scholarly journals Novel grain refinement of AZ91E magnesium alloy and the effect on hot tearing during solidfication

2021 ◽  
Author(s):  
Abdallah Elsayed
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Magnesium Alloys ◽  
Hot Tearing ◽  
Grain Refining ◽  
Grain Refiner ◽  
Structural Applications ◽  
Hot Tearing Susceptibility

For the A1-5Ti-1B grain refiner, the addition of 0.1 wt.% provided a 68 % reduction in grain size as compared to the unrefined AZ91E alloy at a holding time of five minutes. Grain growth restriction by TiB₂ particles was the source of grain refinement. With the addition of A1-5Ti-1B, only a small reduction in hot tearing susceptibility ws observed because large TiA1₃ particles bonded poorly with the eutectic and blocked feeding channels.The addition of 1.0 wt.% A1-1Ti-3B provided a grain size reduction of 63% as compared to the unrefined AZ91E alloy at a holding time of five minutes. The grain refinement with A1-1Ti-3B addition was attributed to a combination of TiB₂ grain growth restriction and A1B₂ nucleating sites. A significant reduction in hot tearing susceptibility was observed with A1-1Ti-3B addition as a result of a higher cooling rate and shorter local soldification time as compared to the AZ91E alloy. The reduction in hot tearing susceptibility was attributed to the good interface between eutectic and TiB₂ particles. Both grain refiners demonstrated a good resistance to fading during the holding times investigated. In addition, the AZ91E + A1-5Ti-1B and AZ91E + A1-1Ti-3B castings showed much fewer dislocation networks as compared to the untreated AZ91E casting.The development of efficient A1-Ti-B refiners can also improve castability of magnesium alloys. In addition, the fade resistant A1-Ti-B grain refiners can reduce operating costs and maintain productivity on the foundry floor. Thus, magnesium alloy with A1-Ti-B treatment have the potential for more demanding structural applications in the automobile and aerospace industries. Vehicle weight in the aerospace and automotive industries directly impacts carbon emissions and fuel efficiency. An increase in the use of lightweight materials for structural applications will result in lighter vehicles. Low density materials, such as magnesium (1.74 g/cm³) are a potential alternative to aluminium (2.70 g/cm³), to reduce component weight in structural applications.However, current magnesium alloys still do not have adequate mechanical properties and castability to meet the performance specifications of the automotive and aerospace industries. Grain refinement can significantly improve mechanical properties and reduce hot tearing during permanent mould casting. Recently, Al-Ti-B based grain refiners have shown potential in grain refining magnesium-aluminum alloys such as AZ91E. This study investigates the grain refining efficiency and fading of A1-5Ti-1B and A1-1Ti-3B in AZ91E magnesium alloy and their subsequent effect on hot tearing.The grain refiners were added at 0.1, 0.2, 0.5 and 1.0 wt.% levels. For the grain refinement and fading experiments, the castings were prepared using graphite moulds with holding times of 5, 10 and 20 minutes. For the hot tearing experiments, castings were produced representing the optimal addition level of each grain refiner. The castings were prepared using a permanent mould with pouring and mould temperatures of 720 and 180 ºC, respectively. The castings were characterized using SEM, TEM, optical microscopy and thermal analysis.

scholarly journals Novel grain refinement of AZ91E magnesium alloy and the effect on hot tearing during solidfication

2021 ◽  
Author(s):  
Abdallah Elsayed
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Magnesium Alloys ◽  
Hot Tearing ◽  
Grain Refining ◽  
Grain Refiner ◽  
Structural Applications ◽  
Hot Tearing Susceptibility

