scholarly journals Gaseous Elemental Mercury and Total and Leached Mercury in Building Materials from the Former Hg-Mining Area of Abbadia San Salvatore (Central Italy)

2017 ◽  
Vol 14 (4) ◽  
pp. 425 ◽  
Author(s):  
Orlando Vaselli ◽  
Barbara Nisi ◽  
Daniele Rappuoli ◽  
Jacopo Cabassi ◽  
Franco Tassi
Keyword(s):  
Building Materials ◽  
Central Italy ◽  
Elemental Mercury ◽  
Mining Area ◽  
Gaseous Elemental Mercury ◽  
Hg Mining

scholarly journals Gaseous Elemental Mercury and Total and Leached Mercury in Building Materials from the Former Hg-Mining Area of Abbadia San Salvatore (Central Italy)

2017 ◽  
Author(s):  
Orlando Vaselli ◽  
Barbara Nisi ◽  
Daniele Rappuoli ◽  
Jacopo Cabassi ◽  
Franco Tassi
Keyword(s):  
Building Materials ◽  
Central Italy ◽  
Elemental Mercury ◽  
Mining Area ◽  
Wood Structures ◽  
Gaseous Elemental Mercury ◽  
Global Concern ◽  
Mining Complex ◽  
Anthropogenic Processes ◽  
Hg Mining

Mercury has a strong environmental impact since both its organic and inorganic forms are toxic and it represents a pollutant of global concern. Liquid Hg is highly volatile and it can be released during natural and anthropogenic processes in the hydrosphere, biosphere and atmosphere. In this study the distribution of Gaseous Elemental Mercury (GEM) and the total and leached mercury concentrations on paints, plasters, roof tiles, concretes, metals, dust and wood structures were determined in the main buildings and structures of the former Hg-mining area of Abbadia San Salvatore (Siena, Central Italy). The mining complex (divided into 7 units) covers a surface of about 65 ha and contains mining structures and managers and workers buildings. In this work, nine surveys of GEM measurements were carried out from July 2011 to August 2015 for the buildings and structures located in the units 2, 3 and 6. Moreover, detailed measurements were performed in February, April, July, September and December 2016 in the edifices and mining structures of Unit 6. GEM concentrations showed a strong variability in terms of space and time mostly depending on the distance from the building hosting driers, furnaces and condensers and ambient temperature, respectively. In the Unit 2 surveys carried out in the hotter period (from June to September) showed GEM concentrations up to 27,500 ng m−3, while in the Unit 6 they were on average much higher and occasionally they saturated the GEM measurement device (>50,000 ng m−3). Concentrations of total (in mg kg−1) and leached (in μg L−1) mercury measured in different building materials (up to 46,580 mg kg−1 and 4,470 mg L−1 for total and leached mercury, respectively) showed for the same type of material highly variable values in dependence on the edifice or mining structure from which they were collected. The results obtained in this study are of relevant interest for the operational cleanings to be carried out during the reclamation activities.

scholarly journals A New Low-Cost and Reliable Method to Evaluate the Release of Hg0 from Synthetic Materials

Processes ◽  
2020 ◽  
Vol 8 (10) ◽  
pp. 1282
Author(s):  
Marta Lazzaroni ◽  
Barbara Nisi ◽  
Daniele Rappuoli ◽  
Jacopo Cabassi ◽  
Orlando Vaselli
Keyword(s):  
Low Cost ◽  
Central Italy ◽  
Elemental Mercury ◽  
Blocking Agent ◽  
Construction And Demolition Waste ◽  
Concrete Wall ◽  
Demolition Waste ◽  
Mining Site ◽  
Gaseous Elemental Mercury ◽  
Synthetic Materials

Mercury is a toxic and noxious element and is the only metal that naturally occurs as gas. One of the most challenging topics (included in the United Nations Minimata convention) is to understand the adsorption–release processes of manmade materials (e.g., concrete, bricks, tiles, painting). Adsorption of Hg by construction and demolition waste materials has recently been studied, but investigations on how much Hg0 can be released from these products are rather poor. The abandoned mining site of Abbadia San Salvatore (Siena, central Italy) where, for about one century, cinnabar was roasted to produce liquid mercury, is known for the high concentrations of (i) Hg0 in edifices and structures and (ii) total and leachate Hg in synthetic materials. In the present paper, a new, simple and low-cost method to measure the amount of GEM (Gaseous Elemental Mercury) released from anthropic materials (concrete, wall rocks, and tiles) located in the Hg0-rich environments of the former mining site, is proposed. The efficiency of a specific paint that was supposed to act as blocking agent to Hg0 was also tested.

scholarly journals Discontinuous Geochemical Monitoring of the Galleria Italia Circumneutral Waters (Former Hg-Mining Area of Abbadia San Salvatore, Tuscany, Central Italy) Feeding the Fosso Della Chiusa Creek

