scholarly journals Ultrafine particulate matter in methane-air premixed flames with oxygen enrichment

2021 ◽  
Author(s):  
Shruthi Dasappa ◽  
Joaquin Camacho
Keyword(s):  
Particle Size ◽  
Particulate Matter ◽  
Equivalence Ratio ◽  
Volume Fraction ◽  
Soot Formation ◽  
Flame Temperature ◽  
Number Density ◽  
Soot Precursors ◽  
Soot Precursor ◽  
Ultrafine Particulate Matter

A complementary computational and experimental study is carried out on the formation of ultrafine particulate matter in premixed laminar methane air flames. Specifically, soot formation is examined in premixed stretch-stabilized flames to observe soot inception and growth at relatively high flame temperatures common to oxygen enriched applications. Particle size distribution functions (PSDF) measured by mobility sizing show clear trends as the equivalence ratio increases from Φ = 2.2 to Φ = 2.4. For a given equivalence ratio, the measured distribution decreases in median mobility particle size as the maximum flame temperature increases from approximately 1950 K to 2050 K. The median mobility particle size is 20 nm or less for all flame conditions studied. The volume fraction decreases with increasing flame temperature for all equivalence ratio conditions. The Φ = 2.2 condition is close to the soot inception limit and both number density and volume fraction decrease monotonically with increasing flame temperature. The higher equivalence ratio conditions show a peak in number density at 2000 K which may indicate competing soot inception processes are optimized at this temperature. Flame structure computations are carried out using detailed gas-phase combustion chemistry of the Appel, Bockhorn, Frenklach (ABF) model to examine the connection of the observed PSDF to soot precursor chemistry. Agreement between measured and computed flame standoff distances indicates that the ABF model could provide a reasonable prediction of the flame temperature and soot precursor formation for the flames currently studied. To the first order, the trends observed in the measured PSDF could be understood in terms of computed trends for the formation of benzene, naphthalene and other soot precursors. Results of the current study inform particulate matter behavior for methane and natural gas combustion applications at elevated temperature and oxygen enriched conditions.

scholarly journals Ultrafine Particulate Matter in Methane-Air Premixed Flames With Oxygen Enrichment

2021 ◽  
Vol 7 ◽  
Author(s):  
Shruthi Dasappa ◽  
Joaquin Camacho
Keyword(s):  
Particle Size ◽  
Particulate Matter ◽  
Equivalence Ratio ◽  
Volume Fraction ◽  
Soot Formation ◽  
Flame Temperature ◽  
Number Density ◽  
Soot Precursors ◽  
Soot Precursor ◽  
Ultrafine Particulate Matter

A complementary computational and experimental study is carried out on the formation of ultrafine particulate matter in premixed laminar methane air flames. Specifically, soot formation is examined in premixed stretch-stabilized flames to observe soot inception and growth at relatively high flame temperatures common to oxygen enriched applications. Particle size distribution functions (PSDF) measured by mobility sizing show clear trends as the equivalence ratio increases from Φ = 2.2 to Φ = 2.4. For a given equivalence ratio, the measured distribution decreases in median mobility particle size as the maximum flame temperature increases from approximately 1,950–2,050 K. The median mobility particle size is 20 nm or less for all flame conditions studied. The volume fraction decreases with increasing flame temperature for all equivalence ratio conditions. The Φ = 2.2 condition is close to the soot inception limit and both number density and volume fraction decrease monotonically with increasing flame temperature. The higher equivalence ratio conditions show a peak in number density at 2,000 K which may indicate competing soot inception processes are optimized at this temperature. Flame structure computations are carried out using detailed gas-phase combustion chemistry of the Appel, Bockhorn, Frenklach (ABF) model to examine the connection of the observed PSDF to soot precursor chemistry. Agreement between measured and computed flame standoff distances indicates that the ABF model could provide a reasonable prediction of the flame temperature and soot precursor formation for the flames currently studied. To the first order, the trends observed in the measured PSDF could be understood in terms of computed trends for the formation of benzene, naphthalene and other soot precursors. Results of the current study inform particulate matter behavior for methane and natural gas combustion applications at elevated temperature and oxygen enriched conditions.

