Dynamic properties of Span-80 adsorbed layers at paraffin-oil/water interface: Capillary pressure experiments under low gravity conditions

Author(s):  
P. Pandolfini ◽  
G. Loglio ◽  
F. Ravera ◽  
L. Liggieri ◽  
V.I. Kovalchuk ◽  
...  
Author(s):  
Qianli Ma ◽  
Wei Wang ◽  
Yang Liu ◽  
Juheng Yang ◽  
Bohui Shi ◽  
...  

2019 ◽  
Vol 290 ◽  
pp. 111186 ◽  
Author(s):  
Hira Zaman ◽  
Nisar Ali ◽  
Anwar ul Haq Ali Shah ◽  
Xiaoyan Gao ◽  
Shizhong Zhang ◽  
...  

2005 ◽  
Vol 19 (4) ◽  
pp. 1337-1341 ◽  
Author(s):  
Sandrine Poteau ◽  
Jean-François Argillier ◽  
Dominique Langevin ◽  
Frédéric Pincet ◽  
Eric Perez

2007 ◽  
Vol 10 (02) ◽  
pp. 191-204 ◽  
Author(s):  
Shehadeh K. Masalmeh ◽  
Issa M. Abu-Shiekah ◽  
Xudong Jing

Summary An oil/water capillary transition zone often contains a sizable portion of a field's initial oil in place, especially for those carbonate reservoirs with low matrix permeability. The field-development plan and ultimate recovery may be influenced heavily by how much oil can be recovered from the transition zone. This in turn depends on a number of geological and petrophysical properties that influence the distribution of initial oil saturation (Sor) against depth, and on the rock and fluid interactions that control the residual oil saturation (Sor), capillary pressure, and relative permeability characteristics as a function of initial oil saturation. Because of the general lack of relevant experimental data and the insufficient physical understanding of the characteristics of the transition zone, modeling both the static and dynamic properties of carbonate fields with large transition zones remains an ongoing challenge. In this paper, we first review the transition-zone definition and the current limitations in modeling transition zones. We describe the methodology recently developed, based on extensive experimental measurements and numerical simulation, for modeling both static and dynamic properties in capillary transition zones. We then address how to calculate initial-oil-saturation distribution in the carbonate fields by reconciling log and core data and taking into account the effect of reservoir wettability and its impact on petrophysical interpretations. The effects of relative permeability and imbibition capillary pressure curves on oil recovery in heterogeneous reservoirs with large transition zones are assessed. It is shown that a proper description of relative permeability and capillary pressure curves including hysteresis, based on experimental special-core-analysis (SCAL) data, has a significant impact on the field-performance predictions, especially for heterogeneous reservoirs with transition zones. Introduction The reservoir interval from the oil/water contact (OWC) to a level at which water saturation reaches irreducible is referred to as the capillary transition zone. Fig. 1 illustrates a typical capillary transition zone in a homogeneous reservoir interval within which both the oil and water phases are mobile. The balance of capillary and buoyancy forces controls this so-called capillary transition zone during the primary-drainage process of oil migrating into an initially water-filled reservoir trap. Because the water-filled rock is originally water-wet, a certain threshold pressure must be reached before the capillary pressure in the largest pore can be overcome and the oil can start to enter the pore. Hence, the largest pore throat determines the minimum capillary rise above the free-water level (FWL). As shown schematically in Fig. 2, close to the OWC, the oil/water pressure differential (i.e., capillary pressure) is small; therefore, only the large pores can be filled with oil. As the distance above the OWC increases, an increasing proportion of smaller pores are entered by oil owing to the increasing capillary pressure with height above the FWL. The height of the transition zone and its saturation distribution is determined by the range and distribution of pore sizes within the rock, as well as the interfacial-force and density difference between the two immiscible fluids.


2019 ◽  
Vol 3 (4) ◽  
pp. 66 ◽  
Author(s):  
Giuseppe Loglio ◽  
Volodymyr I. Kovalchuk ◽  
Alexey G. Bykov ◽  
Michele Ferrari ◽  
Jürgen Krägel ◽  
...  

In this communication, the single element version of the fractional Maxwell model (single-FMM or Scott–Blair model) is adopted to quantify the observed behavior of the linear interfacial dilational viscoelasticity. This mathematical tool is applied to the results obtained by capillary pressure experiments under low-gravity conditions aboard the International Space Station, for adsorption layers at the hydrocarbon/water interface. Two specific experimental sets of steady-state harmonic oscillations of interfacial area are reported, respectively: a drop of pure water into a Span-80 surfactant/paraffin-oil matrix and a pure n-hexane drop into a C13DMPO/TTAB mixed surfactants/aqueous-solution matrix. The fractional constitutive single-FMM is demonstrated to embrace the standard Maxwell model (MM) and the Lucassen–van-den-Tempel model (L–vdT), as particular cases. The single-FMM adequately fits the Span-80/paraffin-oil observed results, correctly predicting the frequency dependence of the complex viscoelastic modulus and the inherent phase-shift angle. In contrast, the single-FMM appears as a scarcely adequate tool to fit the observed behavior of the mixed-adsorption surfactants for the C13DMPO/TTAB/aqueous solution matrix (despite the single-FMM satisfactorily comparing to the phenomenology of the sole complex viscoelastic modulus). Further speculations are envisaged in order to devise combined FMM as rational guidance to interpret the properties and the interfacial structure of complex mixed surfactant adsorption systems.


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