scholarly journals CO2 Metallothermal Reduction to Graphene: The Influence of Zn

2021 ◽  
Vol 3 ◽  
Author(s):  
Carolina Luchetta ◽  
Erica C. Oliveira Munsignatti ◽  
Heloise O. Pastore

CO2 is the most important greenhouse gas involved in climate change; it has been a concern for many years and will remain as such in the years to come. CO2 adsorption and CO2 utilization have been studied as methods to mitigate the concentration of the gas in the atmosphere by sequestering and transforming it into a value-added product, capable of being commercialized. With those aims in mind, CO2 reduction into 3D graphene was studied using a Zn–Mg mixture. The results show that Mg is the only reducing agent, and Zn acted as a porogen during graphene formation as the energy released by the reaction between CO2 and Mg is enough to evaporate Zn. Thus, Zn vapor increases graphene porosity and increases the contact of CO2 with Mg, yielding larger masses of graphene. A relationship between the Zn–Mg ratio and the reaction yield was found.

2012 ◽  
Vol 47 (11) ◽  
pp. 1571-1576 ◽  
Author(s):  
Mohammed A. Gondal ◽  
Mohammad A. Ali ◽  
Xiao F. Chang ◽  
Kai Shen ◽  
Qing Y. Xu ◽  
...  

Eos ◽  
2019 ◽  
Vol 100 ◽  
Author(s):  
Jenessa Duncombe

Experts have given the United States a warning: Reduce greenhouse gas emissions, or suffer the consequences of lower productivity and a sicker population for generations to come.


2021 ◽  
Vol 9 ◽  
Author(s):  
Paloma Trascasa-Castro ◽  
Christopher J. Smith

Climate change is one of the most serious problems that humans face today, but until now progress in stopping it has been slow. Climate simulations show that Earth will only stop warming when we reach “net zero” emissions. This means that carbon dioxide (CO2) emissions are cancelled out by an equal amount of greenhouse gas removal from the atmosphere. Worldwide efforts to achieve net zero emissions by 2050 are necessary to avoid some of the worst effects of climate change. Achieving net zero will require huge changes to our society. While there are some things we can all do to fight climate change, the biggest changes need to come from the way our businesses and countries are run, where we get our energy from, how we travel, and how much “stuff” we consume and waste. By taking urgent action, we can ensure the future well-being of billions of people worldwide.


Author(s):  
Jeremy T. Kerr ◽  
Heather M. Kharouba

It is increasingly recognized that, as a result of ever-growing atmospheric inputs of greenhouse gases like carbon dioxide from the burning of fossil fuels, the climate is changing regionally and globally. This has been affirmed, in light of increasing scientific understanding, in the latest report of the Intergovernmental Panel on Climate Change (IPCC) in 2001, by the US National Academy of Sciences in its 2001 report, and most recently by a statement from the Science Academies of all G8 countries, along with China, India, and Brazil. This latter statement calls on the G8 nations to ‘Identify cost-effective steps that can be taken now to contribute to substantial and longterm reduction in net global greenhouse gas emission [and to] recognize that delayed action will increase the risk of adverse environmental effects and will likely incur a greater cost’. Global warming caused by elevated greenhouse gas levels is expressed with long time lags, which can be difficult to appreciate by those unfamiliar with physical systems. Once in the atmosphere, the characteristic residence time of a carbon dioxide molecule is a century. And the time taken for the ocean’s expansion to come to equilibrium with a given level of greenhouse warming is several centuries. If current trends continue, by around 2050 atmospheric carbon dioxide levels will have reached more than 500 parts per million, which is nearly double pre-industrial levels. The last time our planet experienced levels this high was some 20–40 million years ago, when sea levels were around 100m higher than today. It can also be difficult to relate intuitively to the seriousness of the roughly 0.7 °C average warming of the Earth’s surface over the past century. And the warning by the IPCC in its 2001 report, that global warming would be in the range of 1.4–5.8 °C by the end of this century, may also seem unalarming when we experience such temperature swings from one day to the next. There is, however, a huge difference between daily fluctuations, and global averages sustained year on year; the difference in average global temperature between today and the last ice age is only around 5 °C.


2018 ◽  
Author(s):  
Younghwan Cha ◽  
Jung-In Lee ◽  
Panpan Dong ◽  
Xiahui Zhang ◽  
Min-Kyu Song

A novel strategy for the oxidation of Mg-based intermetallic compounds using CO<sub>2</sub> as an oxidizing agent was realized via simple thermal treatment, called ‘CO2-thermic Oxidation Process (CO-OP)’. Furthermore, as a value-added application, electrochemical properties of one of the reaction products (carbon-coated macroporous silicon) was evaluated. Considering the facile tunability of the chemical/physical properties of Mg-based intermetallics, we believe that this route can provide a simple and versatile platform for functional energy materials synthesis as well as CO<sub>2</sub> chemical utilization in an environment-friendly and sustainable way.


Climate justice requires sharing the burdens and benefits of climate change and its resolution equitably and fairly. It brings together justice between generations and justice within generations. The United Nations Sustainable Development Goals summit in September 2015, and the Conference of Parties to the Framework Convention on Climate Change in Paris in December 2015, brought climate justice center stage in global discussions. In the run up to Paris, Mary Robinson, former president of Ireland and the UN Secretary General’s Special Envoy for Climate Change, instituted the Climate Justice Dialogue. The editors of this volume, an economist and a philosopher, served on the High Level Advisory Committee of the Climate Justice Dialogue. They noted the overlap and mutual enforcement between the economic and philosophical discourses on climate justice. But they also noted the great need for these strands to come together to support the public and policy discourse. This volume is the result.


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