scholarly journals Enhanced Water Resistance Performance of Castor Oil—Based Waterborne Polyurethane Modified by Methoxysilane Coupling Agents via Thiol-Ene Photo Click Reaction

2022 ◽  
Vol 10 (3) ◽  
pp. 591-604
Author(s):  
Zhipeng He ◽  
Junqi Xue ◽  
Yanzi Ke ◽  
Ying Luo ◽  
Qiming Lu ◽  
...  
Keyword(s):  
Castor Oil ◽  
Water Resistance ◽  
Click Reaction ◽  
Waterborne Polyurethane ◽  
Coupling Agents ◽  
Resistance Performance

Preparation and Application of Undecylenate Based Diol for Bio-Based Waterborne Polyurethane Dispersion

2014 ◽  
Vol 955-959 ◽  
pp. 88-91 ◽  
Author(s):  
Zhe Yang ◽  
Yan Bin Zhu ◽  
Fang Peng ◽  
Chang Qing Fu
Keyword(s):  
Castor Oil ◽  
Room Temperature ◽  
Click Reaction ◽  
Waterborne Polyurethane ◽  
Chain Extender ◽  
Proton Nuclear Magnetic Resonance ◽  
Isophorone Diisocyanate ◽  
Polyurethane Dispersion ◽  
Waterborne Polyurethanes ◽  
Ft Ir

The undecylenate based diol (UAD) has been synthesized from undecylenate by esterification and thiol-ene click reaction sequently, and then it was used as a diol to prepare bio-based waterborne polyurethane (WPU) reacting with isophorone diisocyanate (IPDI) and castor oil-based carboxyl hydrophilic chain extender. The structure of undecylenate based diol was verified by hydrogen proton nuclear magnetic resonance (1H NMR). Fourier transform infrared spectroscopy (FT-IR) was used to characterize the structure of WPU film. Furthermore, particle size and viscosity were used to character apparent properties of the bio-based waterborne polyurethane dispersion. The result shows that: bio-based waterborne polyurethane dispersion is transparent and very stable under room temperature. This work provides a simple and efficient method for the preparation of fatty acids based polyols and bio-based waterborne polyurethanes.

scholarly journals Polydimethylsiloxane and Castor Oil Comodified Waterborne Polyurethane

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
Xuan Ji ◽  
Yanming Zhou ◽  
Baoling Zhang ◽  
Caiying Hou ◽  
Guozhang Ma
Keyword(s):  
Thermal Stability ◽  
Castor Oil ◽  
Water Resistance ◽  
Fourier Transforms ◽  
Protective Coatings ◽  
Average Particle Size ◽  
Waterborne Polyurethane ◽  
Average Particle ◽  
Ft Ir ◽  
Fourier Transforms Infrared Spectroscopy

In view of both improving properties of waterborne polyurethane (WPU) and sufficient utilization of renewable resources, a series of polydimethylsiloxane (PDMS) and castor oil (C.O.) comodified anionic WPUs with internal cross-linking was prepared through a prepolymer mixing process. The chemical structure of synthesized polymers was characterized by Fourier transforms infrared spectroscopy (FT-IR). In comparison with traditional linear WPU synthesized from petroleum-based polyols, these novel WPU films exhibited superior properties in solvent and water resistance, thermal stability, and mechanical strength, which suggest promising applications of these new environmentally friendly materials, particularly in the area of decorative and protective coatings. In addition, the results showed that with the increase in PDMS content in these co-modified WPUs the average particle size, the water resistance, and the thermal stability increased accordingly while the solvent resistance and the mechanical properties decreased.

Effect of crystalline structure on water resistance of waterborne polyurethane

2021 ◽  
pp. 110647
Author(s):  
Zhengkai Wei ◽  
Zhimeng Liu ◽  
Xiaowei Fu ◽  
Yuechuan Wang ◽  
Anqian Yuan ◽  
...  
Keyword(s):  
Crystalline Structure ◽  
Water Resistance ◽  
Waterborne Polyurethane

Resistance Tests of an Articulated Pusher Barge System in Deep and Shallow Water

2021 ◽  
Author(s):  
Li Zhang ◽  
Lei Xing ◽  
Mingyu Dong ◽  
Weimin Chen
Keyword(s):  
Shallow Water ◽  
Water Depth ◽  
Deep Water ◽  
Water Resistance ◽  
Model Tests ◽  
System 2 ◽  
Changing Trend ◽  
The Difference ◽  
Transport Vessel ◽  
Resistance Performance

Abstract Articulated pusher barge vessel is a short-distance transport vessel with good economic performance and practicability, which is widely used in the Yangtze River of China. In this present work, the resistance performance of articulated pusher barge vessel in deep water and shallow water was studied by model tests in the towing tank and basin of Shanghai Ship and Shipping Research Institute. During the experimental investigation, the articulated pusher barge vessel was divided into three parts: the pusher, the barge and the articulated pusher barge system. Firstly, the deep water resistance performance of the articulated pusher barge system, barge and the pusher at design draught T was studied, then the water depth h was adjusted, and the shallow water resistance at h/T = 2.0, 1.5 and 1.2 was tested and studied respectively, and the difference between deep water resistance and shallow water resistance at design draught were compared. The results of model tests and analysis show that: 1) in the study of deep water resistance, the total resistance of the barge was larger than that of the articulated pusher barge system. 2) for the barge, the shallow water resistance increases about 0.4–0.7 times at h/T = 2.0, 0.5–1.1 times at h/T = 1.5, and 0.7–2.3 times at h/T = 1.2. 3) for the pusher, the shallow water resistance increases about 1.0–0.4 times at h/T = 2.7, 1.2–0.9 times at h/T = 2.0, and 1.7–2.4 times at h/T = 1.6. 4) for the articulated pusher barge system, the shallow water resistance increases about 0.2–0.3 times at h/T = 2.0, 0.5–1.3 times at h/T = 1.5, and 1.0–3.5 times at h/T = 1.2. Furthermore, the water depth Froude number Frh in shallow water was compared with the changing trend of resistance in shallow water.

