scholarly journals The Feasibility of Two Handheld Spectrometers for Meat Speciation Combined with Chemometric Methods and Its Application for Halal Certification

Foods ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 71
Author(s):  
Abolfazl Dashti ◽  
Judith Müller-Maatsch ◽  
Yannick Weesepoel ◽  
Hadi Parastar ◽  
Farzad Kobarfard ◽  
...  

Handheld visible-near-infrared (Vis-NIR) and near-infrared (NIR) spectroscopy can be cost-effective, rapid, non-destructive and transportable techniques for identifying meat species and may be valuable for enforcement authorities, retail and consumers. In this study, a handheld Vis-NIR (400–1000 nm) and a handheld NIR (900–1700 nm) spectrometer were applied to discriminate halal meat species from pork (halal certification), as well as speciation of intact and ground lamb, beef, chicken and pork (160 meat samples). Several types of class modeling multivariate approaches were applied. The presented one-class classification (OCC) approach, especially with the Vis-NIR sensor (95–100% correct classification rate), was found to be suitable for the application of halal from non-halal meat-species discrimination. In a discriminant approach, using the Vis-NIR data and support vector machine (SVM) classification, the four meat species tested could be classified with accuracies of 93.4% and 94.7% for ground and intact meat, respectively, while with partial least-squares discriminant analysis (PLS-DA), classification accuracies were 87.4% (ground) and 88.6% (intact). Using the NIR sensor, total accuracies of the SVM models were 88.2% and 81.5% for ground and intact meats, respectively, and PLS-DA classification accuracies were 88.3% (ground) and 80% (intact). We conclude that the Vis-NIR sensor was most successful in the halal certification (OCC approaches) and speciation (discriminant approaches) for both intact and ground meat using SVM.

Author(s):  
Nawaf Abu-Khalaf ◽  
Mazen Salman

Early detection of plant disease requires usually elaborating methods techniques and especially when symptoms are not visible. Olive Leaf Spot (OLS) infecting upper surface of olive leaves has a long latent infection period. In this work, VIS/NIR spectroscopy was used to determine the latent infection and severity of the pathogens. Two different classification methods were used, Partial Least Squared-Discrimination Analysis (PLS-DA) (linear method) and Support Vector Machine (SVM) (non-linear). SVM-classification was able to classify severity levels 0, 1, 2, 3, 4, and 5 with classification rates of 94, 90, 73, 79, 83 and 100%, respectively The overall classification rate was about 86%. PLS-DA was able to classify two different severity groups (first group with severity 0, 1, 2, 3, and second group with severity 4, 5), with a classification rate greater than 95%. The results promote further researches, and the possibility of evaluation OLS in-situ using portable VIS/NIR devices.


Author(s):  
Nawaf Abu-Khalaf ◽  
Mazen Salman

Early detection of plant disease requires usually elaborating methods techniques and especially when symptoms are not visible. Olive Leaf Spot (OLS) infecting upper surface of olive leaves has a long latent infection period. In this work, VIS/NIR spectroscopy was used to determine the latent infection and severity of the pathogens. Two different classification methods were used, Partial Least Squared-Discrimination Analysis (PLS-DA) (linear method) and Support Vector Machine (SVM) (non-linear). SVM-classification was able to classify severity levels 0, 1, 2, 3, 4, and 5 with classification rates of 94, 90, 73, 79, 83 and 100%, respectively The overall classification rate was about 86%. PLS-DA was able to classify two different severity groups (first group with severity 0, 1, 2, 3, and second group with severity 4, 5), with a classification rate greater than 95%. The results promote further researches, and the possibility of evaluation OLS in-situ using portable VIS/NIR devices.


2018 ◽  
Vol 2018 ◽  
pp. 1-12 ◽  
Author(s):  
Sylvio Barbon ◽  
Ana Paula Ayub da Costa Barbon ◽  
Rafael Gomes Mantovani ◽  
Douglas Fernandes Barbin

Identification of chicken quality parameters is often inconsistent, time-consuming, and laborious. Near-infrared (NIR) spectroscopy has been used as a powerful tool for food quality assessment. However, the near-infrared (NIR) spectra comprise a large number of redundant information. Determining wavelengths relevance and selecting subsets for classification and prediction models are mandatory for the development of multispectral systems. A combination of both attribute and wavelength selection for NIR spectral information of chicken meat samples was investigated. Decision Trees and Decision Table predictors exploit these optimal wavelengths for classification tasks according to different quality grades of poultry meat. The proposed methodology was conducted with a support vector machine algorithm (SVM) to compare the precision of the proposed model. Experiments were performed on NIR spectral information (1050 wavelengths), colour (CIEL∗a∗b∗, chroma, and hue), water holding capacity (WHC), and pH of each sample analyzed. Results show that the best method was the REPTree based on 12 wavelengths, allowing for classification of poultry samples according to quality grades with 77.2% precision. The selected wavelengths could lead to potential simple multispectral acquisition devices.


