scholarly journals Effects of Water-to-Cement Ratio on Pore Structure Evolution and Strength Development of Cement Slurry Based on HYMOSTRUC3D and Micro-CT

2021 ◽  
Vol 11 (7) ◽  
pp. 3063
Author(s):  
Shaojun Zheng ◽  
Tianle Liu ◽  
Guosheng Jiang ◽  
Changliang Fang ◽  
Bo Qu ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Pore Structure ◽  
Regression Function ◽  
Structure Evolution ◽  
Strength Development ◽  
Cement Stone ◽  
Micro Ct ◽  
Capillary Porosity ◽  
Cement Slurry ◽  
Water To Cement Ratio

Changing the water-to-cement ratio is one of the major ways to develop cement slurry with different densities, which in turn will greatly affect the pore structure and mechanical properties of cement slurry. In the current study, the cement hydration model HYMOSTRUC3D was used to investigate the effects of water-to-cement (w/c) ratio (0.40, 0.44, 0.50) on the pore structure evolution and strength development of cement slurry. The microstructure of the cement stone was characterized via scanning electron microscope (SEM) and micro-computed tomography (micro-CT), and the mechanical strength of the cement stone was tested and analyzed via a mechanical tester. The simulated compressive strength and capillary porosity are in good agreement with the measured data, where the relative error between the simulated results and measured results are within 0.6~10.7% and 13.04~25.31%, respectively. The capillary porosity is proved as the main factor affecting the compressive strength of cement stone with different w/c ratios. Herein, the mathematical relationship between the measured capillary porosity and compressive strength could be well fitted via the mathematical prediction models of the Balshin function (R2 = 0.95), Ryshkewitch function (R2 = 0.94), Schiller function (R2 = 0.96), and the linear regression function (R2 = 0.95). Moreover, the linear regression function (y = −2.38x + 82.76) can be used to characterize and predict the quantitative relationship between the compressive strength and capillary porosity of cement stone. The findings in this study will provide a reference value in the fields of oil and gas cementing and building concrete.

scholarly journals Strength and Pore Structure Development of High-Plasticity Clay Treated with MK-Blended Cement

2019 ◽  
Vol 2019 ◽  
pp. 1-8
Author(s):  
Qian Guo ◽  
Mingli Wei ◽  
Haochen Xue ◽  
Changhui Gao ◽  
Guangyin Du
Keyword(s):  
Compressive Strength ◽  
Pore Structure ◽  
Unconfined Compressive Strength ◽  
Structure Refinement ◽  
Structure Evolution ◽  
Strength Development ◽  
High Plasticity ◽  
Soil Mixture ◽  
Treated Soil ◽  
High Plasticity Clay

This paper focuses on the strength development and pore structure evolution of high-plasticity clay mixtures treated with metakaolin- (MK-) blended ordinary Portland cement (OPC). The unconfined compressive strength (fcu) of treated soil mixtures is measured to study the effect of MK replacement. The microstructural study is carried out by mercury intrusion porosimetry (MIP), scanning electron microscopy (SEM), and X-ray diffraction (XRD). The results showed that the MK replacement led to the decrease of unconfined compressive strength of OPC-treated soil mixture cured for 28 days, but the influence on 7 days strength was negligible. However, the MK addition also enhanced the unconfined compressive strength significantly. The MK addition provided more cementitious products by secondary hydration and pozzolanic reaction, which would give rise to a notable filling effect by turning the large pores (1 to 10 μm) into smaller ones (0.1 to 1 μm). However, the MK replacement led to a decrease of cementitious products due to the lack of calcium hydroxide (CH) in soil mixture, and thus the effect on pore structure refinement was reduced. Nevertheless, the presence of MK enhanced the unconfined compressive strength cured for 7 days, due to the high reactivity of MK with CH.

Chloride Ingress Control and Promotion of Internal Curing in Concrete Using Superabsorbent Polymer

2021 ◽  
Vol 888 ◽  
pp. 67-75
Author(s):  
Ariel Verzosa Melendres ◽  
Napoleon Solo Dela Cruz ◽  
Araceli Magsino Monsada ◽  
Rolan Pepito Vera Cruz
Keyword(s):  
Compressive Strength ◽  
Cementitious Materials ◽  
Internal Curing ◽  
Mix Design ◽  
Chloride Ingress ◽  
Superabsorbent Polymer ◽  
Cement Slurry ◽  
Chloride Permeability ◽  
Cement Ratio ◽  
Water To Cement Ratio