Anticorrosive waterborne polyurethane coatings derived from castor oil and renewable diols

2022 ◽  
pp. 134470
Author(s):  
Rulin Shen ◽  
Mingjun Long ◽  
Chendong Lei ◽  
Liming Dong ◽  
Guipeng Yu ◽  
...  
Keyword(s):  
Castor Oil ◽  
Waterborne Polyurethane ◽  
Polyurethane Coatings

scholarly journals An Easy Fabrication Method to Prepare Inexpensive UV–Cured Transparent Silicone Modified Polyacrylate Coatings with Good Adhesion and UV Resistance

Coatings ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 675 ◽  
Author(s):  
Fei Cheng ◽  
Yunxin Fan ◽  
Lu Zhang ◽  
Xiaojiao Jiao ◽  
Guoqiao Lai ◽  
...  
Keyword(s):  
High Performance ◽  
Click Reaction ◽  
Silicone Resin ◽  
Uv Resistance ◽  
Fabrication Method ◽  
Good Adhesion ◽  
Pencil Hardness ◽  
Uv Curable ◽  
Glass Slides ◽  
Resistance Performance

UV–curable polyacrylate is widely used in free–radical type UV–cure coating systems, the disadvantages of which including poor thermal stability and UV resistance can be overcome through chemical modification by silicone. However, it is a remarkable fact that the strategies for fabrication UV–cured silicone modified polyacrylates are somewhat complicated and the price of the products may be much expensive than pure UV–cured polyacrylates. In this work, an easy fabrication method to prepare inexpensive UV–cured transparent silicone modified polyacrylate coatings with good adhesion and UV resistance performance was developed from copolymers of acylates and thiol silicone resin by UV initiated thiol–ene click reaction without UV initiator. The striking results with a high application value should be emphasized that when the amount of thiol silicone resin is only one wt.% of the copolymer of acrylates, the UV–cured coatings obtained exhibit fairly good performance. These coatings prepared exhibit transparency higher than 96% (800 nm), adhesion property to glass slides can reach grade 0, pencil hardness can reach 6H, water absorption is less than 0.16%. In particular, it is observed obviously that the silicone modified polyacrylate coatings exhibit better UV resistance performance than the coating prepared with only copolymers of acrylates initiated by UV initiator 1173. It is proved that it is actually an easy fabrication method to prepare inexpensive UV–cured transparent silicone modified polyacrylate coatings with high performance by UV initiated thiol–ene click reaction of copolymers of acylates and thiol silicone resin.

Waterborne polyurethane-silica nanocomposite adhesives based on castor oil-recycled polyols: Effects of (3-aminopropyl)triethoxysilane (APTES) content on properties

2019 ◽  
Vol 90 ◽  
pp. 22-31 ◽  
Author(s):  
Suzana M. Cakić ◽  
Maja D. Valcic ◽  
Ivan S. Ristić ◽  
Tanja Radusin ◽  
Miroslav J. Cvetinov ◽  
...  
Keyword(s):  
Castor Oil ◽  
Waterborne Polyurethane ◽  
Silica Nanocomposite

scholarly journals The Puncture and Water Resistance of Polyurethane- Impregnated Fabrics after UV Weathering

Polymers ◽  
2019 ◽  
Vol 12 (1) ◽  
pp. 15
Author(s):  
Antonella Patti ◽  
Domenico Acierno
Keyword(s):  
Experimental Data ◽  
Uv Radiation ◽  
Water Resistance ◽  
Uv Light ◽  
Crosslinking Agent ◽  
Waterborne Polyurethane ◽  
Impregnation Method ◽  
Polyurethane Dispersion ◽  
Spectroscopic Analyses ◽  
Before And After

Polyurethane is a polymer adaptable to different scientific and industrial requirements; nevertheless it is also extremely susceptible to UV radiation, which compromises the physical and mechanical functionality. In this framework, our study investigated the effect of waterborne polyurethane dispersion (WPUD) applied to a polyester (PET)-based fabric, through the impregnation method, on the puncturing and water resistance of the pristine material, before and after UV weathering. Results confirmed an increment of both features in the prepared fabrics, attributed to the PUR textile treatment; but a partially loss of the gained properties in the samples due to the UV weathering. In order to improve the efficiency of the impregnating dispersions, in protecting the durability of the treated materials, the addition of different UV light stabilizers, or/and of crosslinking agent into WPUD was also tested. From the experimental data, it can be concluded that formulations based on WPUD, containing both the crosslinker and UV organic absorber, have displayed an increment of their perforation and water resistance for the treated samples with respect to the starting textile, and contemporary have preserved the features against the UV light. Finally, microscopic and spectroscopic analyses have been performed as further characterization techniques of the samples surface.

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