2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Hui Chen ◽  
Zan Lin ◽  
Chao Tan

Near-infrared (NIR) spectroscopy technique offers many potential advantages as tool for biomedical analysis since it enables the subtle biochemical signatures related to pathology to be detected and extracted. In conjunction with advanced chemometrics, NIR spectroscopy opens the possibility of their use in cancer diagnosis. The study focuses on the application of near-infrared (NIR) spectroscopy and classification models for discriminating colorectal cancer. A total of 107 surgical specimens and a corresponding NIR diffuse reflection spectral dataset were prepared. Three preprocessing methods were attempted and least-squares support vector machine (LS-SVM) was used to build a classification model. The hybrid preprocessing of first derivative and principal component analysis (PCA) resulted in the best LS-SVM model with the sensitivity and specificity of 0.96 and 0.96 for the training and 0.94 and 0.96 for test sets, respectively. The similarity performance on both subsets indicated that overfitting did not occur, assuring the robustness and reliability of the developed LS-SVM model. The area of receiver operating characteristic (ROC) curve was 0.99, demonstrating once again the high prediction power of the model. The result confirms the applicability of the combination of NIR spectroscopy, LS-SVM, PCA, and first derivative preprocessing for cancer diagnosis.


1991 ◽  
Vol 31 (2) ◽  
pp. 205 ◽  
Author(s):  
KF Smith ◽  
PC Flinn

Near infrared reflectance (NIR) spectroscopy is a rapid and cost-effective method for the measurement of organic constituents of agricultural products. NIR is widely used to measure feed quality around the world and is gaining acceptance in Australia. This study describes the development of an NIR calibration to measure crude protein (CP), predicted in vivo dry matter digestibility (IVDMD) and neutral detergent fibre (NDF) in temperate pasture species grown in south-western Victoria. A subset of 116 samples was selected on the basis of spectral characteristics from 461 pasture samples grown in 1987-89. Several grass and legume species were present in the population. Stepwise multiple linear regression analysis was used on the 116 samples to develop calibration equations with standard errors of 0.8,2.3 and 2.2% for CP, NDF and IVDMD, respectively. When these equations were tested on 2 independent pasture populations, a significant bias existed between NIR and reference values for 2 constituents in each population, indicating that the calibration samples did not adequately represent the new populations for these constituents. The results also showed that the H statistic alone was inadequate as an indicator of equation performance. It was confirmed that it was possible to develop a broad-based calibration to measure accurately the nutritive value of closed populations of temperate pasture species. For the resulting equations to be used for analysis of other populations, however, they must be monitored by comparing reference and NIR analyses on a small number of samples to check for the presence of bias or a significant increase in unexplained error.


2009 ◽  
Vol 2009 ◽  
pp. 135-135
Author(s):  
N Prieto ◽  
D W Ross ◽  
E A Navajas ◽  
G Nute ◽  
R I Richardson ◽  
...  

Visible and near infrared reflectance spectroscopy (Vis-NIR) has been widely used by the industry research-base for large-scale meat quality evaluation to predict the chemical composition of meat quickly and accurately. Meat tenderness is measured by means of slow and destructive methods (e.g. Warner-Bratzler shear force). Similarly, sensory analysis, using trained panellists, requires large meat samples and is a complex, expensive and time-consuming technique. Nevertheless, these characteristics are important criteria that affect consumers’ evaluation of beef quality. Vis-NIR technique provides information about the molecular bonds (chemical constituents) and tissue ultra-structure in a scanned sample and thus can indirectly predict physical or sensory parameters of meat samples. Applications of Vis-NIR spectroscopy in an abattoir for prediction of physical and sensory characteristics have been less developed than in other fields. Therefore, the aim of this study was to test the on-line Vis-NIR spectroscopy for the prediction of beef quality characteristics such as colour, instrumental texture, water holding capacity (WHC) and sensory traits, by direct application of a fibre-optic probe to the M. longissimus thoracis with no prior sample treatment.