Chloride ingress into concrete from the surrounding environment can result in the corrosion of the embedded steel reinforcement and cause damage to the concrete. Superabsorbent polymer (SAP) with fine particle size was incorporated into the structure of concrete for controlling the chloride ingress and improving its compressive strength via promotion of internal curing. The SAP used in this study was evaluated for its absorbency property when exposed to cementitious environment such as aqueous solution of Ca (OH)2 and cement slurry. The results were compared to that in sodium chloride solution, the environment where absorbency of most of the SAP found in the market are well studied. Results showed that although SAP absorbency decreased with increasing concentration of Ca (OH)2 and cement, the results suggest that water containing cementitious materials are able to be absorbed by SAP. Chloride ingress into 28-day cured concrete specimens were determined using Rapid Chloride Penetration Test (RCPT) method employing 60V DC driving force. Concrete samples with size of 50 mm height x 100 mm diameter were prepared using a M25 mix design with 0.4 and 0.45 water to cement ratios and different percentages of SAP such as 0.05%, 0.1% and 0.15% with respect to cement mass. Results showed that concrete with 0.15% SAP gave the best result with 14% less chloride permeability than concrete with no SAP for a 0.4 water to cement ratio. Concrete samples for compressive strength tests with size of 200 mm height x 100 mm diameter were prepared using the same mix design and percentages of SAP and cured for 28 days. Results showed that the best results for compressive strength was found at 0.1% SAP at a 0.4 water to cement ratio which can be attributed to internal curing provided by SAP.

Development and Change of Compressive Strength for Class G Oil Well Cement under High Temperature

2014 ◽  
Vol 941-944 ◽  
pp. 1441-1444 ◽  
Author(s):  
Jing Fu Zhang ◽  
Kai Liu ◽  
Rui Xue Hou ◽  
Bo Wang ◽  
Jin Long Yang
Keyword(s):  
Compressive Strength ◽  
High Temperature ◽  
Initial Period ◽  
Strength Development ◽  
Oil Well ◽  
Curing Time ◽  
Cement Slurry ◽  
Critical Temperatures ◽  
Oil Well Cement ◽  
Well Cement

The compressive strength of oil well cement would be damaged by high temperature in deep oil wells, which was caused by the obvious change of the components and microstructure of cement hydration products. The adaptability of common oil well cement for cementing under higher temperatures was confined by above reasons. Characteristics of development and change of compressive strength of Class G oil well cement were studied under different temperatures by using Static Gel Strength Analyzer and High Temperature-High Pressure curing chamber. The influence law of temperature and silica sands on compressive strength was analyzed. The results showed that the critical temperatures at which the compressive strength begun to decline were about 110°C and 150°C respectively; The compressive strength increased with curing time during the initial period and would reduced after it reached a certain value when temperature exceeded 110°C; For cement with silica sands, the compressive strength development trend was in the shape of two-stage form with increase of curing time within the range of 110~150°C, but for 160~200°C temperature range the development form was in the shape of single stage; The reasonable amounts of silica sands which would be added to cement slurry to enhance the compressive strength of hardening paste were determined to be 30%~40%.

Research on New Materials to Improve the Bonding Strength and Relieve Contamination of the Cement Slurry with Oil Based Muds

2016 ◽  
Vol 847 ◽  
pp. 510-518
Author(s):  
Zao Yuan Li ◽  
Hong Hua Liu ◽  
Xiao Yang Guo ◽  
Xiao Wei Cheng ◽  
Hong Juan Ou ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Shale Gas ◽  
Bonding Strength ◽  
Filter Cake ◽  
Honeycomb Structure ◽  
Cement Stone ◽  
New Materials ◽  
Cement Slurry ◽  
Current Application ◽  
Gas Well

During shale gas well drilling and completion, the oil based muds (OBMs) would reduce the bonding strength of cement slurry by filter-cake and oil-wettability. At the same time, mixing cement slurry with the OBMs can lead to contamination, and subsequently creates significant problems, such as, reducing the normal thickening time and the compressive strength, and hence affecting the quality of the cementing of the shale gas well. Therefore in the present investigation, the mechanism of the interface displacement, wetting conversion and the contamination was explored by Atomic Force Microscopy (AFM), X-Ray Diffraction (XRD), scanning electron microscope (SEM) and other methods. And then the new materials with the enhanced bonding strength and the contamination relieving by OBMs were obtained. The results showed that the chemical composition of filter-cake determined the properties of chemical preflush, the combined systems (LSS) efficiently flushed filter-cake and increased the bonding strength. It has been found that the reverse wetting agent (APG) has better reverse wetting properties than Tarim Oilfield current application system, which effectively changes the wettability of cementing surface from lipophilicity to hydrophilic. The OBMs and cement slurry mixing generated the emulsion structure and honeycomb structure, and the structures can affect the rheology and the strength of cement slurry; the contaminative relieve agent (SCW) can form a thin film on the surface of the cement stone, the film covers the hole and improves cement compressive strength, thus the SCW can relieve the contamination by OBMs.

