Digital Rock Typing DRT Algorithm Formulation with Optimal Supervised Semantic Segmentation

<p><a></a>Each grid block in a 3D geological model requires a rock type that represents all physical and chemical properties of that block. The properties that classify rock types are lithology, permeability, and capillary pressure. Scientists and engineers determined these properties using conventional laboratory measurements, which embedded destructive methods to the sample or altered some of its properties (i.e., wettability, permeability, and porosity) because the measurements process includes sample crushing, fluid flow, or fluid saturation. Lately, Digital Rock Physics (DRT) has emerged to quantify these properties from micro-Computerized Tomography (uCT) and Magnetic Resonance Imaging (MRI) images. However, the literature did not attempt rock typing in a wholly digital context. We propose performing Digital Rock Typing (DRT) by: (1) integrating the latest DRP advances in a novel process that honors digital rock properties determination, while; (2) digitalizing the latest rock typing approaches in carbonate, and (3) introducing a novel carbonate rock typing process that utilizes computer vision capabilities to provide more insight about the heterogeneous carbonate rock texture.<br></p>

Digital Rock Typing DRT Algorithm Formulation with Optimal Supervised Semantic Segmentation

<p><a></a>Each grid block in a 3D geological model requires a rock type that represents all physical and chemical properties of that block. The properties that classify rock types are lithology, permeability, and capillary pressure. Scientists and engineers determined these properties using conventional laboratory measurements, which embedded destructive methods to the sample or altered some of its properties (i.e., wettability, permeability, and porosity) because the measurements process includes sample crushing, fluid flow, or fluid saturation. Lately, Digital Rock Physics (DRT) has emerged to quantify these properties from micro-Computerized Tomography (uCT) and Magnetic Resonance Imaging (MRI) images. However, the literature did not attempt rock typing in a wholly digital context. We propose performing Digital Rock Typing (DRT) by: (1) integrating the latest DRP advances in a novel process that honors digital rock properties determination, while; (2) digitalizing the latest rock typing approaches in carbonate, and (3) introducing a novel carbonate rock typing process that utilizes computer vision capabilities to provide more insight about the heterogeneous carbonate rock texture.<br></p>

Chemical Compositions in Modified Salinity Waterflooding of Calcium Carbonate Reservoirs: Experiment

Modified or low-salinity waterflooding of carbonate oil reservoirs is of considerable economic interest because of potentially inexpensive incremental oil production. The injected modified brine changes the surface chemistry of the carbonate rock and crude oil interfaces and detaches some of adhered crude oil. Composition design of brine modified to enhance oil recovery is determined by labor-intensive trial-and-error laboratory corefloods. Unfortunately, limestone, which predominantly consists of aqueous-reactive calcium carbonate, alters injected brine composition by mineral dissolution/precipitation. Accordingly, the rock reactivity hinders rational design of brines tailored to improve oil recovery. Previously, we presented a theoretical analysis of 1D, single-phase brine injection into calcium carbonate-rock that accounts for mineral dissolution, ion exchange, and dispersion (Yutkin et al. in SPE J 23(01):084–101, 2018. 10.2118/182829-PA). Here, we present the results of single-phase waterflood-brine experiments that verify the theoretical framework. We show that concentration histories eluted from Indiana limestone cores possess features characteristic of fast calcium carbonate dissolution, 2:1 ion exchange, and high dispersion. The injected brine reaches chemical equilibrium inside the porous rock even at injection rates higher than 3.5 $$\times$$ × 10$$^{-3}$$ - 3 m s$$^{-1}$$ - 1 (1000 ft/day). Ion exchange results in salinity waves observed experimentally, while high dispersion is responsible for long concentration history tails. Using the verified theoretical framework, we briefly explore how these processes modify aqueous-phase composition during the injection of designer brines into a calcium-carbonate reservoir. Because of high salinity of the initial and injected brines, ion exchange affects injected concentrations only in high surface area carbonates/limestones, such as chalks. Calcium-carbonate dissolution only affects aqueous solution pH. The rock surface composition is affected by all processes.

