronounced effect on the discoloration of dyes which could be used for management of textile effluents contain waste dyes.


Author(s):  
André Gadelha de Oliveira ◽  
Jefferson Pereira Ribeiro ◽  
Juliene Tome de Oliveira ◽  
Denis De Keukeleire ◽  
Maíra Saldanha Duarte ◽  
...  

AbstractThis study investigates the use of an advanced oxidation process (AOP) for removal of the pesticide chlorpyrifos in a recirculated system, especially considering the effects of temperature, hydrogen peroxide dosage, pH, pesticide concentration and added inorganic anions. The results indicate that a temperature of 45 °C gave the best performance using only UV-radiation, while for the UV/H


2021 ◽  
Vol 33 (6) ◽  
pp. 1294-1298
Author(s):  
R. Raja ◽  
A. Rose Venis ◽  
R. Tamil Selvan ◽  
T. Mohandas

The Congo red dye was decolourized by advanced oxidation process using solar/H2O2 method and the effect of various parameters on decolourization like pH, H2O2 concentration, dye concentration, solar light intensity, additives, COD and TOC removal studies and kinetic studies were investigated. The photodegradation process was done by exposing dye solutions with the concentration of 100 mg/L treated with 50% H2O2 to sunlight with the lux intensity range of 60,000-90,000 lux. The best possible pH 2 with an optimal H2O2 concentration of 1000 mM to achieve 100% decolourization within the period of 5 h. The kinetic studies done on H2O2 concentration also proved that the high solar light intensity leads to higher decolourization and low solar light intensity leads to lesser decolourization. Addition of additives like H2PO4 – and Cl– leads to a decrease in the rate of decolourization. The removal of COD and TOC removal was found to be 83.26% and 5.18%, respectively.


2021 ◽  
Author(s):  
Sutrisno Salomo Hutagalung ◽  
Deddy Kurniadi ◽  
Nurul Taufiqu Rochman ◽  
Sri Harjati Suhardi ◽  
Khusnul Khotimah

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