For the A1-5Ti-1B grain refiner, the addition of 0.1 wt.% provided a 68 % reduction in grain size as compared to the unrefined AZ91E alloy at a holding time of five minutes. Grain growth restriction by TiB₂ particles was the source of grain refinement. With the addition of A1-5Ti-1B, only a small reduction in hot tearing susceptibility ws observed because large TiA1₃ particles bonded poorly with the eutectic and blocked feeding channels.The addition of 1.0 wt.% A1-1Ti-3B provided a grain size reduction of 63% as compared to the unrefined AZ91E alloy at a holding time of five minutes. The grain refinement with A1-1Ti-3B addition was attributed to a combination of TiB₂ grain growth restriction and A1B₂ nucleating sites. A significant reduction in hot tearing susceptibility was observed with A1-1Ti-3B addition as a result of a higher cooling rate and shorter local soldification time as compared to the AZ91E alloy. The reduction in hot tearing susceptibility was attributed to the good interface between eutectic and TiB₂ particles. Both grain refiners demonstrated a good resistance to fading during the holding times investigated. In addition, the AZ91E + A1-5Ti-1B and AZ91E + A1-1Ti-3B castings showed much fewer dislocation networks as compared to the untreated AZ91E casting.The development of efficient A1-Ti-B refiners can also improve castability of magnesium alloys. In addition, the fade resistant A1-Ti-B grain refiners can reduce operating costs and maintain productivity on the foundry floor. Thus, magnesium alloy with A1-Ti-B treatment have the potential for more demanding structural applications in the automobile and aerospace industries. Vehicle weight in the aerospace and automotive industries directly impacts carbon emissions and fuel efficiency. An increase in the use of lightweight materials for structural applications will result in lighter vehicles. Low density materials, such as magnesium (1.74 g/cm³) are a potential alternative to aluminium (2.70 g/cm³), to reduce component weight in structural applications.However, current magnesium alloys still do not have adequate mechanical properties and castability to meet the performance specifications of the automotive and aerospace industries. Grain refinement can significantly improve mechanical properties and reduce hot tearing during permanent mould casting. Recently, Al-Ti-B based grain refiners have shown potential in grain refining magnesium-aluminum alloys such as AZ91E. This study investigates the grain refining efficiency and fading of A1-5Ti-1B and A1-1Ti-3B in AZ91E magnesium alloy and their subsequent effect on hot tearing.The grain refiners were added at 0.1, 0.2, 0.5 and 1.0 wt.% levels. For the grain refinement and fading experiments, the castings were prepared using graphite moulds with holding times of 5, 10 and 20 minutes. For the hot tearing experiments, castings were produced representing the optimal addition level of each grain refiner. The castings were prepared using a permanent mould with pouring and mould temperatures of 720 and 180 ºC, respectively. The castings were characterized using SEM, TEM, optical microscopy and thermal analysis.

scholarly journals Grain Refinement Of Magnesium and Az19E Magnesium Alloy By Addition Of MgB2 Inoculant

2021 ◽  
Author(s):  
Payam Emadi
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Thermal Expansion ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Coefficient Of Thermal Expansion ◽  
Fuel Efficiency ◽  
Grain Refining ◽  
Nano Particle ◽  
Thermal Expansion Mismatch

The increased use of magnesium alloys with improved mechanical properties is a prominent strategy towards increasing fuel efficiency of vehicles and decreasing emissions. This study investigates the grain refining efficiency and fading of MgB2 micro- and nano-particle added Pure Mg and AZ91E. Addition of micro and nano-sized MgB2 provided a reduction in grain size for Pure Mg and AZ91E. Enhanced heterogeneous nucleation and grain growth restriction was believed to be the source of refinement. Fading was observed for both Pure Mg and AZ91E, with the nano-particle added castings showing an increased resistance. The elongation of the Pure Mg samples showed improvements, whereas no improvements for UTS and YS was seen. The improved ductility was believed to be due to the grain refinement and coefficient of thermal expansion mismatch. The AZ91E samples did not show improvements in mechanical properties. This was believed to be due to stress concentration from Al-Mn intermetallics.

Effects of AlN Particles and Electromagnetic Stirring on As-Cast Structure of AZ31 Alloys

2011 ◽  
Vol 675-677 ◽  
pp. 771-774 ◽  
Author(s):  
Song Wei Gu ◽  
Hai Hao ◽  
Can Feng Fang ◽  
Shou Hua Ji ◽  
Xing Guo Zhang
Keyword(s):  
Grain Size ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Grain Growth ◽  
Magnesium Alloys ◽  
Electromagnetic Stirring ◽  
Grain Refiner ◽  
Cast Structure ◽  
Fine Grain ◽  
Refinement Mechanism

A fine grain size generally leads to improved structural uniformity of magnesium alloys. AlN has been identified as a potential grain refiner and electromagnetic stirring may have great effects on microstructure and grain growth. This study will be focused on the effects of AlN particles and electromagnetic stirring on the as-cast structure of AZ31 alloys.The grain refinement mechanism of both methods on magnesium alloy and their interaction effects are also discussed.

scholarly journals Grain Refinement Of Magnesium and Az19E Magnesium Alloy By Addition Of MgB2 Inoculant

2021 ◽  
Author(s):  
Payam Emadi
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Thermal Expansion ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Coefficient Of Thermal Expansion ◽  
Fuel Efficiency ◽  
Grain Refining ◽  
Nano Particle ◽  
Thermal Expansion Mismatch

The increased use of magnesium alloys with improved mechanical properties is a prominent strategy towards increasing fuel efficiency of vehicles and decreasing emissions. This study investigates the grain refining efficiency and fading of MgB2 micro- and nano-particle added Pure Mg and AZ91E. Addition of micro and nano-sized MgB2 provided a reduction in grain size for Pure Mg and AZ91E. Enhanced heterogeneous nucleation and grain growth restriction was believed to be the source of refinement. Fading was observed for both Pure Mg and AZ91E, with the nano-particle added castings showing an increased resistance. The elongation of the Pure Mg samples showed improvements, whereas no improvements for UTS and YS was seen. The improved ductility was believed to be due to the grain refinement and coefficient of thermal expansion mismatch. The AZ91E samples did not show improvements in mechanical properties. This was believed to be due to stress concentration from Al-Mn intermetallics.

