scholarly journals Corrosion Protection of Carbon Steel in 2M HCl Using Aizoon canariense Extract

2021 ◽  
Vol 12 (1) ◽  
pp. 230-243
Keyword(s):  
Activation Energy ◽  
Carbon Steel ◽  
Adsorption Isotherm ◽  
Corrosion Rate ◽  
Surface Morphology ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Adsorption Effect ◽  
Inhibition Effect ◽  
Langmuir Adsorption

The corrosion inhibition effectiveness of Aizoon canariense for carbon steel (CS) in 2 M HCl (the corrosive medium) has been examined by employing chemical and electrochemical methods. The inhibition efficiency was found to improve with a rise in the environment's extract and temperature concentration. The inhibitive effect of this extract was explained on the basis of adsorption on the metal surface; the adsorption effect follows Langmuir adsorption isotherm. The percent inhibition efficiency (IE%) reached 90.23% at 45oC, and activation energy (E*a) has been determined in the presence and absence of Aizoon canariense extract. The corrosion rate was calculated and revealed that Aizoon canariense has a good inhibition effect on CS. The surface morphology of CS was examined by employing various techniques. The polarization results indicated that this extract acts as a mixed kind inhibitor. The parameters for the corrosion procedure have also been determined and discussed.

scholarly journals Sweet Corrosion Inhibition on API 5L-B Pipeline Steel

2012 ◽  
Vol 2012 ◽  
pp. 1-15 ◽  
Author(s):  
Mahmoud Abbas Ibraheem ◽  
Abd El Aziz El Sayed Fouda ◽  
Mohamed Talaat Rashad ◽  
Fawzy Nagy Sabbahy
Keyword(s):  
Activation Energy ◽  
Carbon Steel ◽  
Corrosion Inhibition ◽  
Mixed Type ◽  
Inhibition Efficiency ◽  
Pipeline Steel ◽  
Langmuir Adsorption Isotherm ◽  
Iron Nitrides ◽  
Langmuir Adsorption ◽  
Sweet Corrosion

Corrosion inhibition and adsorption behavior of two triazole derivatives on API 5L-B carbon steel in CO2-saturated 3.5% NaCl solutions was investigated using potentiodynamic polarization, EIS, and EFM techniques. Specimen surfaces were characterized using SEM, EDX, and XRD. Results show that the two compounds are mixed-type inhibitors and inhibition efficiency increases with increasing concentrations. Adsorption of the two compounds chemisorption and obeys Langmuir adsorption isotherm. Activation energy and thermodynamic parameters were calculated. Surface analyses confirm the formation of iron nitrides on the metal surface which supports results obtained from previous techniques.

scholarly journals The Inhibition Effect of Potassium Iodide on the Corrosion of Pure Iron in Sulphuric Acid

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Tarik Attar ◽  
Lahcène Larabi ◽  
Yahia Harek
Keyword(s):  
Activation Energy ◽  
Weight Loss ◽  
Organic Compounds ◽  
Potassium Iodide ◽  
Pure Iron ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Inhibitor Concentration ◽  
Inhibition Effect ◽  
Langmuir Adsorption

The use of inorganic inhibitors as an alternative to organic compounds is based on the possibility of degradation of organic compounds with time and temperature. The inhibition effect of potassium iodide on the corrosion of pure iron in 0.5 M H2SO4 has been studied by weight loss. It has been observed from the results that the inhibition efficiency (IE%) of KI increases from 82.17% to 97.51% with the increase in inhibitor concentration from 1·10−4 to 2·10−3 M. The apparent activation energy (Ea) and the equilibrium constant of adsorption (Kads) were calculated. The adsorption of the inhibitor on the pure iron surface is in agreement with Langmuir adsorption isotherm.

The Adsorption Behavior of Thiazole on the Surface of Carbon Steel in Heterogeneous Solution

2014 ◽  
Vol 1010-1012 ◽  
pp. 1740-1744
Author(s):  
Jun Zhe Ai
Keyword(s):  
Carbon Steel ◽  
Adsorption Isotherm ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Adsorption Behavior ◽  
Nacl Solution ◽  
Langmuir Adsorption ◽  
Potentiodynamic Polarization Curves ◽  
Electrochemical Parameters ◽  
Spontaneous Behavior

The adsorption behavior of thiazole inhibitior on the surface of N80 carbon steel was studied by potentiodynamic polarization curves in heterogeneous NaCl solution at pH=4. The electrochemical parameters were fitted. The result shows that thiazole inhibitor is of anodic adsorption, and the inhibition efficiency increases with the concentration increasing (4.9×10-4~1.9×10-3mol/L), but decreases with the temperature increasing (30~60°C). The thermodynamics of this adsorption was also discussed. The result is shown that the adsorption is according with Langmuir adsorption isotherm formula in acidic condition, and adsorption is a spontaneous behavior.