scholarly journals Monte Carlo simulation for soot dynamics

2012 ◽  
Vol 16 (5) ◽  
pp. 1391-1394 ◽  
Author(s):  
Kun Zhou
Keyword(s):  
Particle Size ◽  
Monte Carlo ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Gas Phase ◽  
Volume Fraction ◽  
Soot Formation ◽  
Bimodal Distribution ◽  
Number Density ◽  
Stochastic Error

A new Monte Carlo method termed Comb-like frame Monte Carlo is developed to simulate the soot dynamics. Detailed stochastic error analysis is provided. Comb-like frame Monte Carlo is coupled with the gas phase solver Chemkin II to simulate soot formation in a 1-D premixed burner stabilized flame. The simulated soot number density, volume fraction, and particle size distribution all agree well with the measurement available in literature. The origin of the bimodal distribution of particle size distribution is revealed with quantitative proof.

scholarly journals Raman spectroscopy, mobility size and radiative emissions data for soot formed at increasing temperature and equivalence ratio in flames hotter than conventional combustion applications

2021 ◽  
Author(s):  
Shruthi Dasappa ◽  
Joaquin Camacho
Keyword(s):  
Particle Size ◽  
Equivalence Ratio ◽  
Carbon Nanomaterials ◽  
Soot Formation ◽  
Flame Temperature ◽  
Growth Environment ◽  
Conventional Combustion ◽  
Structural Order ◽  
Color Ratio ◽  
Research Article

The dataset presented in this article is linked to the research article titled “Evolution in size and structural order for incipient soot formed at flame temperatures greater than 2100 K” [1]. The research article discusses the systematic evolution of flame formed carbon in premixed stagnation flames with flame temperatures hotter than conventional combustion applications. The effect of the growth environment on particle size, structure, composition and properties are studied. The flame temperature (1950 K < Tf,max < 2250 K) and equivalence ratio (Φ = 2.4, 2.5, and 2.6) are methodically varied to analyze impact on insipient soot while maintaining a comparable particle residence time (tp ~ 15 ms). This article presents the data acquired for this systematic study. The data presented herein provides fundamental observations suitable for development of soot formation theory and modeling. Characterization of material properties and morphology are also relevant to potential applications of functional carbon nanomaterials. Raman spectra are measured for carbon films deposited from the flames, soot particle size distributions are obtained by aerosol sampling from the flames and soot radiative emissions are measured in-situ by color-ratio pyrometry. Deconvolution of Raman peaks is carried out to extract information on carbon bonding and structural order. Flame temperature is extracted from the measured color-ratio field making assumptions for the soot optical dispersion exponent.

A Numerical Study on the Influence of Hydrogen Addition on Soot Formation in a Laminar Aviation Kerosene (Jet A1) Flame at Elevated Pressure

2021 ◽  
Author(s):  
Mingshan Sun ◽  
Zhiwen Gan
Keyword(s):  
Volume Fraction ◽  
Soot Formation ◽  
Laminar Flame ◽  
Numerical Study ◽  
Soot Volume Fraction ◽  
Elevated Pressure ◽  
Condensation Process ◽  
Hydrogen Addition ◽  
Aviation Kerosene ◽  
Soot Precursor

Abstract The hydrogen addition is a potential way to reduce the soot emission of aviation kerosene. The current study analyzed the effect of hydrogen addition on aviation kerosene (Jet A1) soot formation in a laminar flame at elevated pressure to obtain a fundamental understanding of the reduced soot formation by hydrogen addition. The soot formation of flame was simulated by CoFlame code. The soot formation of kerosene-nitrogen-air, (kerosene + replaced hydrogen addition)-nitrogen-air, (kerosene + direct hydrogen addition)-nitrogen-air and (kerosene + direct nitrogen addition)-nitrogen-air laminar flames were simulated. The calculated pressure includes 1, 2 and 5 atm. The hydrogen addition increases the peak temperature of Jet A1 flame and extends the height of flame. The hydrogen addition suppresses the soot precursor formation of Jet A1 by physical dilution effect and chemical inhibition effect, which weaken the poly-aromatic hydrocarbon (PAH) condensation process and reduce the soot formation. The elevated pressure significantly accelerates the soot precursor formation and increases the soot formation in flame. Meanwhile, the ratio of reduced soot volume fraction to base soot volume fraction by hydrogen addition decreases with the increase of pressure, indicating that the elevated pressure weakens the suppression effect of hydrogen addition on soot formation in Jet A1 flame.

