scholarly journals Interfacial Dilational Viscoelasticity of Adsorption Layers at the Hydrocarbon/Water Interface: The Fractional Maxwell Model

2019 ◽  
Vol 3 (4) ◽  
pp. 66 ◽  
Author(s):  
Giuseppe Loglio ◽  
Volodymyr I. Kovalchuk ◽  
Alexey G. Bykov ◽  
Michele Ferrari ◽  
Jürgen Krägel ◽  
...  

In this communication, the single element version of the fractional Maxwell model (single-FMM or Scott–Blair model) is adopted to quantify the observed behavior of the linear interfacial dilational viscoelasticity. This mathematical tool is applied to the results obtained by capillary pressure experiments under low-gravity conditions aboard the International Space Station, for adsorption layers at the hydrocarbon/water interface. Two specific experimental sets of steady-state harmonic oscillations of interfacial area are reported, respectively: a drop of pure water into a Span-80 surfactant/paraffin-oil matrix and a pure n-hexane drop into a C13DMPO/TTAB mixed surfactants/aqueous-solution matrix. The fractional constitutive single-FMM is demonstrated to embrace the standard Maxwell model (MM) and the Lucassen–van-den-Tempel model (L–vdT), as particular cases. The single-FMM adequately fits the Span-80/paraffin-oil observed results, correctly predicting the frequency dependence of the complex viscoelastic modulus and the inherent phase-shift angle. In contrast, the single-FMM appears as a scarcely adequate tool to fit the observed behavior of the mixed-adsorption surfactants for the C13DMPO/TTAB/aqueous solution matrix (despite the single-FMM satisfactorily comparing to the phenomenology of the sole complex viscoelastic modulus). Further speculations are envisaged in order to devise combined FMM as rational guidance to interpret the properties and the interfacial structure of complex mixed surfactant adsorption systems.

Author(s):  
Adel Aschi ◽  
Abdehafidh Gharbi ◽  
Patrick Calmettes ◽  
Mohamed Daoud ◽  
Veronique Aguié-Béghin ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2020
Author(s):  
Baoquan Mao ◽  
Rui Zhu ◽  
Zhiqian Wang ◽  
Yuying Yang ◽  
Xiaoping Han ◽  
...  

To better describe its constitutive relation, we need a new constitutive equation for an important nonlinear elastic material, Mn-Cu damping alloy. In this work, we studied the nonlinear and hysteretic characteristics of the stress-strain curve of the M2052 alloy with the uniaxial cyclic tensile test with constant strain rate. The strain rate and amplitude correlations of M2052 resembled those of nonlinear viscoelastic material. Therefore, we created a new constitutive equation for the M2052 damping alloy by modifying the fractional Maxwell model, and we used the genetic algorithm to carry out numerical fitting with MATLAB. By comparing with the experimental data, we confirmed that the new constitutive equation could accurately depict the nonlinear constitutive relation and hysteretic property of the damping alloy. Taken together, this new constitutive equation for Mn-Cu damping alloy based on the fractional Maxwell model can serve as an effective tool for further studies of the constitutive relation of the Mn-Cu damping alloys.


2020 ◽  
Vol 2020 ◽  
pp. 1-8
Author(s):  
Irene Nepita ◽  
Rodolfo Repetto ◽  
Jan O. Pralits ◽  
Mario R. Romano ◽  
Francesca Ravera ◽  
...  

The present work is aimed at investigating the chemicophysical properties of the interface between silicone oils (SOs) used in vitreoretinal surgery and aqueous solutions, in the presence of surfactant biomolecules. Such molecules are thought to play an important role in the formation of SO emulsions in vitrectomised eyes, in which the natural vitreous body has been replaced with a SO. In particular, we have measured the interfacial tension (IT) and the interfacial dilational viscoelasticity (DV) of the interface between SO (Siluron 1000) and serum proteins (albumin and γ-globulins) at various concentrations in a Dulbecco alkaline buffer. The equilibrium IT value is relevant for the onset of emulsification, and the DV influences the stability of an emulsion, once formed. The study is complemented by preliminary emulsification tests. The experimental results show that, when proteins are dissolved in the aqueous solution, the rheological properties of the interface change. The IT decreases significantly for physiological protein concentrations, and the DV modulus achieves high values, even for small protein concentrations. The emulsification tests confirm that, in the presence of proteins, emulsions are stable on the time scale of months. We conclude that the measured values of IT in the presence of serum proteins are compatible with the promotion of droplet formation, which, in addition, are expected to be stable against coalescence. Adsorption of biomolecules at the interface with the SO is, therefore, likely to play an important role in the generation of an emulsion in eyes subjected to vitrectomy. These findings are relevant to identify strategies to avoid or control the formation of emulsions in eyes.


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