Environments ◽  
2021 ◽  
Vol 8 (2) ◽  
pp. 15
Author(s):  
Orlando Vaselli ◽  
Marta Lazzaroni ◽  
Barbara Nisi ◽  
Jacopo Cabassi ◽  
Franco Tassi ◽  
...  
Keyword(s):  
Trace Elements ◽  
Central Italy ◽  
Mining Area ◽  
Geochemical Monitoring ◽  
Mean Flow ◽  
Congruent Dissolution ◽  
Tiber Basin ◽  
Tunnel System ◽  
Dissolved Mercury ◽  
Hg Mining

The Galleria Italia waters drain the complex tunnel system of the former Hg-mining area of Abbadia San Salvatore (Tuscany, central Italia) and feed the 2.5 km-long Fosso della Chiusa creek. The mining exploitation was active for more than one century and more than 100,000 tons of liquid mercury were produced by roasting processes of cinnabar (HgS). In this work, a discontinuous geochemical monitoring of the Galleria Italia circumneutral waters was carried out from February 2009 to October 2020, during which the main physicochemical parameters, main and minor dissolved species and trace elements (including Hg) were determined. In the observation period, significant variations in the water chemistry were recorded, particularly when flooding waves, due to intense precipitations, occurred, with the two main events being recorded in February 2009 and January 2010. The chemical composition of the Galleria Italia waters was Ca(Mg)-SO4 and related to congruent dissolution of gypsum/anhydrite at which a contribution from carbonatic and silicatic minerals and partial solubilization of CO2 and and H2S oxidation is to be added. Regarding the trace elements, Al, Mn and Fe were up to 1500, 768 and 39520 μg L−1, with these elements also showing high contents in the sediment precipitating by the Galleria Italia waters. In most cases, dissolved mercury was below the instrumental detection limit (<0.1 μg L−1), although occasionally it reached >1 μg L−1. Considering a mean flow rate of 40 L s−1 of the discharged water, the amount of dissolved mercury released from Galleria Italia was computed, although most mercury was occurring in the sediment (1.2 mg kg−1). A more realistic computation of mercury released from Galleria Italia should involve a sampling network along the Fosso della Chiusa before entering the riverine system of the Tiber basin, into which dissolved and suspended mercury are to be determined along with that occurring in the sediments.

scholarly journals Air Concentrations of Gaseous Elemental Mercury and Vegetation–Air Fluxes within Saltmarshes of the Tagus Estuary, Portugal

Atmosphere ◽  
2021 ◽  
Vol 12 (2) ◽  
pp. 228
Author(s):  
Rute Cesário ◽  
Nelson J. O’Driscoll ◽  
Sara Justino ◽  
Claire E. Wilson ◽  
Carlos E. Monteiro ◽  
...  
Keyword(s):  
Leaf Area ◽  
Elemental Mercury ◽  
Ambient Air ◽  
Tagus Estuary ◽  
Contaminated Site ◽  
Gaseous Elemental Mercury ◽  
Mercury Flux ◽  
Sarcocornia Fruticosa ◽  
Air Concentrations

In situ air concentrations of gaseous elemental mercury (Hg(0)) and vegetation–atmosphere fluxes were quantified in both high (Cala Norte, CN) and low-to-moderate (Alcochete, ALC) Hg-contaminated saltmarsh areas of the Tagus estuary colonized by plant species Halimione portulacoides (Hp) and Sarcocornia fruticosa (Sf). Atmospheric Hg(0) ranged between 1.08–18.15 ng m−3 in CN and 1.18–3.53 ng m−3 in ALC. In CN, most of the high Hg(0) levels occurred during nighttime, while the opposite was observed at ALC, suggesting that photoreduction was not driving the air Hg(0) concentrations at the contaminated site. Vegetation–air Hg(0) fluxes were low in ALC and ranged from −0.76 to 1.52 ng m−2 (leaf area) h−1 for Hp and from −0.40 to 1.28 ng m−2 (leaf area) h−1 for Sf. In CN, higher Hg fluxes were observed for both plants, ranging from −9.90 to 15.45 ng m−2 (leaf area) h−1 for Hp and from −8.93 to 12.58 ng m−2 (leaf area) h−1 for Sf. Mercury flux results at CN were considered less reliable due to large and fast variations in the ambient air concentrations of Hg(0), which may have been influenced by emissions from the nearby chlor-alkali plant, or historical contamination. Improved experimental setup, the influence of high local Hg concentrations and the seasonal activity of the plants must be considered when assessing vegetation–air Hg(0) fluxes in Hg-contaminated areas.

scholarly journals An Integrated Investigation of Atmospheric Gaseous Elemental Mercury Transport and Dispersion Around a Chlor-Alkali Plant in the Ossola Valley (Italian Central Alps)