Soot and PAH Formation Characteristics in a Micro Flow Reactor With a Controlled Temperature Profile

2011 ◽  
Author(s):  
Ryu Tanimoto ◽  
Takuya Tezuka ◽  
Susumu Hasegawa ◽  
Hisashi Nakamura ◽  
Kaoru Maruta
Keyword(s):  
Flow Velocity ◽  
Temperature Profile ◽  
Mole Fraction ◽  
Equivalence Ratio ◽  
Flow Reactor ◽  
Volume Fraction ◽  
Soot Formation ◽  
Soot Volume Fraction ◽  
Low Flow ◽  
Micro Flow

To examine soot and PAH formation processes for rich methane/air and acetylene/air mixtures, a micro flow reactor with a controlled temperature profile was employed. In the experiment for a methane/air mixture, four kinds of responses to the variations of flow velocity and equivalence ratio were observed as follows: soot formation without a flame; a flame with soot formation; a flame without soot formation; and neither flame nor soot formation. Soot formations were observed in low flow velocity and high equivalence ratio. Starting point of soot formation shifted to the upstream side, i.e., low-temperature side, of the micro flow reactor with the decrease of flow velocity. One-dimensional steady-state computation was conducted by a flame code. In high flow velocity, low mole fraction of C2H2 and high mole fraction of OH were observed in the whole region of the micro flow reactor. Soot volume fraction did not increase in this case. On the other hand, in low flow velocity, high mole fraction of C2H2 and low mole fraction of OH were observed at the downstream side of the micro flow reactor. Soot volume fraction increased in this case. Since significant soot formation was observed at the low flow velocity and the high equivalence ratio, experiments with gas sampling were conducted for acetylene/air mixture to investigate temperature and equivalence ratio dependence of soot precursor production in such condition. Volume fractions of benzene increased with an increase of temperature. They were larger at higher equivalence ratio at the same temperature. Volume fractions of styrene increased with an increase of temperature. They were larger at higher equivalence ratio when the temperature is less than 1000 K. However the tendency was changed at 1000 K, styrene volume fraction at equivalence ratio of 7.0 was larger than that at equivalence ratio of 8.0.

Mechanism of smokeless diesel combustion with oxygenated fuels based on the dependence of the equivalence ration and temperature on soot particle formation

2002 ◽  
Vol 3 (4) ◽  
pp. 223-248 ◽  
Author(s):  
T Kitamura ◽  
T Ito ◽  
J Senda ◽  
H Fujimoto
Keyword(s):  
Fine Particles ◽  
Volume Fraction ◽  
Soot Formation ◽  
Particle Diameter ◽  
Soot Volume Fraction ◽  
Diesel Combustion ◽  
Number Density ◽  
Particulate Size ◽  
Lower Temperature ◽  
Ultra Fine Particles

The equivalence ratio φ and temperature T are well known to have a significant effect on the quality of particulate formation, such as the soot volume fraction, particle diameter and number density. The purpose of this work is to clarify the φ-T dependence of soot formation for various kinds of fuels, including paraffinic hydrocarbon, aromatic hydrocarbon and oxygenated hydrocarbon, and to discuss a possibility for smokeless diesel combustion considering particulate size and number density. The sooting φ-T map, showing the tendency to generate soot particles as a function of φ-T and T, was made using a detailed soot kinetic model. The computational results show that oxygenated fuel reactions lead to a lower soot yield, smaller particle diameter, lower number density and narrower sooting φ-T region than those of aliphatic and aromatic fuels, due to the notable reduction in production of both acetylene and polycyclic aromatic hydrocarbons (PAHs). Furthermore, this lower sooting tendency is emphasized as the fuel oxygen content increases. It was also found that the leaner mixture side of the soot formation peninsula on the φ-T map, rather than the lower temperature side, should be utilized to suppress the formation of PAHs and ultra-fine particles together with a large reduction in particulate mass.