scholarly journals Azadirachta indica Leaf as a Corrosion Inhibitor for Coper in Nitric Acid

2019 ◽  
Vol 70 (2) ◽  
pp. 581-584 ◽  
Author(s):  
Liviu Mitu ◽  
Sweetlin Rajula Rubavathi ◽  
Muthupoongodi Subramani ◽  
T. Linda ◽  
S. Balakumar
Keyword(s):  
Weight Loss ◽  
Nitric Acid ◽  
Adsorption Isotherm ◽  
Corrosion Rate ◽  
Corrosion Inhibitor ◽  
Plant Extract ◽  
Azadirachta Indica ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Langmuir Adsorption

The effect of Azadirachta indica leaf (AIL) extract on the corrosion of copper in 1M HNO3 was investigated by weight loss technique. The result showed that the corrosion rate decreased in the presence of plant extract and inhibition efficiency increased with increasing the concentration of extract. The decreased corrosion rate was due to adsorption of plant extract which was discussed on the basis of Langmuir adsorption isotherm.

scholarly journals COVID-19 Vaccine, Contraceptive, Viscosity and Safety Margin Change

2021 ◽  
Vol 11 (2) ◽  
pp. 3509-3512
Keyword(s):  
Adsorption Isotherm ◽  
Mild Steel ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Safety Margin ◽  
Steel Corrosion ◽  
Langmuir Adsorption Isotherm ◽  
Langmuir Adsorption ◽  
Mild Steel Corrosion ◽  
Hcl Solution

The temperature effect of 4-ethyl-1-(4-oxo-4-phenylbutanoyl)thiosemicarbazide (EOPT) on the mild steel corrosion in 1 M HCl solution was studied by gravimetric techniques at temperatures varying from 303 to 333 K. The investigated inhibitor concentrations were started from 100 ppm and ended with 500 ppm. The inhibition efficiency increased with the increase of the concentration of the inhibitor and reached 96.1% with the concentration of 500 ppm at 303 K and decreased to 66.3% at 333 K. Moreover, the inhibition efficiencies decreased with the temperature increase for both acids. Using the Langmuir adsorption isotherm for the adsorption of this inhibitor on the mild steel surface was determined. EOPT was found to be an efficient corrosion inhibitor due to its structural molecules, which contain sulfur, nitrogen, and oxygen, hetero atoms an addition to the aromatic ring.

scholarly journals Artichoke Extract as an Eco-Friendly Corrosion Inhibitor for Zinc in 1 M Hydrochloric Acid Solution

2021 ◽  
Vol 10 (4) ◽  
pp. 2655-2679
Keyword(s):  
Adsorption Isotherm ◽  
Corrosion Inhibitor ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Free Energy Of Adsorption ◽  
Adsorption Parameters ◽  
Langmuir Adsorption ◽  
Zinc Surface ◽  
Dynamics Simulations ◽  
Hcl Solution

Artichoke extract (AE) was studied as the corrosion inhibitor for zinc in 1 M HCl utilizing chemical and electrochemical methods. The adsorption isotherm of Artichoke extract on Zn surface accords with Langmuir adsorption isotherm. The inhibition efficiency increases with increasing the extract's concentration and decreases with the rise in the medium's temperature. The inhibition efficiency reached a value of 93.2% at 300 ppm of extract. This extract may be forming a film and acts as a barrier, which minimizes the contact area between zinc surface and HCl solution. Artichoke extract acts as a mixed inhibitor in HCl solution. Thermodynamic parameters of activation and adsorption were determined and explained. The adsorption parameters also obeyed the Langmuir adsorption isotherm, and the sign of the free energy of adsorption showed a spontaneous process. The surface morphology of zinc metal was examined by employing various techniques. Also, the biological effect of the Artichoke extract was studied. Theoretical studies of quantum mechanics and molecular dynamics simulations studies were carried out on the Artichoke extract compounds, and the results agree with the experimental one. The efficiencies marked from all employed techniques were in perfect correspondence, demonstrating the validity of these procedures.

SELECTED BIS-THIADIAZOLE: SYNTHESIS AND CORROSION INHIBITION STUDIES ON MILD STEEL IN HCL ENVIRONMENT

2020 ◽  
Vol 27 (12) ◽  
pp. 2050014
Author(s):  
ABBAS Z. SALMAN ◽  
QUSAY A. JAWAD ◽  
KHALID S. RIDAH ◽  
LINA M. SHAKER ◽  
AHMED A. AL-AMIERY
Keyword(s):  
Mild Steel ◽  
Immersion Time ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Inhibitor Concentration ◽  
Conjugation System ◽  
Inhibition Effect ◽  
Langmuir Adsorption ◽  
Acid Environment ◽  
Inhibition Studies

