scholarly journals RESEARCH OF THE PHYSICAL PROPERTIES OF DIESEL FUEL-HYDROGEN MIXTURES

2021 ◽  
Vol 87 (9) ◽  
pp. 45-54
Author(s):  
Lev Leybovych ◽  
Borys Dymo ◽  
Sergey Anastasenko ◽  
Yurii Yevstigneyev
Keyword(s):  
Diffusion Coefficient ◽  
Diesel Fuel ◽  
Liquid Fuel ◽  
Hydrogen Diffusion ◽  
Heat Engine ◽  
Chemical Properties ◽  
Hydrogen Sensor ◽  
Engine Operation ◽  
Rate Of Dissolution ◽  
Hydrogen Mixtures

The change in the viscosity of diesel fuel with dissolved hydrogen, the rate of dissolution of hydrogen in the diesel fuel, and the hydrogen diffusion coefficient in diesel fuel were experimentally determined. Dissolving hydrogen in liquid fuel changes its physical-chemical properties. It has been found that the viscosity and density of diesel fuel change little when it is saturated with hydrogen. The flashpoint in a closed crucible is reduced by 3–4 °C. The rate of dissolution of hydrogen in diesel fuel has been investigated. It has been found that the diffusion coefficient of hydrogen in diesel fuel depends significantly on the initial concentration of H2 in the fuel. The liquid fuel is advisable to supply with saturated hydrogen for the safety of the heat engine operation. The design of the hydrogen fuel saturation system with a special hydrogen sensor based on the MQ-8 sensor was proposed. The system of protection of the research stand from unauthorized emissions of hydrogen into the environment has been worked out. The protection ensures the shutdown of the stand equipment when the hydrogen concentration in the zone of its generation and supply to the fuel is at the level of 1%.

DIESEL ENGINE OPERATION IN USE OF FUEL WITH ADDITIVES

2018 ◽  
pp. 18-24
Author(s):  
Petar Kazakov ◽  
Atanas Iliev ◽  
Emil Marinov
Keyword(s):  
Diesel Engine ◽  
Fuel Consumption ◽  
Diesel Fuel ◽  
Internal Combustion Engines ◽  
Experimental Studies ◽  
Combustion Engines ◽  
Engine Operation ◽  
Factors Affecting ◽  
Operating Modes ◽  
Positive Effects

Over the decades, more attention has been paid to emissions from the means of transport and the use of different fuels and combustion fuels for the operation of internal combustion engines than on fuel consumption. This, in turn, enables research into products that are said to reduce fuel consumption. The report summarizes four studies of fuel-related innovation products. The studies covered by this report are conducted with diesel fuel and usually contain diesel fuel and three additives for it. Manufacturers of additives are based on already existing studies showing a 10-30% reduction in fuel consumption. Comparative experimental studies related to the use of commercially available diesel fuel with and without the use of additives have been performed in laboratory conditions. The studies were carried out on a stationary diesel engine СМД-17КН equipped with brake КИ1368В. Repeated results were recorded, but they did not confirm the significant positive effect of additives on specific fuel consumption. In some cases, the factors affecting errors in this type of research on the effectiveness of fuel additives for commercial purposes are considered. The reasons for the positive effects of such use of additives in certain engine operating modes are also clarified.

OPTIMIZATION OF GAS-DIESEL ENGINE REGULATION AS A METHOD OF IMPROVING ITS ECOLOGICAL CHARACTERISTICS

2021 ◽  
pp. 28-32
Author(s):  
VALERIY L. CHUMAKOV ◽  
Keyword(s):  
Carbon Monoxide ◽  
Diesel Engine ◽  
Nitrogen Oxides ◽  
Diesel Fuel ◽  
Hydrocarbon Fuel ◽  
Load Range ◽  
Engine Operation ◽  
Exhaust Gases ◽  
Wide Range ◽  
Diesel Cycle

The paper shows some ways to improve the environmental characteristics of a diesel engine using gaseous hydrocarbon fuel and operating the engine in a gas-diesel cycle mode. Some possibilities to reduce toxic components of exhaust gases in a gas-diesel engine operating on liquefi ed propane-butane mixtures have been studied. Experiments carried out in a wide range of load from 10 to 100% and speed from 1400 to 2000 rpm showed that the gas-diesel engine provides a suffi ciently high level of diesel fuel replacement with gas hydrocarbon fuel. The authors indicate some eff ective ways to reduce the toxicity of exhaust gases. The engine power should be adjusted by the simultaneous supply of fuel, gas and throttling the air charge in the intake manifold. This method enriches the fi rst combusting portions to reduce nitrogen oxides and maintains the depletion of the main charge within the fl ammability limits of the gas-air charge to reduce carbon monoxide and hydrocarbons. The authors found that when the engine operates in a gas-diesel cycle mode, the power change provides a decrease in nitrogen oxide emissions of gas-diesel fuel only due to gas supply in almost the entire load range as compared to the pure diesel. At high loads (more than 80%) stable engine operation is ensured up to 90% of diesel fuel replaced by gas. Even at 10% of diesel fuel used the concentration of nitrogen oxides decreases by at least 15…20% as compared with a diesel engine in the entire load range. However, there is an increased emission of hydrocarbons and carbon monoxide in the exhaust gases. Further experimental studies have shown that optimization of the gas diesel regulation can reduce the mass emission of nitrogen oxides contained in exhaust gases in 2…3 times and greatly reduce the emission of incomplete combustion products – carbon monoxide and hydrocarbons.