scholarly journals Strength Development and Pore Structure Characterisation of Binary Alkali-activated Binder Based on Tungsten Mining Waste

2020 ◽  
Author(s):  
Naim Sedira ◽  
João Castro-Gomes
Keyword(s):  
Compressive Strength ◽  
Pore Structure ◽  
Mining Waste ◽  
Strength Development ◽  
Red Clay ◽  
Alumino Silicate ◽  
Red Clay Brick ◽  
Electric Arc Furnace Slag ◽  
Furnace Slag ◽  
Alkali Activated

The mineralogical properties of tungsten mining waste mud (TMWM) make its valorisation and re-usage as an alumino-silicate source material to produce an alkali-activated binder without calcination is a challenge. Moreover, the dissolution of silicate and alumina species from TMWM is very slow. Despite the crystallinity of TMWM, this study demonstrates that its combination with other sources of the alumino-silicate source was the materials–such as red clay brick waste(RCBW),ground granulated blast furnace slag (GGBFS) and electric arc furnace slag (EAFS) – improved the compressive strength and the pore structure of the alkali-activated matrix.Thecombinedprecursors (90 vt.%TMWM+10 vt.%RCBW, 90 vt.%TMWM+10 vt.%GGBFS, and 90 vt.%TMWM+10 vt.%EAFS) were activated using a combination of alkaline activator solutions (sodium silicate and sodium hydroxide) with the ratio of 1:3(66.6wt.%sodiumsilicatecombined with 33.33 wt.% of NaOH 10M). The results show that the compressive strength increased from11.23MPa at 28 days to reach 24.98MPawhentheTMWMwaspartially replacedby10vt.%RCBW. In addition,this study shows that the interconnected porosity decreased where the critical pore size was reduced from 21.28 µm to 0.55 µm for the tungsten mining waste-based alkali-activated binder and the binary alkali-activated binder based on TMWM and RCBW. Keywords: Mining Waste, Alkali-activated, Microstructure, MIP, Metakaolin

scholarly journals APPLICATION OF HYDROPHOBIC CEMENT SLURRIES «RAN-M» OF «RAMSINKS-2M» GROUP TO AVOID FLUID KICK

2018 ◽  
Vol 2 (49) ◽  
pp. 295-300
Author(s):  
O. I. Nalyvaiko ◽  
O. L. Melnikov ◽  
L. G. Nalyvaiko ◽  
R. V. Petrash ◽  
V. N. Khivrenko
Keyword(s):  
Strength Development ◽  
Cement Stone ◽  
Laboratory Studies ◽  
Cement Slurry ◽  
Technical Parameters ◽  
Density Separation ◽  
Selection Of

Laboratory studies of cement slurry and cement stone is established that hydrophobic cement slurry «RAN-M» consists of NTPha additives for well cements PTC-1-100 and «Ramsinks-2M». In the laboratory confirmed the technical parameters of the newest hydrophobic cement slurries (mobility, density, separation, pumpability, etc.) according to the standard requirements in the respective devices. Done such works as: implementation of the selection of formulations of cement slurries with different rate of strength development for different temperature integrals.

Development and Implementation of the Method of Cementing Production Casing 178 mm with Pressure on the Cement Slurry on the East Part of the Orenburg Oil and Gas Condensate Field

2021 ◽  
Author(s):  
Maxim Viktorovich Miklyaev ◽  
Ivan Vyacheslavovich Denisov ◽  
Ivan Mikhailovich Gavrilin
Keyword(s):  
Economic Efficiency ◽  
Oil And Gas ◽  
Excess Pressure ◽  
Strength Development ◽  
Cement Stone ◽  
Drilling Fluids ◽  
Cement Slurry ◽  
Negative Effect ◽  
Sustained Casing Pressure ◽  
Well Abandonment