Development model of rock relief on thick horizontal and gently sloping rock strata exposed to rain

Due to various factors influencing diverse rocks, karst phenomena take unique shapes that are most often reflected in the rock relief. Through a series of different developmental factors, new factors first gradually transform the traces of old formations and over time, if they are distinct enough, they can replace them with completely new ones. In places old forms are reflected in the formation of a new rock relief only indirectly. The rock relief of karst phenomena, in this case karren, also develops under the influence of a single factor. Developmentally, rock forms, due to dissection of the surface and lasting of development, often in several layers merge into one another. A development model enables us to discover the overall development of the formation of the selected part of the rocky karst surface. The individual rock forms which have merged into the rock relief represent just one stage of development. Good knowledge of the overall development enables us to discern the development so far and predict future development. A number of development models can be discerned. One of the basic models reveals the manner of the rain-induced formation and development of horizontal and gently sloping carbonate rock strata into karren and stone forests, especially after the disintegration of the upper (thinner) rock strata and the denudation and shaping of the bottom strata. It reveals many characteristics of rock formation, from the sheet flow to the formation of rain flutes, their merging into rain channels and the development of funnel-like notches; that is, developmental transition of rock forms and rock relief in the overall development from the flat surface to its dissection into peaks.

Polymer in-Situ Rheology in Carbonate Reservoirs

A large, untapped EOR potential may be extracted by extending polymer flooding to carbonate reservoirs. However, several challenges are encountered in carbonates due to generally more heterogeneous rock and lower permeability. In addition, high salinity may lead to high polymer retention. Here we show how in-situ viscosity varies with permeability and heterogeneity in carbonate rock from analysis of core flood results and combined with review of data available in literature. In-situ rheology experiments were performed on both carbonate outcrop and reservoir cores with a range in permeabilities. The polymer used was a high ATBS content polyacrylamide (SAV10) which tolerates high temperature and high salinity. Some cores were aged with crude oil to generate non-water-wet, reservoir representative wettability conditions. These results are compared to a compilation of literature data on in-situ rheology for predominantly synthetic polymers in various carbonate rock. A systematic approach was utilized to derive correlations for resistance factor, permeability reduction and in-situ viscosity as a function of rock and polymer properties. Polymer flooding is applied to improve sweep efficiency that may occur due to reservoir heterogeneities (large permeability contrasts, anisotropy, thief zones) or adverse mobility ratio (high mobility contrast oil-brine). In flooding design, the viscosity of the polymer solution in the reservoir, the in-situ viscosity, is an essential parameter as this is tuned to correct the mobility difference and to improve sweep. The viscosity is estimated from rheometer/viscometer measurements or, better, measured in laboratory core flood experiments. However, upscaling core flood experiments to field is challenging. Core flood experiments measure differential pressure, which is the basis for the resistance factor, RF, that describes the increased resistance to flow for polymer relative to brine. However, the pressure is also influenced by several other factors such as the permeability reduction caused by adsorption and retention of polymer in the rock, the tortuosity of the rock and the viscosity of the flowing polymer solution. Deduction of in-situ viscosity is straight forward using Darcy's law but the capillary bundle model that is the basis for applying this law fails for non-Newtonian fluids. This is particularly evident in carbonate rock. Interpretation of in-situ rheology experiments can therefore be misleading if the wrong assumptions are made. Polymer flooding in carbonate reservoirs has a large potential for increased utilization of petroleum reserves at a reduced CO2 footprint. In this paper we apply learnings from an extensive core flood program for a polymer flood project in the UAE and combine this with reported literature data to generate a basis for interpretation of in-situ rheology experiments in carbonates. Most importantly, we suggest a methodology to screen experiments and select data to be used as basis for modelling polymer flooding. This improves polymer flood design, optimize the polymer consumption, and thereby improve project economy and energy efficiency.

Simulation of Immiscible WAG Experiments Performed in Carbonate Rocks: The Impact of Heterogeneity on Hysteresis Phenomenon

Simulation of Water-Alternating-Gas (WAG) Experiments require precise estimation of hysteresis phenomenon in three-phase relative permeability. Most of the research available in the literature are focused on experiments performed on sandstone rocks and the study of carbonate rocks has attracted less attention. In this paper, a recently published hysteresis model by Heriot-Watt University (HWU) was used for simulation of WAG experiments conducted on mixed-wet homogenous carbonate rock. In this study, we simulated immiscible WAG experiments, which were performed under reservoir conditions on mixed-wet carbonate reservoir rock extracted from Abu Dhabi field by using real reservoir fluids. Experiments are performed with different injection scenarios and at high IFT conditions. Then, the results of the coreflood experiments were history matched using 3RPSim to generate two-phase and three-phase relative permeability data. Finally, the hysteresis model suggested by Heriot-Watt University was used for the estimation of hysteresis in relative permeability data. The performance of the model was compared with the experimental data from sandstones to evaluate the impact of heterogeneity on hysteresis phenomenon. It was shown that the available correlations for estimation of three-phase oil relative permeability fail to simulate the oil production during WAG experiments, while the modified Stone model suggested by HWU provided a better prediction. Overall, HWU hysteresis model improved the match for trapped gas saturation and pressure drop. The results show that the hysteresis effect is less dominant in the carbonate rock compared to the sandstone rock. The tracer test results show that the carbonate rock is more homogenous compared to sandstone rock. Therefore, the conclusion is that the hysteresis effect is negligible in homogenous systems.

