scholarly journals MODELING SOIL PH FATE IN CRUDE OIL CONTAMINATED SOIL IN THE NIGER DELTA

2018 ◽  
Vol VI (XI) ◽  
Author(s):  
N. L. Nwakwasi ◽  
J. C. Osuagwu ◽  
B. U. Dike ◽  
H. U. Nwoke ◽  
J. C. Agunwamba
2009 ◽  
Vol 62-64 ◽  
pp. 451-455 ◽  
Author(s):  
F.A. Aisien ◽  
J.C. Chiadikobi ◽  
E.T. Aisien

This paper considered the toxicity assessment of some crude oil contaminated soils in Niger Delta areas. The soil samples were collected from different horizontal distances, vertical depths and contaminated soil of different ages. The heavy metals in the contaminated soils were digested and extracted using di-acid digested and DTPA extraction methods respectively. The physiochemical parameters (moisture content, pH, N, P and heavy metals (Ni, Pb and Cd) were analysed with APHA method. The heavy metals concentration was determined using atomic absorption spectrophotometer (AAS). The results show that the metals concentration decreased with the age of the contaminated soil and with increased vertical depths. However, the metals concentrations were almost constant at different horizontal distances. Similar trend was observed for the moisture content, pH, N, P and K.


2019 ◽  
Vol 4 (3) ◽  
pp. 93-96
Author(s):  
LEVI NGOZI NWAKWASI ◽  
B. C. Okoro ◽  
J. C. Osuagwu ◽  
A. N. Nwachukwu ◽  
J. C. Agunwamba

Oil spillage is a major environmental threat in south south of Nigeria where most of oil exploration and exploitation activities takes place. If this goes on unchecked or poorly managed, it would lead to total annihilation of the ecosystem. The objective of this study is to develop a model for the prediction of potassium depletion in the crude oil contaminated soil with time using regression analysis. Each sample containing 10kg of soil was artificially polluted with 0.5, 1.0, 1.5, 2.0, and 2.5 liters of crude oil (Bonny Light).  The potassium concentrations were determined using standard methods. Results shows that the concentration of residual potassium in the soil for all the volumes of crude oil introduced into the soil decrees significantly with time when compared to values obtained for the control samples. The concentration of residual concentration in the control soil sample was about three times higher than the concentration obtained for other samples. The results obtained from the derived model were very close to the experimental value. The model is suitable for determining potassium content in crude oil polluted site.


2020 ◽  
pp. 21-34
Author(s):  
Uche-Chinemere NWAOZUZU ◽  
Ifeanyichukwu ABADA ◽  
Emeka ANIAGO

This study presents an interdisciplinary approach towards a critical analysis of some impacts of crude-oil exploration in Niger Delta and polemics of viable conϐlict resolution framework. This approach involves analysis of Ahmed Yerima’s creative portrayal in Hard Ground which revolves around the variables activating conϐlicting emotional interests in matters concerning ‘black gold’ in Nigeria, and how these variables resonant in debates and demands for Nigeria’s polity restructuring because of perceived resource mismanagement. More so, our scope includes an analytical attempt at illuminating elaborately our interpretation of the dimensions to the loud and shrewd inclinations subsuming what some see as solution to the lingering conϐlict, and the suppositions explaining why others see the debates and demands on polity restructuring as dark convoluted ploys aimed at hidden agenda. Hence, through select theories of victimhood, this study attempts to elucidate on the variables propelling conϐlicting emotional interestsabout oil exploration in Niger Delta, by looking interpretively hard and deep on the perspectives, views and suppositions deϐining the ideologies and inclinations propelling them. In the end, this study notes that the disenchantments and troubles with Nigeria’s polity framework and structure as it relates to oil exploration in Niger Delta are subsumed in Hard Ground’s creativecontribution as a means of assessing the points to the fault-lines that characterize the subsisting socio-political structure upon which Nigeria stands and wobbles.


Biomolecules ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 448
Author(s):  
Mahrous Awad ◽  
Zhongzhen Liu ◽  
Milan Skalicky ◽  
Eldessoky S. Dessoky ◽  
Marian Brestic ◽  
...  

Heavy metals (HMs) toxicity represents a global problem depending on the soil environment’s geochemical forms. Biochar addition safely reduces HMs mobile forms, thus, reducing their toxicity to plants. While several studies have shown that biochar could significantly stabilize HMs in contaminated soils, the study of the relationship of soil properties to potential mechanisms still needs further clarification; hence the importance of assessing a naturally contaminated soil amended, in this case with Paulownia biochar (PB) and Bamboo biochar (BB) to fractionate Pb, Cd, Zn, and Cu using short sequential fractionation plans. The relationship of soil pH and organic matter and its effect on the redistribution of these metals were estimated. The results indicated that the acid-soluble metals decreased while the fraction bound to organic matter increased compared to untreated pots. The increase in the organic matter metal-bound was mostly at the expense of the decrease in the acid extractable and Fe/Mn bound ones. The highest application of PB increased the organically bound fraction of Pb, Cd, Zn, and Cu (62, 61, 34, and 61%, respectively), while the BB increased them (61, 49, 42, and 22%, respectively) over the control. Meanwhile, Fe/Mn oxides bound represents the large portion associated with zinc and copper. Concerning soil organic matter (SOM) and soil pH, as potential tools to reduce the risk of the target metals, a significant positive correlation was observed with acid-soluble extractable metal, while a negative correlation was obtained with organic matter-bound metal. The principal component analysis (PCA) shows that the total variance represents 89.7% for the TCPL-extractable and HMs forms and their relation to pH and SOM, which confirms the positive effect of the pH and SOM under PB and BB treatments on reducing the risk of the studied metals. The mobility and bioavailability of these metals and their geochemical forms widely varied according to pH, soil organic matter, biochar types, and application rates. As an environmentally friendly and economical material, biochar emphasizes its importance as a tool that makes the soil more suitable for safe cultivation in the short term and its long-term sustainability. This study proves that it reduces the mobility of HMs, their environmental risks and contributes to food safety. It also confirms that performing more controlled experiments, such as a pot, is a disciplined and effective way to assess the suitability of different types of biochar as soil modifications to restore HMs contaminated soil via controlling the mobilization of these minerals.


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