scholarly journals The Influence of Temperature on the Capacity of Lithium Ion Batteries with Different Anodes

Energies ◽  
2021 ◽  
Vol 15 (1) ◽  
pp. 60
Author(s):  
Shuaishuai Lv ◽  
Xingxing Wang ◽  
Wenfan Lu ◽  
Jiaqiao Zhang ◽  
Hongjun Ni
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Lithium Iron Phosphate ◽  
Operating Temperature ◽  
Lithium Ion ◽  
Internal Resistance ◽  
Discharge Process ◽  
Optimal Operating ◽  
Important Indicator ◽  
Optimal Operating Temperature

Temperature is considered to be an important indicator that affects the capacity of a lithium ion batteries. Therefore, it is of great significance to study the relationship between the capacity and temperature of lithium ion batteries with different anodes. In this study, the single battery is used as the research object to simulate the temperature environment during the actual use of the power battery, and conduct a charge and discharge comparison test for lithium iron phosphate battery, lithium manganate battery and lithium cobalt oxide battery. In the test of capacity characteristics of lithium ion batteries of three different cathode materials at different temperatures, the optimal operating temperature range of the lithium ion battery is extracted from the discharge efficiencies obtained. According to the research results, the discharge capacity of a lithium ion battery can be approximated by a cubic polynomial of temperature. The optimal operating temperature of lithium ion battery is 20–50 °C within 1 s, as time increases, the direct current (DC) internal resistance of the battery increases and the slope becomes smaller. Between 1 s and 10 s, the DC internal resistance of the battery basically shows a linear relationship with time. In the charge and discharge process, when state of charge (SOC) 0% and SOC 100%, the internal resistance of the battery is the largest. The SOC has the greatest impact on the polarization internal resistance, and the smallest impact on the ohmic internal resistance.

Lithium-Ion Battery Packs Formation With Improved Electrochemical Performance for Electric Vehicles: Experimental and Clustering Analysis

2019 ◽  
Vol 16 (2) ◽  
Author(s):  
Liu Yun ◽  
Jayne Sandoval ◽  
Jian Zhang ◽  
Liang Gao ◽  
Akhil Garg ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Electric Vehicles ◽  
Clustering Analysis ◽  
Lithium Ion ◽  
Internal Resistance ◽  
Battery Pack ◽  
Self Organizing Map ◽  
Battery Packs

With the increase of production of electrical vehicles (EVs) and battery packs, lithium ion batteries inconsistency problem has drawn much attention. Lithium ion battery imbalance phenomenon exists during three different stages of life cycle. First stage is premanufacturing of battery pack i.e., during the design, the cells of similar performance need to be clustered to improve the performance of pack. Second is during the use of battery pack in EVs, batteries equalization is necessary. In the third stage, clustering of spent lithium ion batteries for reuse is also an important problem because of the great recycling challenge of lithium batteries. In this work, several clustering and equalization methods are compared and summarized for different stages. The methods are divided into the traditional methods and intelligent methods. The work also proposes experimental combined clustering analysis for new lithium-ion battery packs formation with improved electrochemical performance for electric vehicles. Experiments were conducted by dismantling of pack and measurement of capacity, voltage, and internal resistance data. Clustering analysis based on self-organizing map (SOM) neural networks is then applied on the measured data to form clusters of battery packs. The validation results conclude that the battery packs formed from the clustering analysis have higher electrochemical performance than randomly selected ones. In addition, a comprehensive discussion was carried out.

scholarly journals Comparison of Lithium-Ion Battery Cathode Materials and the Internal Stress Development

2011 ◽  
Author(s):  
Yixu Wang ◽  
Hsiao-Ying Shadow Huang
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Lithium Iron Phosphate ◽  
Lithium Ion ◽  
High Energy ◽  
Rechargeable Batteries ◽  
Electrochemical Process ◽  
Environmental Benefits ◽  
Analytical Models ◽  
Stress Development

The need for development and deployment of reliable and efficient energy storage devices, such as lithium-ion rechargeable batteries, is becoming increasingly important due to the scarcity of petroleum. Lithium-ion batteries operate via an electrochemical process in which lithium ions are shuttled between cathode and anode while electrons flowing through an external wire to form an electrical circuit. The study showed that the development of lithium-iron-phosphate (LiFePO4) batteries promises an alternative to conventional lithium-ion batteries, with their potential for high energy capacity and power density, improved safety, and reduced cost. However, current prototype LiFePO4 batteries have been reported to lose capacity over ∼3000 charge/discharge cycles or degrade rapidly under high discharging rate. In this study, we report that the mechanical and structural failures are attributed to dislocations formations. Analytical models and crystal visualizations provide details to further understand the stress development due to lithium movements during charging or discharging. This study contributes to the fundamental understanding of the mechanisms of capacity loss in lithium-ion battery materials and helps the design of better rechargeable batteries, and thus leads to economic and environmental benefits.