Internal Structure Characteristics and Formation Mechanism of Reverse Fault in the Carbonate Rock, A Case Study of Outcrops in Xike’er Area, Tarim Basin, Northwest China

China’s Paleozoic deep carbonate effective reservoirs, mainly non-porous reservoirs, are generally formed under the interaction of late diagenesis, hydrothermal fluids, and structural fractures. Faults and their deformation mechanism and internal structure of fault zones play an important role in the formation of carbonate reservoirs and hydrocarbon accumulation. Based on the detailed analysis of outcrop data in Xike’er area, Tarim Basin, this paper systematically studies the deformation mechanism and internal structure of reverse fault in the carbonate rock, and discusses the reservoir characteristics, control factors and development rules. The study shows that the deformation mechanism of the fault in carbonate rocks is faulting and fracturing, and the dual structure of fault core and damage zone is developed. The fault core is mainly composed of fault breccia, fault gouge and calcite zone, and a large number of fractures are formed in the damage zone, which are cemented by calcite locally. The mineral composition and rare earth element tests show that the fault core has the dual effect of hydrothermal fluids and atmospheric fresh water, which is easy to be cemented by calcite; while the damage zone is dominated by atmospheric fresh water, which is a favorable zone for the development of fracture-vuggy reservoirs. Therefore, the damage zone is the “sweet spot” area of carbonate oil and gas enrichment, and generally shows strip distribution along the fault.

Effect of Total Acid Number and Recovery Mode on Low-Salinity Enhanced Oil Recovery in Carbonates

Summary Low-salinity water (LSW) flooding is an attractive enhanced oil recovery (EOR) option, but its mechanism leading to EOR is poorly understood, especially in carbonate rock. In this paper, we investigate the main reason behind two tertiary LSW coreflood tests that failed to demonstrate promising EOR response in reservoir carbonate rock; additional oil recovery factors by the LSW injection were only +2% and +4% oil initially in place. We suspected either the oil composition (lack of acid content) or the recovery mode (tertiary mode) was inappropriate. Therefore, we repeated the experiments using an acid-enriched oil sample and injected LSW in the secondary mode. The result showed that the low-salinity effect was substantially enhanced; the additional oil recovery factor by the tertiary LSW injection jumped to +23%. Moreover, it was also found that the secondary LSW injection was more efficient than the tertiary LSW injection, especially in the acid-enriched oil reservoir. In summary, it was concluded that the total acid number (TAN) and the recovery mode appear to be the key successful factors for LSW in our carbonate system. To support the conclusion, we also performed contact angle measurement and spontaneous imbibition tests to investigate the influence of acid enrichment on wettability, and moreover, LSW injection on wettability alteration.

A Method for Quantifying the Role of Carbonate Acid, Sulfuric Acid and Nitric Acid in Carbonate Weathering After Modifying the Effect of Evaporite in Qingjiang Karst Catchment

Qingjiang river is the second largest tributary of the Yangtze River in Hubei province, it’s also a typical karst catchment. Eighty-two important groundwater samples were collected during high and low water period of 2019. The results show that: (1) The major hydrochemistry types are Ca+Mg-HCO3 and Ca-HCO3, indicate that carbonate weathering is the main source of groundwater chemistry; (2) The results of inverse hydrochemical modeling show that there are two kinds of groundwater-carbonate rock interactions. One is co-dissolution of calcite and dolomite, the other is dedolomitization, and thereinto, dedolomitization is widespread in dolomite aquifers. Furthermore, gypsum has a tendency to dissolve in each aquifer, and the common ion effect of Ca2+ caused by gypsum dissolution promotes dedolomitization. The modeling results suggest that major elements have a good traceability effect on the material source of groundwater. (3) The chemical weathering of carbonate rock is mainly affected by carbonic acid, sulfuric acid and nitric acid. After modifying the impact of evaporite and atmospheric input, the calculations show that the contribution of carbonic acid involved in carbonate weathering is 70.9% (high water period) and 70.0% (low water period). Through statistics of karst springs discharge and contribution of acid involved in carbonate weathering, the two are in a positive relationship. The result can reflect the laws of sulfuric acid and nitric acid under the hydrodynamic condition in different seasons. Therefore, the carbonate weathering should be carefully evaluated in karst areas which have abundant groundwater and the role of groundwater in carbonate weathering is worthy of further study.