Strength and Transport Properties of Concretes Modified with Coarse Limestone Powder to Compensate for Dilution Effects

2012 ◽  
Vol 2290 (1) ◽  
pp. 130-138 ◽  
Author(s):  
Narayanan Neithalath ◽  
Hieu T. Cam

The use of a coarse limestone powder (median particle size of approximately 70 μm, five times larger than cement particles) as a cement replacement material results in a dilution effect. The magnitude of strength and transport property reduction is found to be greater than the magnitude of the cement replacement level. In this paper, methodologies to proportion concrete containing 10% to 15% of coarse limestone powder, in which the dilution effect is compensated through a combination of reduction in water-to-powder ratio and addition of 5% of silica fume, are discussed. Limestone–silica fume blended concretes at a reduced water-to-powder ratio (0.37 or 0.34, depending on limestone replacement level) show similar or higher 56-day compressive strengths than does the benchmark plain concrete with a water-to-cement ratio of 0.40. The rapid chloride permeability and non–steady state migration values of the modified concretes are evaluated along with their pore structure parameter extracted from electrical impedance data. The impact of water-to-powder reduction and silica fume incorporation is quantified through this pore structure parameter.

Materials ◽  
2020 ◽  
Vol 13 (19) ◽  
pp. 4248
Author(s):  
Xingxing Li ◽  
Ying Ma ◽  
Xiaodong Shen ◽  
Ya Zhong ◽  
Yuwei Li

The utilization of coral waste is an economical way of using concrete in coastal and offshore constructions. Coral waste with more than 96% CaCO3 can be ground to fines and combined with supplementary cementitious materials (SCMs) such as fly ash, silica fume, granulated blast furnace slag in replacing Portland cement to promote the properties of cement concrete. The effects of coral sand powder (CSP) compared to limestone powder (LSP) blended with SCMs on hydration and microstructure of mortar were investigated. The result shows CSP has higher activity than LSP when participating in the chemical reaction. The chemical effect among CSP, SCMs, and ordinary Portland cement (OPC) results in the appearance of the third hydration peak, facilitating the production of carboaluminate. CSP-SCMs mortar has smaller interconnected pores on account of the porous character of CSP as well as the filler and chemical effect. The dilution effect of CSP leads to the reduction of compressive strength of OPC-CSP and OPC-CSP-SCMs mortars. The synergic effects of CSP with slag and silica fume facilitate the development of compressive strength and lead to a compacted isolation and transfer zone (ITZ) in mortar.


2018 ◽  
Vol 6 (4) ◽  
pp. SM1-SM8 ◽  
Author(s):  
Tingting Zhang ◽  
Yuefeng Sun

Fractured zones in deeply buried carbonate hills are important because they often have better permeability resulting in prolific production than similar low-porosity rocks. Nevertheless, their detection poses great challenge to conventional seismic inversion methods because they are mostly low in acoustic impedance and bulk modulus, hardly distinguishable from high-porosity zones or mudstones. A proxy parameter of pore structure defined in a rock-physics model, the so-called Sun model, has been used for delineating fractured zones in which the pore structure parameter is relatively high, whereas the porosity is low in general. Simultaneous seismic inversion of the pore structure parameter and porosity proves to be difficult and nontrivial in practice. Although the pore structure parameter is well-defined at locations where density, P-, and S-velocity are known from logs, estimation of P- and S-velocity information, especially density information from prestack seismic data is rather challenging. A three-step iterative inversion method, which uses acoustic, gradient, and elastic impedance from angle-stacked seismic data as input to the rock-physics model for calculating porosity and bulk and shear pore structure parameters simultaneously, is proposed and implemented to solve this problem. The methodology is successfully tested with well logs and seismic data from a deeply buried carbonate hill in the Bohai Bay Basin, China.


2018 ◽  
Vol 6 (4) ◽  
pp. SM9-SM17 ◽  
Author(s):  
Tingting Zhang ◽  
Ruifeng Zhang ◽  
Jianzhang Tian ◽  
Lifei Lu ◽  
Fengqi Qin ◽  
...  

Fractures and fracture-related dissolution pores, as well as cavities, molds, and vugs, provide the major conduit and/or storage space for hydrocarbons in the deeply buried carbonate hill of Hexiwu field, Bohai Bay Basin. The fractured reservoir generally has lower porosity but better permeability than moldic/vuggy reservoir, and it consists of the major part of the buried-hill slope and buried-hill internal reservoirs. The conventional method of characterizing carbonate reservoirs, however, often mixes these two types of reservoirs together because they both have low acoustic impedance and low bulk modulus. The rock-physics analysis of two field wells indicates that a pore-structure parameter defined in a rock-physics model, the so-called Sun model, can help to distinguish the fractured reservoir zones together with porosity. Fractured zones usually have porosity of less than 5% and a pore-structure parameter of greater than six, whereas moldic/vuggy reservoirs of higher porosity have a pore-structure parameter of less than six. Field-scale application demonstrates that simultaneous prestack seismic inversion for the porosity and pore-structure parameter enables 3D mapping of fractured reservoir zones in the buried carbonate hills. It also provides an analog of detecting fractures and/or fracture-related pores in deeply buried carbonates in similar geologic settings.


Materials ◽  
2021 ◽  
Vol 14 (18) ◽  
pp. 5464
Author(s):  
Linglin Xu ◽  
Siyu Liu ◽  
Peiming Wang ◽  
Zhenghong Yang

Efflorescence is aesthetically undesirable to all cementitious materials products and mainly results from the carbonation of hydrates and salt precipitation. Alternative binders without portlandite formation theoretically have much lower efflorescence risk, but in practice, the efflorescence of ettringite-rich systems is still serious. This study reports the impacts of mineral additives on the efflorescence of ettringite-rich systems and the corresponding microstructural evolution. The effects of silica fume, limestone powder, and diatomite on efflorescence and the capillary pore structure of mortars were investigated from a multi-scale analysis. The composition and microstructure of efflorescent phases were revealed by optical microscope (O.M.), in-situ Raman spectroscopy, and Scanning Electron Microscopy (SEM). Results indicate that the addition of mineral additives can efficiently inhibit the efflorescence of reference, especially with silica fume. Similar to the ettringite-rich system, the efflorescence substances of all modifies are composed of ettringite and CaCO3, indicating that the addition of mineral admixture does not lead to chemical reactions, lower capillary absorption coefficient of mineral additives modified specimen, the denser pore structure and the lower efflorescence degree.


2020 ◽  
Vol 71 (7) ◽  
pp. 775-788
Author(s):  
Quyet Truong Van ◽  
Sang Nguyen Thanh

The utilisation of supplementary cementitious materials (SCMs) is widespread in the concrete industry because of the performance benefits and economic. Ground granulated blast furnace slag (GGBFS) and fly ash (FA) have been used as the SCMs in concrete for reducing the weight of cement and improving durability properties. In this study, GGBFS at different cement replacement ratios of 0%, 20%, 40% and 60% by weight were used in fine-grained concrete. The ternary binders containing GGBFS and FA at cement replacement ratio of 60% by weight have also evaluated. Flexural and compressive strength test, rapid chloride permeability test and under-water abrasion test were performed. Experimental results show that the increase in concrete strength with GGBFS contents from 20% to 40% but at a higher period of maturity (56 days and more). The chloride permeability the under-water abrasion reduced with the increasing cement replacement by GGBFS or a combination of GGBFS and FA


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