scholarly journals Stochastic Simulation of Soot Formation Evolution in Counterflow Diffusion Flames

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Xiao Jiang ◽  
Kun Zhou ◽  
Ming Xiao ◽  
Ke Sun ◽  
Yu Wang
Keyword(s):  
Nozzle Exit ◽  
Volume Fraction ◽  
Diffusion Flames ◽  
Soot Formation ◽  
Hydrocarbon Fuels ◽  
Number Density ◽  
Exit Velocity ◽  
Soot Particles ◽  
Counterflow Diffusion Flames ◽  
Nozzle Exit Velocity

Soot generally refers to carbonaceous particles formed during incomplete combustion of hydrocarbon fuels. A typical simulation of soot formation and evolution contains two parts: gas chemical kinetics, which models the chemical reaction from hydrocarbon fuels to soot precursors, that is, polycyclic aromatic hydrocarbons or PAHs, and soot dynamics, which models the soot formation from PAHs and evolution due to gas-soot and soot-soot interactions. In this study, two detailed gas kinetic mechanisms (ABF and KM2) have been compared during the simulation (using the solver Chemkin II) of ethylene combustion in counterflow diffusion flames. Subsequently, the operator splitting Monte Carlo method is used to simulate the soot dynamics. Both the simulated data from the two mechanisms for gas and soot particles are compared with experimental data available in the literature. It is found that both mechanisms predict similar profiles for the gas temperature and velocity, agreeing well with measurements. However, KM2 mechanism provides much closer prediction compared to measurements for soot gas precursors. Furthermore, KM2 also shows much better predictions for soot number density and volume fraction than ABF. The effect of nozzle exit velocity on soot dynamics has also been investigated. Higher nozzle exit velocity renders shorter residence time for soot particles, which reduces the soot number density and volume fraction accordingly.

A Numerical and Experimental Study of Soot Precursor and Primary Particle Size of N-Butylbenzene in Laminar Flame

2021 ◽  
Author(s):  
Mingshan Sun ◽  
Zhiwen Gan
Keyword(s):  
Soot Particle ◽  
Primary Particle ◽  
Volume Fraction ◽  
Soot Formation ◽  
Laminar Flame ◽  
Particle Diameter ◽  
Soot Volume Fraction ◽  
The Core ◽  
Soot Precursor ◽  
Combined Mechanism

Abstract The current study analyzed the soot precursor of the n-butylbenzene found in diesel and kerosene in laminar flame, and integrated the corresponding poly-aromatic hydrocarbon (PAH) growth mechanism with the popular n-butylbenzene oxidation mechanisms to improve the soot formation prediction of n-butylbenzene. The size of soot precursor was determined by the fringe length in the core of soot particle since the nanostructure of the core of soot particle is similar with that of nascent soot particle formed by soot precursor nucleation. The geometric mean fringe length in core of soot particles was measured to be 0.67 nm approximating to the size of five-ringed PAH (A5). An A5 growth mechanism was added on a popular n-butylbenzene mechanism, and the combined mechanism was further reduced. After validation by the ignition delay time in literature, the combined mechanism was then validated by the primary particle diameter in laboratory and soot volume fraction of n-propylbenzene in literature. The calculated soot precursor concentration and PAH condensation rate of the combined mechanism are smaller than that of the base mechanism. The simulated primary soot particle diameter of proposed combined mechanism agrees well with the measure primary soot particle diameter. Comparing to the simulated soot volume fraction of base n-butylbenzene mechanism, the simulated soot volume fraction of proposed combined n-butylbenzene-A5 mechanism agrees well with the measure soot volume fraction of n-propylbenzene in literature. This study provides certain support for further investigation of soot formation of n-butylbenzene and its relative fuel like diesel and kerosene.

