scholarly journals RESEARCH OF TECHNOLOGICAL PROPERTIES OF RUBBER MIXTURES BASED ON SYNTHETIC RUBBERS FILLED WITH CARBON-CONTAINING MATERIAL

2020 ◽  
Vol 2 (3(72)) ◽  
Author(s):  
Sh.T. Dzhuraev ◽  
B.F. Muhiddinov ◽  
A.S. Ibodullaev
Keyword(s):  
Zinc Oxide ◽  
Rheological Properties ◽  
Physicochemical Characteristics ◽  
Technological Properties ◽  
Natural Surface ◽  
Rubber Compounds ◽  
Elastomeric Materials ◽  
Automobile Tires

The paper presents the results of studies of the physicochemical characteristics of the carbon-containing material obtained as a result of the pyrolysis of worn automobile tires. Ankerite (1.21%), zinc oxide (1.14%) and other components. Composite elastomeric materials based on rubbers SKI-3 and Nairit KR-50, filled with carboncontaining material, have been developed. Interconnections between structural radiations and the natural surface of a carbon-containing material and rubber macromolecules were found. The technological and rheological properties of the floor-elastomeric compositions with a carbon-containing effect were studied, and their optimal content in rubber compounds was shown.

scholarly journals Hybrid cultivars of pear in subtropics regions: processing ability in the form of jelly

2017 ◽  
Vol 47 (11) ◽  
Author(s):  
Paula Nogueira Curi ◽  
Rayane Barcelos Bisi ◽  
Derlyene Lucas Salgado ◽  
Caio Morais de Alcântara Barbosa ◽  
Rafael Pio ◽  
...  
Keyword(s):  
Antioxidant Activity ◽  
Rheological Properties ◽  
Bioactive Compounds ◽  
Phenolic Content ◽  
Physicochemical Characteristics ◽  
Color Parameter ◽  
Sensory Acceptance ◽  
Processing Ability ◽  
Industrial Use ◽  
Pear Trees

ABSTRACT: The aim of this study was to characterize five different hybrid cultivars pears (‘Tenra’, ‘Centenária’, ‘Cascatence’, ‘Primorosa’ and ‘Seleta’) deployed in subtropical regions of Brazil regarding its physicochemical characteristics, bioactive compounds and antioxidant activity, as well as to evaluate the influence of these cultivars on the characteristics physicochemical, rheological properties and sensory acceptance of the obtained jelly, for identifying varieties with higher potential for industrial use. Regardingthe bioactive compounds and antioxidant activity it was observed that ‘Seleta’ cultivar was characterized by a higher phenolic content (57.68mg GAEs 100g-1), higher antioxidant activity (13.56% of DPPH sequestration and 1.25µM of trolox g -1) and higher content of vitamin C (3.59mg 100g-1). As the acidity, it ranged from 4.09 to 5.81 g of malic acid 100g-1 (‘Tenra’ and ‘Seleta’, respectively). Regarding color, the color parameter L* varied from 32.14 to 36.83, a* ranged from 2.87 to 5.20, b* ranged from 16.57 to 20.42, Chroma ranged from 16.67 to 21.02 and °Hue ranged from 74.94 to 80.18. Regarding the texture, the jellies produced from ‘Centenária’ and ‘Tenra’ were characterized by having the highest values of hardness (1.21 and 1.23N, respectively), gumminess (0.42 and 0.45, respectively) and chewiness (0.40 and 0.45N, respectively). The jelly obtained from the ‘Centenária’ still showed the highest adhesiveness (2.27N s-1) and springiness (0.99). Already jellies prepared by ‘Cascatence’ showed the highest cohesiveness values (0.68). The jellies prepared with different pear cultivars showed good sensory acceptance for all measured properties, with average scores ranging between the hedonic terms “liked slightly” to “liked very much”. Cultivars of subtropical pear trees present different physicochemical characteristics, resulting in jellies with different physicochemical characteristics and rheological properties. Processing in the form of jelly is extremely viable due to the good acceptance by consumers of all formulations elaborated.

Rheological Properties of Rubber Compounds with Finely Divided Carbon Additives

2018 ◽  
Vol 91 (1) ◽  
pp. 146-151 ◽  
Author(s):  
Zh. S. Shashok ◽  
N. R. Prokopchuk ◽  
K. V. Vishnevskii ◽  
A. V. Krauklis ◽  
K. O. Borisevich ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Rubber Compounds ◽  
Carbon Additives

scholarly journals Low-Temperature Rheological Properties and Microscopic Characterization of Asphalt Rubbers Containing Heterogeneous Crumb Rubbers

Materials ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4120 ◽  
Author(s):  
Mingfeng Chang ◽  
Yixing Zhang ◽  
Jianzhong Pei ◽  
Jiupeng Zhang ◽  
Min Wang ◽  
...  
Keyword(s):  
Low Temperature ◽  
Rheological Properties ◽  
Fine Particles ◽  
Physicochemical Characteristics ◽  
Crumb Rubber ◽  
Rubber Content ◽  
Evaluation Indexes ◽  
Asphalt Rubber ◽  
Linear Viscoelastic Material ◽  
Microscopic Morphology