Abstract Well construction in the Volga-Ural Region faces different sorts of complications, the most common ones being the loss of drilling fluids and rockslides. Such complications may cause considerable financial losses due to non-productive time (NPT) and longer well construction periods. Moreover, there are complications, which might occur both during well construction and during its exploitation. The commonest complications are sustained casing pressure (SCP) and annular flow. The complications, which occur when operating a well, also have a negative effect on the economic efficiency of well operation and call for additional actions, for example, repair and insulation works, which require well shutdown and killing, though a desired outcome still cannot be guaranteed; moreover, it is possible that several different operations may have to be carried out. In addition, the occurrence of SCP during well life is one of the most crucial problems that may cause well abandonment due to high risks posed by its operation. It is known that the main reasons for SCP are as follows: Channels in cement stone Casing leaks Leaks in wellhead connections To resolve the problem of cement stone channeling, several measures were taken, such as revising cement slurry designs, cutting time for setting strings on slips, applying two-stage cementing, etc. These measures were not successful, besides, they caused additional expenses for extra equipment (for example, a cementer). In order to reduce the risk of cement stone channeling, a cementing method is required that will allow to apply excess pressure on cement slurry during the period of transition and early strength development. To achieve this goal, a well-known method of controlled pressure cementing may be applied. Its main drawback, however, is that it requires much extra equipment, thus increasing operation expenses. In addition, the abovementioned method allows affecting the cement stone only during the operation process and / or during the waiting on cement (WOC) time. Upon receiving the results of the implemented measures and considering the existing technologies and evaluating the economic efficiency, the need was flagged for developing a combined cementing method. The goal of this method is to modify the production string cementing method with a view to applying excess pressure on cement stone during strength development and throughout the well lifecycle. The introduction of this lining method does not lead to an increase in well construction costs and considerably reduces the risks of losing a well from the production well stock.

Potentials of Nano-Designed Plugs: Implications for Short and Long Term Well Integrity

2019 ◽  
Author(s):  
Raymos Kimanzi ◽  
Harshkumar Patel ◽  
Mahmoud Khalifeh ◽  
Saeed Salehi ◽  
Catalin Teodoriu
Keyword(s):  
Compressive Strength ◽  
Oil And Gas ◽  
Strength Development ◽  
Cement Slurry ◽  
Preparation Conditions ◽  
Cement System ◽  
Sustained Casing Pressure ◽  
Short And Long Term ◽  
Casing Pressure

Abstract Cement plugs are designed to protect the integrity of oil and gas wells by mitigating movement of formation fluids and leaks. A failure of the cement sheath can result in the loss of zonal isolation, which can lead to sustained casing pressure. In this study, nanosynthetic graphite with designed expansive properties has been introduced to fresh cement slurry. The expansive properties of nanosynthetic graphite were achieved by controlling the preparation conditions. The material was made from synthetic graphite and has a surface area ranging from 325–375 m2/gram. Several tests including compressive strength, rheology, and thickening time were performed. An addition of 1% nanosynthetic graphite with appropriate reactivity was sufficient to maintain expansion in the cement system, leading to an early compressive strength development. It has excellent thermal and electrical conductivity and can be used to design a cement system with short and long-term integrity. Rheology and thickening time tests confirmed its pumpability. Controlling the concentration of the additive is a promising method that can be used to mitigate gas migration in gas bearing and shallow gas formations.

scholarly journals Hybrid Effect of Wollastonite Fiber and Carbon Fiber on the Mechanical Properties of Oil Well Cement Pastes

2020 ◽  
Vol 2020 ◽  
pp. 1-9
Author(s):  
Jianglin Zhu ◽  
Jiangxiong Wei ◽  
Qijun Yu ◽  
Mingbiao Xu ◽  
Yuwei Luo
Keyword(s):  
Mechanical Properties ◽  
Compressive Strength ◽  
Carbon Fiber ◽  
Impact Strength ◽  
Flexural Strength ◽  
Cement Stone ◽  
Oil Well ◽  
Cement Slurry ◽  
Oil Well Cement ◽  
Well Cement

Oil well cement is a type of natural brittle material that cannot be used directly in cementing operations. Fiber is a type of material that can effectively improve the strength and toughness of cement stone, and hybrid fiber materials can more effectively improve the performance of a cement sample. To overcome the natural defects of oil well cement, the new mineral fiber, i.e., wollastonite fiber, and common carbon fiber were used in oil well cement, and the micromorphology, mechanical properties, and stress-strain behavior of the cement were evaluated. The experimental results show that carbon fiber and wollastonite fiber are randomly distributed in the cement paste. The mechanical properties of the cement paste are improved by bridging and pulling out. The compressive strength, flexural strength, and impact strength of cement stone containing only carbon fiber or wollastonite fiber are higher than those of the pure cement, but too many fibers are not conducive to the development of mechanical properties. A mixture of 0.3% carbon fiber with 6% wollastonite fiber in oil well cement slurry results in a greater increase in compressive strength, flexural strength, and impact strength. In addition, compared with blank cement stone, the strain of the mixed cement stone increases substantially, and the elastic modulus decreases by 37.8%. The experimental results supply technical support for the design of a high-performance cement slurry system.

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