The inhibition effect of synthesized corrosion inhibitor namely 5,5′-(1,4-phenylene)bis([Formula: see text]-phenyl-1,3,4-thiadiazol-2-amine) (PBPA) on the corrosion of mild steel in 1-M hydrochloric acid environment are examined by gravimetric techniques at various temperature (303–343 K). The synthesized inhibitor concentrations are 0.1–0.5[Formula: see text]mM. The inhibition efficiency increased with the increase of the inhibitor concentration. The inhibition efficiency reached 94% at the highest studied concentration of 0.5[Formula: see text]mM for 5[Formula: see text]h of immersion time and 303[Formula: see text]K. Moreover, the inhibition efficiency decreased with the temperature increase. The adsorption of tested inhibitor molecules on the surface of mild steel follows the Langmuir adsorption isotherm. The studied inhibitor molecules showed excellent inhibition since PBPA molecules have nitrogen and sulfur atoms in addition to phenyl and thiadiazol rings which were linked together in conjugation system.

Investigation of 4-Methoxysalicylaldehyde Thiosemicarbazone as Inhibitor for Carbon Steel in Sulfuric Acid Solution

2014 ◽  
Vol 633-634 ◽  
pp. 513-516
Author(s):  
Hong Hong Zhang ◽  
Yan Zhang ◽  
Zhong Nian Yang
Keyword(s):  
Weight Loss ◽  
Schiff Base ◽  
Carbon Steel ◽  
Steel Surface ◽  
Electrochemical Impedance ◽  
Langmuir Adsorption Isotherm ◽  
Inhibition Effect ◽  
Langmuir Adsorption ◽  
Carbon Steel Surface ◽  
Eis Measurements

The Schiff base 4-methoxysalicylaldehyde thiosemicarbazone (MST) was synthesized and its corrosion inhibition effect on carbon steel in 0.5 M H2SO4 solution was tested via weight loss and electrochemical impedance spectroscopy (EIS) measurements. The results show that MST serves as an effective corrosion inhibitor for carbon steel. The corrosion rate of carbon steel decreases with the increase in concentration of MST. The adsorption of MST on the carbon steel surface conforms to the Langmuir adsorption isotherm.

Adsorption and Inhibitive Properties of 1-phenylaminomethyl-benzimidazole on Corrosion of Mild Steel in Hydrochloric Acid

2014 ◽  
Vol 989-994 ◽  
pp. 536-539 ◽  
Author(s):  
Tie Jun Su ◽  
Ke Hua Li
Keyword(s):  
Hydrochloric Acid ◽  
Adsorption Isotherm ◽  
Mild Steel ◽  
Corrosion Inhibition ◽  
Potentiodynamic Polarization ◽  
Steel Surface ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Mild Steel Surface ◽  
Langmuir Adsorption

The corrosion inhibition of mild steel in 5.0 M HCl by 1–phenylaminomethyl-benzimidazo -le (PMB) was studied by gravimetric and potentiodynamic polarization methods. Inhibition efficiency of PMB increased with increase in the concentration of inhibitor and decreased with the increase in temperature. PMB acts as anodic-type inhibitor for mild steel. The adsorption of PMB on mild steel surface obeys the Langmuir adsorption isotherm.

Preparation of Eco-Friendly Acidic Corrosion Inhibitors from Ilex Chinensis Sims Leaves

2021 ◽  
Vol 15 (4) ◽  
pp. 472-477
Author(s):  
Qianlong Wang ◽  
Ruquan Zhang ◽  
Liyuan Zhang ◽  
Minlan Gao ◽  
Weichao Du ◽  
...  
Keyword(s):  
Corrosion Inhibition ◽  
Corrosion Inhibitors ◽  
Adsorption Mechanism ◽  
Protocatechuic Acid ◽  
Inhibition Efficiency ◽  
Langmuir Adsorption Isotherm ◽  
Inhibition Effect ◽  
Acidic Corrosion ◽  
Langmuir Adsorption ◽  
Corrosion Inhibition Efficiency

Preparing chemicals from natural product is a simple way to green chemistry. May flavonoids and protocatechuic acid have been found in Ilex Chinensis Sims leaves extracts, which indicates its extracts suitable to be used as an effective corrosion inhibitor. Extracts of Ilex Chinensis Sims leaves (HE) were modified with hydroxymethylation reaction and Mannich reaction to produce the relative stable green acidic corrosion inhibitors (HM1 and HM2). The extracts of Ilex Chinensis Sims leaves and the modified samples were investigated on the corrosion inhibition of A3 steel accordingly. The results show that these inhibitors have effective corrosion inhibition effect on A3 steel. The HM2 are the most effective for corrosion inhibition, and the inhibition efficiency can reach to 78.36%. At 60 °C, the corrosion inhibition efficiency of these three extracts is HM2 > HM1 > HE. And the extracts inhibit corrosion mainly by adsorption mechanism. This adsorption accords with Langmuir adsorption isotherm.

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