Toxics ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 172
Author(s):  
Laura Fantozzi ◽  
Nicoletta Guerrieri ◽  
Giovanni Manca ◽  
Arianna Orrù ◽  
Laura Marziali
Keyword(s):  
Elemental Mercury ◽  
Background Concentration ◽  
Dispersion Pattern ◽  
Central Alps ◽  
Gaseous Elemental Mercury ◽  
Mercury Transport ◽  
Close Proximity ◽  
Potential Impact ◽  
Hg Accumulation

We present the first assessment of atmospheric pollution by mercury (Hg) in an industrialized area located in the Ossola Valley (Italian Central Alps), in close proximity to the Toce River. The study area suffers from a level of Hg contamination due to a Hg cell chlor-alkali plant operating from 1915 to the end of 2017. We measured gaseous elemental Hg (GEM) levels by means of a portable Hg analyzer during car surveys between autumn 2018 and summer 2020. Moreover, we assessed the long-term dispersion pattern of atmospheric Hg by analyzing the total Hg concentration in samples of lichens collected in the Ossola Valley. High values of GEM concentrations (1112 ng m−3) up to three orders of magnitude higher than the typical terrestrial background concentration in the northern hemisphere were measured in the proximity of the chlor-alkali plant. Hg concentrations in lichens ranged from 142 ng g−1 at sampling sites located north of the chlor-alkali plant to 624 ng g−1 in lichens collected south of the chlor-alkali plant. A north-south gradient of Hg accumulation in lichens along the Ossola Valley channel was observed, highlighting that the area located south of the chlor-alkali plant is more exposed to the dispersion of Hg emitted into the atmosphere from the industrial site. Long-term studies on Hg emission and dispersion in the Ossola Valley are needed to better assess potential impact on ecosystems and human health.

scholarly journals On the Thermal Stresses Due to Weathering in Natural Stones

2021 ◽  
Vol 11 (3) ◽  
pp. 1188
Author(s):  
William Hideki Ito ◽  
Talita Scussiato ◽  
Federico Vagnon ◽  
Anna Maria Ferrero ◽  
Maria Rita Migliazza ◽  
...  
Keyword(s):  
Building Materials ◽  
Thermal Stresses ◽  
Central Italy ◽  
Theory Of Elasticity ◽  
International Standards ◽  
Natural Material ◽  
Physical Weathering ◽  
Mechanism Of Degradation ◽  
Ancient Times ◽  
Natural Stones

Natural weathering is known as one of the key mechanisms causing degradation in building materials. Great efforts have been made to develop new materials and new processes for protecting those that already exist. Natural stones are an example of a natural material that has been extensively used for building construction since ancient times. In addition, they fit durability, aesthetic, and mechanical requirements. Thus, they still have great importance in the construction business nowadays. Though chemical interactions in natural stones, such as oxidation or hydrolyses, have been widely studied, in the last few decades, the physical weathering due to daily temperature variations has begun to be considered as a key mechanism of degradation and has been incorporated in international standards. This process is particularly important in calcitic marble slabs, where it can cause extensive damages to facades. Consequently, there are restrictive rules for the use of marble as an external coating material in many countries. In this paper, the thermal stresses induced by daily variations in temperature are calculated using geographic and meteorological information. The concept of sol-air temperature is used to estimate the temperatures of the hidden and exposed surfaces of a slab, and Fourier’s law and the theory of elasticity are used to calculate the temperature and stress distribution, respectively. The proposed methodology allows for a detailed reconstruction of the stress induced inside marble slabs using parameters commonly acquired in meteorological stations as input data. The developed methodology was validated by comparing in-situ measurements of the temperature of a building in Pescara (Central Italy). A good correlation between the theoretical and real temperatures was found; in particular, the peak tensile stresses inside the slabs were estimated at 75 kPa.

scholarly journals Technosols Development in an Abandoned Mining Area and Environmental Risk Assessment

2021 ◽  
Vol 11 (15) ◽  
pp. 6982
Author(s):  
Chiara Ferronato ◽  
Gilmo Vianello ◽  
Mauro De Feudis ◽  
Livia Vittori Antisari
Keyword(s):  
Central Italy ◽  
Organic Matter Content ◽  
Chemical Properties ◽  
Soil Surface ◽  
Mining Area ◽  
Physicochemical Characteristics ◽  
Matter Content ◽  
Mine Tailing ◽  
Inorganic Materials ◽  
Soil Features

The study of Technosols development, spatial distribution and physicochemical characteristics is becoming more and more important in the Anthropocene Era. The aim of the present study was to assess soil features and potential heavy metal release risk of soils developed on different mine tailing types after the waste disposal derived from mining activity in Central Italy. Soils were analyzed for their morphological, physical and chemical properties, and a chemical sequential extraction of heavy metals was performed. The investigated soils were classified as Technosols toxic having in some layer within 50 cm of the soil surface inorganic materials with high concentrations of toxic elements. Our findings showed that the bioavailability of potentially toxic element concentrations in the soil changed according to the origin of the mine tailing. However, because of the acidic pH, there is a serious risk of metals leaching which was reduced where the soil organic matter content was higher.

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