Mechanical Properties of ECAP Processed Magnesium Alloy AS21X

2006 ◽  
Vol 503-504 ◽  
pp. 889-894 ◽  
Author(s):  
T.T. Lamark ◽  
Ralph Jörg Hellmig ◽  
Yuri Estrin
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Magnesium Alloys ◽  
Elastic Properties ◽  
Room Temperature ◽  
Tensile Tests ◽  
Coarse Grained ◽  
Cyclic Behaviour

Typically, magnesium alloys with conventional grain size exhibit microplastic behaviour already at low stresses. This behaviour restricts the technological utilization of these materials. The aim of this study was to investigate whether ECAP can be applied to enlarge the elastic range of AS21X. Cyclic tensile tests at room temperature were carried out to examine the effect of the ECAP induced grain refinement on the elastic properties. The results obtained are compared with the cyclic behaviour of conventional, coarse-grained AS21X. The differences in mechanical properties between the two conditions are discussed.

Effect of Al-Ti-B Based Master Alloys on Grain Refinement and Hot Tearing Susceptibility of AZ91E Magnesium Alloy

2011 ◽  
Vol 690 ◽  
pp. 351-354 ◽  
Author(s):  
Elsayed Abdallah ◽  
Comondore Ravindran ◽  
B.S Murty
Keyword(s):  
Magnesium Alloy ◽  
Grain Refinement ◽  
Magnesium Alloys ◽  
Base Alloy ◽  
Hot Tearing ◽  
Automotive Applications ◽  
Dog Bone ◽  
Master Alloys ◽  
As Stress ◽  
Hot Tearing Susceptibility

The objective of this study was to examine the potential of Al-5Ti-1B and Al-1Ti-3B master alloys in reducing the hot tearing susceptibility of AZ91E magnesium alloy. The low penetration of magnesium alloys for structural automotive applications can be attributed to their poor castability during permanent mould casting. An improvement in the castability of magnesium alloys will result in the production of larger castings for automotive applications and a reduction in vehicle weight. The addition levels examined for both master alloys were 0.1, 0.2, 0.5 and 1.0 wt.%. The master alloys were added to the AZ91E alloy and stirred for 30 seconds. For the graphite mould castings used to observe grain refinement, the pouring and mould temperatures were 720 and 750 °C respectively. The hot tear castings were produced using a “dog bone” shaped H-13 tool steel mould. The pouring and mould temperatures were 720 and 180 °C respectively. Without master alloy addition, the base AZ91E casting had severe hot tears. The addition of Al-5Ti-1B slightly reduced hot tears while Al-1Ti-3B addition significantly reduced hot tears. The addition of Al-1Ti-3B also significantly reduced the grain size of the castings from 113 µm in the base alloy to 72 µm with 1.0 wt.% addition. The addition of Al-5Ti-1B did not lead to a reduction of hot tears because of large TiAl3 particles acting as stress risers during solidification.

The Effect of Grain Refinement and Cooling Rate on the Hot Tearing of Wrought Aluminium Alloys

2006 ◽  
Vol 519-521 ◽  
pp. 1675-1680 ◽  
Author(s):  
Mark Easton ◽  
John F. Grandfield ◽  
David H. StJohn ◽  
Barbara Rinderer
Keyword(s):  
Grain Size ◽  
Cooling Rate ◽  
Grain Refinement ◽  
Aluminium Alloys ◽  
Grain Morphology ◽  
Hot Tearing ◽  
Grain Refiner ◽  
Cooling Rates ◽  
High Cooling Rates ◽  
Hot Tearing Susceptibility

Using modifications to the Rappaz-Drezet-Gremaud hot tearing model, and using empirical equations developed for grain size and dendrite arm spacing (DAS) on the addition of grain refiner for a range of cooling rates, the effect of grain refinement and cooling rate on hot tearing susceptibility has been analysed. It was found that grain refinement decreased the grain size and made the grain morphology more globular. Therefore refining the grain size of an equiaxed dendritic grain decreased the hot tearing susceptibility. However, when the alloy was grain refined such that globular grain morphologies where obtained, further grain refinement increased the hot tearing susceptibility. Increasing the cooling decreased the grain size and made the grain morphology more dendritic and therefore increased the likelihood of hot tearing. The effect was particularly strong for equiaxed dendritic grain morphologies; hence grain refinement is increasingly important at high cooling rates to obtain more globular grain morphologies to reduce the hot tearing susceptibility.