scholarly journals Fuel Molecular Structure and Flame Temperature Effects on Soot Formation in Gas Turbine Combustors

1990 ◽  
Vol 112 (1) ◽  
pp. 52-59 ◽  
Author(s):  
O¨. L. Gu¨lder ◽  
B. Glavincˇevski ◽  
M. F. Baksh
Keyword(s):  
Molecular Structure ◽  
Volume Fraction ◽  
Diffusion Flames ◽  
Soot Formation ◽  
Empirical Relationship ◽  
Flame Temperature ◽  
Soot Volume Fraction ◽  
Smoke Point ◽  
Temperature Fields ◽  
Diesel Fuels

A systematic study of soot formation along the centerlines of axisymmetric laminar diffusion flames of a large number of liquid hydrocarbons, hydrocarbon blends, and aviation turbine and diesel fuels was made. Measurements of the attenuation of a laser beam across the flame diameter were used to obtain the soot volume fraction, assuming Rayleigh extinction. Two sets of hydrocarbon blends were designed such that the molecular fuel composition varied considerably but the temperature fields in the flames were kept practically constant. Thus it was possible to separate the effects of molecular structure and the flame temperature on soot formation. It was quantitatively shown that the smoke point height is a lumped measure of fuel molecular constitution. The developed empirical relationship between soot volume fractions and fuel smoke point and hydrogen-to-carbon ratio was applied to five different combustor radiation data, and good agreement was obtained.

Investigation of Flame Structure and Soot Formation in a Single Sector Model Combustor Using Experiments and Numerical Simulations Based on the LES/CMC Approach

2017 ◽  
Author(s):  
Andrea Giusti ◽  
Epaminondas Mastorakos ◽  
Christoph Hassa ◽  
Johannes Heinze ◽  
Eggert Magens ◽  
...  
Keyword(s):  
Numerical Simulations ◽  
Volume Fraction ◽  
Soot Formation ◽  
Flame Structure ◽  
Soot Volume Fraction ◽  
Moment Closure ◽  
Quantitative Prediction ◽  
Lean Burn ◽  
Soot Precursors ◽  
Wide Range

In this work a single sector lean burn model combustor operating in pilot only mode has been investigated using both experiments and computations with the main objective of analyzing the flame structure and soot formation at conditions relevant to aero-engine applications. Numerical simulations were performed using the Large Eddy Simulation (LES) approach and the Conditional Moment Closure (CMC) combustion model with detailed chemistry and a two-equation model for soot. The CMC model is based on the time-resolved solution of the local flame structure and allows to directly take into account the phenomena associated to molecular mixing and turbulent transport which are of great importance for the prediction of emissions. The rig investigated in this work, called Big Optical Single Sector (BOSS) rig, allows to test real scale lean burn injectors. Experiments, performed at elevated pressure and temperature, corresponding to engine conditions at part load, include OH-PLIF and PDA and have been complemented with new LII measurements for soot location. The wide range of measurements available allows a comprehensive analysis of the primary combustion region and can be exploited to further assess and validate the LES/CMC approach to capture the flame behaviour at engine conditions. It is shown that the LES/CMC approach is able to predict the main characteristics of the flame with a good agreement with the experiment in terms of flame shape, spray characteristics and soot location. Finite-rate chemistry effects appear very important in the region very close to the injector exit leading to the lift-off of the flame. Low levels of soot are observed immediately downstream of the injector exit, where a high amount of vaporized fuel is still present. Further downstream, the fuel vapour disappears quite quickly and an extended region characterised by the presence of pyrolysis products and soot precursors is observed. The strong production of soot precursors together with high soot surface growth rates lead to high values of soot volume fraction in locations consistent with the experiment. Soot oxidation is also very important in the downstream region resulting in a decrease of the soot level at the combustor exit. The results show a very promising capability of the LES/CMC approach to capture the main characteristics of the flame, soot formation and location at engine relevant conditions. More advanced soot models will be considered in future work in order to improve the quantitative prediction of the soot level.

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