Asphalt rubbers mixed with untreated and plasticized crumb rubbers and a compounding coupling agent were investigated in this study. The low-temperature rheological properties of asphalt rubbers at different aging levels were tested using a dynamic shear rheometer (DSR). An interconversion between linear viscoelastic material functions was used to obtain converted evaluation indexes for the asphalt rubbers at low temperatures. Lastly, the physicochemical characteristics and the microscopic morphology of the asphalt rubbers were evaluated using Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), respectively. In conclusion, the storage moduli of the asphalt rubbers containing heterogeneous crumb rubbers increased with the plasticized crumb rubber content and the aging level. The converted relaxation moduli were consistent with the change trend of the storage moduli, and the relaxation rate decreased as the plasticized crumb rubber content and the aging level increased. The process of mixing the base asphalt with crumb and plasticized crumb rubbers was physical blending, and the effect of aging on the absorption peak change of asphalt rubber with plasticized crumb rubbers was less than that of asphalt rubber with ordinary crumb rubbers. Aging deteriorated the blending between the crumb rubber and the base asphalt, and a distinct interface appeared between the crumb rubber and the base asphalt. The particle cores of the plasticized crumb rubber in the asphalt rubber were difficult to maintain. Furthermore, as the plasticized crumb rubber content increased, more fine particles stripped off the plasticized crumb rubber after aging.

scholarly journals Organic Zinc Salts as Pro-Ecological Activators for Sulfur Vulcanization of Styrene–Butadiene Rubber

Polymers ◽  
2019 ◽  
Vol 11 (10) ◽  
pp. 1723 ◽  
Author(s):  
Magdalena Maciejewska ◽  
Anna Sowińska ◽  
Judyta Kucharska
Keyword(s):  
Zinc Oxide ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Zinc Ions ◽  
Organic Zinc ◽  
Rubber Compounds ◽  
Curing Characteristics ◽  
Sulfur Vulcanization ◽  
Zinc Salts ◽  
Styrene Butadiene

Organic zinc salts and complexes were applied as activators for sulfur vulcanization of styrene–butadiene elastomer (SBR) in order to reduce the content of zinc ions in rubber compounds as compared with conventionally used zinc oxide. In this article, the effects of different organic zinc activators on the curing characteristics, crosslink densities, and mechanical properties of SBR as well as the aging resistance and thermal behavior of vulcanizates are discussed. Organic zinc salts seem to be good substitutes for zinc oxide as activators for sulfur vulcanization of SBR rubber, without detrimental effects to the vulcanization time and temperature. Moreover, vulcanizates containing organic zinc salts exhibit higher tensile strength and better damping properties than vulcanizate crosslinked with zinc oxide. The application of organic zinc activators allows the amount of zinc ions in SBR compounds to be reduced by 70–90 wt % compared to vulcanizate with zinc oxide. This is very important for ecological reasons, since zinc oxide is classified as being toxic to aquatic species.

Zinc Oxide Nanoparticles Enhance Physicochemical Characteristics of Grossman Sealer

2016 ◽  
Vol 42 (12) ◽  
pp. 1804-1810 ◽  
Author(s):  
Marco Aurélio Versiani ◽  
Fuad Jacob Abi Rached-Junior ◽  
Anil Kishen ◽  
Jesus Djalma Pécora ◽  
Yara Terezinha Silva-Sousa ◽  
...  
Keyword(s):  
Zinc Oxide ◽  
Zinc Oxide Nanoparticles ◽  
Physicochemical Characteristics ◽  
Oxide Nanoparticles

Investigation of the physical and rheological properties of SBR-1712 rubber compounds by neural network approaches

2007 ◽  
Vol 28 (5) ◽  
pp. 1737-1741 ◽  
Author(s):  
Enver Demirhan ◽  
Fatma Kandemirli ◽  
Mithat Kandemirli ◽  
Vasyl Kovalishyn
Keyword(s):  
Neural Network ◽  
Rheological Properties ◽  
Rubber Compounds ◽  
Network Approaches

Adhesion of Rubber to Magnesium Alloys in the Presence of Nickel Branched Alkyl Carboxylates

2003 ◽  
Vol 76 (4) ◽  
pp. 1019-1030 ◽  
Author(s):  
K. Mori ◽  
X. Shi ◽  
H. Hirahara ◽  
Y. Oishi
Keyword(s):  
Aqueous Solution ◽  
Zinc Oxide ◽  
Magnesium Alloy ◽  
Aqueous Solutions ◽  
Sodium Hydroxide ◽  
Magnesium Alloys ◽  
Peel Strength ◽  
Magnesium Alloy Az31 ◽  
Rubber Compounds ◽  
Alkyl Carboxylates

Abstract The authors investigated the adhesion of rubber compounds containing nickel blanched alkyl carboxylate to surface treated magnesium alloys during curing. Ni i-octylate and Ni i-stearate were used as nickel branched alkyl carboxylate. Rubbers used in the study did not adhere at all to magnesium alloys, such as AZ91, AZ31, AZ 21, and M1 washed with acetone; not even in the presence of Ni i-octylate. Among numerous treating solutions, only sodium hydroxide aqueous solution was effective for adhesion of rubber to magnesium alloys. Adhesion of rubber to magnesium alloy AZ31 treated in 0.5M- sodium hydroxide aqueous solution for 10 min at 80 °C yielded high peel strength and a 100% rubber coverage. Peel strength and a 100% rubber coverage varied with the concentration of additives, such as curing accelerators, sulfur, zinc oxide and Ni-type adhesive accelerators. Ni branched alkyl carboxylates such as Ni i-octylate and Ni i-stearate were effective for accelerating the adhesion of rubber to magnesium alloys treated in sodium hydroxide aqueous solutions during curing. The authors postulate that Ni branched alkyl carboxylate acts to yield interface bonds between magnesium alloys and rubber or Ni-S-rubber linkage.

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