The influence of gadolinium on Al–Ti–C master alloy and its refining effect on AZ31 magnesium alloy

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Wenxue Fan ◽  
Hai Hao
Keyword(s):  
Mechanical Properties ◽  
Magnesium Alloy ◽  
Grain Refinement ◽  
Magnesium Alloys ◽  
Master Alloy ◽  
Cast Alloy ◽  
Az31 Magnesium Alloy ◽  
Synthesis Mechanism ◽  
Refining Effect ◽  
Master Alloys

Abstract Grain refinement has a significant influence on the improvement of mechanical properties of magnesium alloys. In this study, a series of Al–Ti–C-xGd (x = 0, 1, 2, 3) master alloys as grain refiners were prepared by self-propagating high-temperature synthesis. The synthesis mechanism of the Al–Ti–C-xGd master alloy was analyzed. The effects of Al–Ti–C-xGd master alloys on the grain refinement and mechanical properties of AZ31 (Mg-3Al-1Zn-0.4Mn) magnesium alloys were investigated. The results show that the microstructure of the Al–Ti–C-xGd alloy contains α-Al, TiAl3, TiC and the core–shell structure TiAl3/Ti2Al20Gd. The refining effect of the prepared Al–Ti–C–Gd master alloy is obviously better than that of Al–Ti–C master alloy. The grain size of AZ31 magnesium alloy was reduced from 323 μm to 72 μm when adding 1 wt.% Al–Ti–C-2Gd master alloy. In the same condition, the ultimate tensile strength and elongation of as-cast alloy were increased from 130 MPa, 7.9% to 207 MPa, 16.6% respectively.

scholarly journals Development of Al–Mg–Si alloy performance by addition of grain refiner Al–5Ti–1B alloy

2021 ◽  
Vol 104 (2) ◽  
pp. 003685042110294
Author(s):  
Khaled Abd El-Aziz ◽  
Emad M Ahmed ◽  
Abdulaziz H Alghtani ◽  
Bassem F Felemban ◽  
Hafiz T Ali ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Corrosion Resistance ◽  
Testing Machine ◽  
Dendritic Structure ◽  
Grain Refiner ◽  
Corrosion Properties ◽  
Average Grain Size ◽  
Structural Applications ◽  
Alloy Addition

Aluminum alloys are the most essential part of all shaped castings manufactured, mainly in the automotive, food industry, and structural applications. There is little consensus as to the precise relationship between grain size after grain refinement and corrosion resistance; conflicting conclusions have been published showing that reduced grain size can decrease or increase corrosion resistance. The effect of Al–5Ti–1B grain refiner (GR alloy) with different percentages on the mechanical properties and corrosion behavior of Aluminum-magnesium-silicon alloy (Al–Mg–Si) was studied. The average grain size is determined according to the E112ASTM standard. The compressive test specimens were made as per ASTM: E8/E8M-16 standard to get their compressive properties. The bulk hardness using Vickers hardness testing machine at a load of 50 g. Electrochemical corrosion tests were carried out in 3.5 % NaCl solution using Autolab Potentiostat/Galvanostat (PGSTAT 30).The grain size of the Al–Mg–Si alloy was reduced from 82 to 46 µm by the addition of GR alloy. The morphology of α-Al dendrites changes from coarse dendritic structure to fine equiaxed grains due to the addition of GR alloy and segregation of Ti, which controls the growth of primary α-Al. In addition, the mechanical properties of the Al–Mg–Si alloy were improved by GR alloy addition. GR alloy addition to Al–Mg–Si alloy produced fine-grained structure and better hardness and compressive strength. The addition of GR alloy did not reveal any marked improvements in the corrosion properties of Al–Mg–Si alloy.

Research on the Microstructures and Mechanical Properties of Annealed Cold Upsetting AZ31 Magnesium Alloy

2009 ◽  
Vol 610-613 ◽  
pp. 826-830
Author(s):  
Tian Mo Liu ◽  
Wei Hui Hu ◽  
Qing Liu
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Annealing Temperature ◽  
Volume Fraction ◽  
Cold Upsetting ◽  
Cast Magnesium Alloys ◽  
Microstructures And Mechanical Properties ◽  
Cast Magnesium

The microstructures and mechanical properties of cold upsetting magnesium alloys were investigated upon anneal under different conditions. The results show that a large amount of twins were observed in the original grains of cold upsetting AZ31 magnesium alloys. The twins disappeared gradually and recrystal grains formed after anneal. The volume fraction of the recrystal grains increases as the strain of samples rises. Recrystal grain size grows large with the elevated annealing temperature. Recrystal grain size reduces at first and then grows as the annealing time is prolonged. In addition, compared with as-cast magnesium alloys, the yield strength of cold upsetting samples increase apparently due to grain refinement after anneals.

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