Graphenised Lithium Iron Phosphate and Lithium Manganese Silicate Hybrid Cathodes: Potentials for Application in Lithium‐ion Batteries

2020 ◽  
Vol 32 (12) ◽  
pp. 2982-2999
Author(s):  
Zolani Myalo ◽  
Chinwe Oluchi Ikpo ◽  
Assumpta Chinwe Nwanya ◽  
Miranda Mengwi Ndipingwi ◽  
Samantha Fiona Duoman ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Iron Phosphate ◽  
Lithium Ion ◽  
Iron Phosphate ◽  
Manganese Silicate ◽  
Lithium Manganese

scholarly journals A Novel Pyrometallurgical Recycling Process for Lithium-Ion Batteries and Its Application to the Recycling of LCO and LFP

Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 149
Author(s):  
Alexandra Holzer ◽  
Stefan Windisch-Kern ◽  
Christoph Ponak ◽  
Harald Raupenstrauch
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Iron Phosphate ◽  
Process Development ◽  
Removal Rate ◽  
Continuous Process ◽  
Lithium Ion ◽  
Iron Phosphate ◽  
Recycling Process ◽  
Subsequent Step ◽  
Pre Treatment

The bottleneck of recycling chains for spent lithium-ion batteries (LIBs) is the recovery of valuable metals from the black matter that remains after dismantling and deactivation in pre‑treatment processes, which has to be treated in a subsequent step with pyrometallurgical and/or hydrometallurgical methods. In the course of this paper, investigations in a heating microscope were conducted to determine the high-temperature behavior of the cathode materials lithium cobalt oxide (LCO—chem., LiCoO2) and lithium iron phosphate (LFP—chem., LiFePO4) from LIB with carbon addition. For the purpose of continuous process development of a novel pyrometallurgical recycling process and adaptation of this to the requirements of the LIB material, two different reactor designs were examined. When treating LCO in an Al2O3 crucible, lithium could be removed at a rate of 76% via the gas stream, which is directly and purely available for further processing. In contrast, a removal rate of lithium of up to 97% was achieved in an MgO crucible. In addition, the basic capability of the concept for the treatment of LFP was investigated whereby a phosphorus removal rate of 64% with a simultaneous lithium removal rate of 68% was observed.

scholarly journals Effect of dynamic loads and vibrations on lithium-ion batteries

2021 ◽  
pp. 146134842110081
Author(s):  
Xia Hua ◽  
Alan Thomas
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Experimental Studies ◽  
Lithium Ion ◽  
Battery Pack ◽  
Dynamic Loads ◽  
Electrical Performance ◽  
Mechanical Degradation ◽  
Energy Storage Devices ◽  
Battery Cell

Lithium-ion batteries are being increasingly used as the main energy storage devices in modern mobile applications, including modern spacecrafts, satellites, and electric vehicles, in which consistent and severe vibrations exist. As the lithium-ion battery market share grows, so must our understanding of the effect of mechanical vibrations and shocks on the electrical performance and mechanical properties of such batteries. Only a few recent studies investigated the effect of vibrations on the degradation and fatigue of battery cell materials as well as the effect of vibrations on the battery pack structure. This review focused on the recent progress in determining the effect of dynamic loads and vibrations on lithium-ion batteries to advance the understanding of lithium-ion battery systems. Theoretical, computational, and experimental studies conducted in both academia and industry in the past few years are reviewed herein. Although the effect of dynamic loads and random vibrations on the mechanical behavior of battery pack structures has been investigated and the correlation between vibration and the battery cell electrical performance has been determined to support the development of more robust electrical systems, it is still necessary to clarify the mechanical degradation mechanisms that affect the electrical performance and safety of battery cells.

scholarly journals Characterization of the Compressive Load on a Lithium-Ion Battery for Electric Vehicle Application

Machines ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 71
Author(s):  
Seyed Saeed Madani ◽  
Erik Schaltz ◽  
Søren Knudsen Kær
Keyword(s):  
Electrochemical Impedance Spectroscopy ◽  
Impedance Spectroscopy ◽  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
Electric Vehicles ◽  
Large Scale ◽  
Electrochemical Impedance ◽  
Applied Pressure ◽  
Lithium Ion ◽  
Battery Cells

Lithium-ion batteries are being implemented in different large-scale applications, including aerospace and electric vehicles. For these utilizations, it is essential to improve battery cells with a great life cycle because a battery substitute is costly. For their implementation in real applications, lithium-ion battery cells undergo extension during the course of discharging and charging. To avoid disconnection among battery pack ingredients and deformity during cycling, compacting force is exerted to battery packs in electric vehicles. This research used a mechanical design feature that can address these issues. This investigation exhibits a comprehensive description of the experimental setup that can be used for battery testing under pressure to consider lithium-ion batteries’ safety, which could be employed in electrified transportation. Besides, this investigation strives to demonstrate how exterior force affects a lithium-ion battery cell’s performance and behavior corresponding to static exterior force by monitoring the applied pressure at the dissimilar state of charge. Electrochemical impedance spectroscopy was used as the primary technique for this research. It was concluded that the profiles of the achieved spectrums from the experiments seem entirely dissimilar in comparison with the cases without external pressure. By employing electrochemical impedance spectroscopy, it was noticed that the pure ohmic resistance, which is related to ion transport resistance of the separator, could substantially result in the corresponding resistance increase.

scholarly journals Lithium ion battery recycling using high-intensity ultrasonication

2021 ◽  
Author(s):  
chunhong lei ◽  
Iain M Aldous ◽  
Jennifer Hartley ◽  
Dana Thompson ◽  
Sean Scott ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion Battery ◽  
High Intensity ◽  
Lithium Ion ◽  
Battery Recycling

Decarbonisation of energy will rely heavily, at least initially, on the use of lithium ion batteries for automotive transportation. The projected volumes of batteries necessitate the development of fast and...

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