Fuel Composition Effects on Forced Ignition of Liquid Fuel Sprays

2018 ◽  
Author(s):  
Sheng Wei ◽  
Brandon Sforzo ◽  
Jerry Seitzman
Keyword(s):  
Physical Properties ◽  
Liquid Fuel ◽  
Chemical Properties ◽  
Reaction Rates ◽  
High Energy ◽  
Fuel Spray ◽  
Successful Outcome ◽  
Fuel Composition ◽  
Ignition Probability ◽  
Fuel Sprays

In gas turbine combustors, ignition is achieved by using sparks from igniters to start a flame. The process of sparks interacting with fuel/air mixture and creating self-sustained flames is termed forced ignition. Physical and chemical properties of a liquid fuel can influence forced ignition. The physical effects manifest through processes such as droplet atomization, spray distribution, and vaporization rate. The chemical effects impact reaction rates and heat release. This study focuses on the effect of fuel composition on forced ignition of fuel sprays in a well-controlled flow with a commercial style igniter. A facility previously used to examine prevaporized, premixed liquid fuel-air mixtures is modified and employed to study forced ignition of liquid fuel sprays. In our experiments, a wall-mounted, high energy, recessed cavity discharge igniter operating at 15 Hz with average spark energy of 1.25 J is used to ignite liquid fuel spray produced by a pressure atomizer located in a uniform air coflow. The successful outcome of each ignition events is characterized by the (continued) presence of chemiluminescence 2 ms after spark discharge, as detected by a high-speed camera. The ignition probability is defined as the fraction of successful sparks at a fixed condition, with the number of events evaluated for each fuel typically in the range 600–1200. Ten fuels were tested, including standard distillate jet fuels (e.g., JP-8 and Jet-A), as well as many distillate and alternative fuel blends, technical grade n-dodecane, and surrogates composed of a small number of components. During the experiments, the air temperature is controlled at 27 C and the fuel temperature is controlled at 21 C. Experiments are conducted at a global equivalence ratio of 0.55. Results show that ignition probabilities correlate strongly to liquid fuel viscosity (presumably through droplet atomization) and vapor pressure (or recovery temperature), as smaller droplets of a more volatile fuel would lead to increased vaporization rates. This allows the kernel to transition to a self-sustained flame before entrainment reduces its temperature to a point where chemical rates are too slow. Chemical properties of the fuel showed little influence, except when the fuels had similar physical properties. This result demonstrates that physical properties of liquid fuels have dominating effects on forced ignition of liquid fuel spray in coflow air.

scholarly journals Hydrogen Diffusion Coefficient, Hydrogen Solution Coefficient and Hydrogen Permeability of Nb-TiNi Eutectic Alloy

2010 ◽  
Vol 638-642 ◽  
pp. 1131-1136
Author(s):  
Wei Liang Wang ◽  
Kazuhiro Ishikawa ◽  
Kiyoshi Aoki
Keyword(s):  
Diffusion Coefficient ◽  
Hydrogen Absorption ◽  
Hydrogen Diffusion ◽  
Hydrogen Permeability ◽  
K Value ◽  
Hydrogen Flow ◽  
Hydrogen Diffusion Coefficient ◽  
High K ◽  
Pressure Region ◽  
The Difference

In general, hydrogen permeabilityΦ of the alloy membrane is expressed as the product of the hydrogen diffusion coefficient D and the hydrogen solution coefficient K. Therefore, to improve the hydrogen permeability efficiently, the values of K and D should be separately considered. In the present study, hydrogen absorption and permeation behaviors of the Nb19Ti40Ni41 alloy consisting of the eutectic phase are investigated by measuring pressure-composition-isotherm (PCI) and by the hydrogen flow method and compared with those of palladium. The hydrogen absorption in the Nb19Ti40Ni41 alloy does not obey the Sieverts’ law in the pressure region of 0-1.0MPa at 523K, but it shows linear relationship between the difference in the square root of hydrogen pressure and hydrogen content between 0.1 and 0.4MPa. Although the value of D for the Nb19Ti40Ni41 alloy is considerably lower than that of palladium, its high K value enhances the hydrogen permeability Φ. It is suggested that the enhancement of D by microstructural control for Nb19Ti40Ni41 alloy is effective for improvement of Φ.

scholarly journals Volume Dependence of Hydrogen Sorption and Desorption Diffusion in Cylindrical Polymers

2021 ◽  
Author(s):  
Jae Kap Jung ◽  
Kyu-Tae Kim ◽  
Un Bong Baek ◽  
Seung Hoon Nahm
Keyword(s):  
Diffusion Coefficient ◽  
Hydrogen Diffusion ◽  
Chain Scission ◽  
Volumetric Analysis ◽  
Cylindrical Sample ◽  
Desorption Process ◽  
Hydrogen Molecules ◽  
Volume Dependence ◽  
Analysis Technique ◽  
Volume Swelling

Abstract We have investigated the volume effects on hydrogen diffusion properties in both sorption and desorption processes by employing a volumetric analysis technique. The total uptake (𝐶∞), total desorbed content (𝐶0), sorption diffusion coefficient (Ds), desorption diffusion coefficient (Dd), sorption and desorption equilibrium time of hydrogen in two rubbery polymers are determined relative to the diameter and thickness of the cylindrical sample in the two processes. 𝐶∞ and 𝐶0 do not demonstrate the appreciable volume dependence for all rubbers. The identical values in 𝐶∞ and 𝐶0 indicate the reversibility between sorption and desorption, which is interpreted by the occurrence of physisorption rather than chemisorption by introducing hydrogen molecules. The larger Dd values in the desorption process than Ds may be attributed to increased amorphous phase and volume swelling caused by increased hydrogen voids and polymer chain scission after decompression. The time to reach equilibrium in both sorption and desorption processes was found to be linearly proportional to the square of thickness above an aspect ratio of 3.7, which is consistent with the numerical simulations based on the solution of Fick’s law. This finding could be used to predict the equilibrium adsorption time depending on the sample size in the polymer.

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