2020 ◽  
Vol 28 (4) ◽  
pp. 224-235
Author(s):  
Irina M Benson ◽  
Beverly K Barnett ◽  
Thomas E Helser

Applications of Fourier transform near infrared (FT-NIR) spectroscopy in fisheries science are currently limited. This current analysis of otolith spectral data demonstrate the potential applicability of FT-NIR spectroscopy to otolith chemistry and spatial variability in fisheries science. The objective of this study was to examine the use of NIR spectroscopy as a tool to differentiate among marine fishes in four large marine ecosystems. We examined otoliths from 13 different species, with three of these species coming from different regions. Principal component analysis described the main directions along which the specimens were separated. The separation of species and their ecosystems may suggest interactions between fish phylogeny, ontogeny, and environmental conditions that can be evaluated using NIR spectroscopy. In order to discriminate spectra across ecosystems and species, four supervised classification model techniques were utilized: soft independent modelling of class analogies, support vector machine discriminant analysis, partial least squares discriminant analysis, and k-nearest neighbor analysis (KNN). This study showed that the best performing model to classify combined ecosystems, all four ecosystems, and species was the KNN model, which had an overall accuracy rate of 99.9%, 97.6%, and 91.5%, respectively. Results from this study suggest that further investigations are needed to determine applications of NIR spectroscopy to otolith chemistry and spatial variability.


2004 ◽  
Vol 34 (1) ◽  
pp. 76-84 ◽  
Author(s):  
Mulualem Tigabu ◽  
Per Christer Odén ◽  
Tong Yun Shen

The use of near-infrared (NIR) spectroscopy to discriminate between uninfested seeds of Picea abies (L.) Karst and seeds infested with Plemeliella abietina Seitn (Hymenoptera, Torymidae) larva is sensitive to seed origin and year of collection. Five seed lots collected during different years from Sweden, Finland, and Belarus were used in this study. Initially, seeds were classified as infested or uninfested with X-radiography, and then, NIR spectra from single seeds were collected with a NIR spectrometer from 1100 to 2498 nm with a resolution of 2 nm. Discriminant models were derived by partial least squares regression using raw and orthogonal signal corrected spectra (OSC). The resulting OSC model developed on a pooled data set was more robust than the raw model and resulted in 100% classification accuracy. Once irrelevant spectral variations were removed by using OSC pretreatment, single-lot calibration models resulted in similar classification rates for the new samples irrespective of origin and year of collection. Dis criminant analyses performed with selected NIR absorption bands also gave nearly 100% classification rate for new samples. The origin of spectral differences between infested and uninfested seeds was attributed to storage lipids and proteins that were completely depleted in the former by the feeding larva.


2019 ◽  
Vol 2019 ◽  
pp. 1-6
Author(s):  
Lu Xu ◽  
Qiong Shi ◽  
Bang-Cheng Tang ◽  
Shunping Xie

A rapid indicator of mercury in soil using a plant (Artemisia lavandulaefolia DC., ALDC) commonly distributed in mercury mining area was established by fusion of Fourier-transform near-infrared (FT-NIR) spectroscopy coupled with least squares support vector machine (LS-SVM). The representative samples of ALDC (stem and leaf) were gathered from the surrounding and distant areas of the mercury mines. As a reference method, the total mercury contents in soil and ALDC samples were determined by a direct mercury analyzer incorporating high-temperature decomposition, catalytic adsorption for impurity removal, amalgamation capture, and atomic absorption spectrometry (AAS). Based on the FT-NIR data of ALDC samples, LS-SVM models were established to distinguish mercury-contaminated and ordinary soil. The results of reference analysis showed that the mercury level of the areas surrounding mercury mines (0–3 kilometers, 7.52–88.59 mg/kg) was significantly higher than that of the areas distant from mercury mines (>5 kilometers, 0–0.75 mg/kg). The LS-SVM classification model of ALDC samples was established based on the original spectra, smoothed spectra, second-derivative (D2) spectra, and standard normal transformation (SNV) spectra, respectively. The prediction accuracy of D2-LS-SVM was the highest (0.950). FT-NIR combined with LS-SVM modeling can quickly and accurately identify the contaminated ALDC. Compared with traditional methods which rely on naked eye observation of plants, this method is objective and more sensitive and applicable.


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