scholarly journals Pollution Level and Health Risk Assessment of PM2.5-Bound Metals in Baoding City Before and After the Heating Period

Author(s):  
Yixuan Liu ◽  
Shanshan Li ◽  
Chunyuan Sun ◽  
Mengxi Qi ◽  
Xue Yu ◽  
...  

In order to assess the pollution levels and health risks of PM2.5-bound metals in Baoding City before and after the heating period, samples were collected in 2016 at Hebei University from September 25th to November 14th during the non-heating period, and November 15th to December 26th during the heating period, respectively. ICP-MS was applied to analyze seven heavy metals (Cr, Zn, Cu, Pb, Ni, Cd and Fe). The statistical analysis, enrichment factor (EF), pollution load index method, and Risk Assessment Method proposed by U.S. EPA were used to evaluate the non-carcinogenic risks of six of these heavy metals (Cr, Zn, Cu, Pb, Ni and Cd) and carcinogenic risks of three of these heavy metals (Cr, Ni and Cd). The results showed three main results. First, the average daily PM2.5 concentrations of the national air monitoring stations was 155.66 μg·m−3 which was 2.08 times as high as that of the second level criterion in China (75 μg·m−3) during the observation period. Compared with the non-heating period, all heavy metals concentrations increased during heating period. The growth rates of Pb and Ni were the highest and the lowest, which were 88.03 and 5.11 percent, respectively. Second, the results of enrichment factor indicated that the EF values of all heavy metals were higher during the heating period in comparison with during the non-heating period, but the degree of enrichment of all heavy metals remained unchanged. Not only those, Cr and Ni were minimally enriched and were affected by both human and natural factors, Pb, Cu and Zn were significantly enriched and were mainly affected by human factors, the enrichment of Cd was much higher than that of the other heavy metals, exhibiting extremely high enrichment, mainly due to human factors during the whole sampling period. The results of the pollution load index indicated that the proportions of the number of highly and very highly polluted PM2.5-bound metals were the highest during the heating period, while the proportion of moderately polluted PM2.5-bound metals was the highest during the non-heating period. The combined pollution degree of heavy metals was more serious during the heating period. Third, according to the health risk assessment model, we concluded that the non-carcinogenic and carcinogenic risks caused by inhalation exposure were the highest and by dermal exposure were the lowest for all kinds of people. The overall non-carcinogenic risk of heavy metals via inhalation and subsequent ingestion exposure caused significant harm to children during the non-heating and the heating periods, and the risk values were 2.64, 4.47, 1.20 and 1.47, respectively. Pb and Cr exhibited the biggest contributions to the non-carcinogenic risk. All the above non-carcinogenic risks exceeded the standard limits suggested by EPA (HI or HQ < 1). The carcinogenic risk via inhalation exposure to children, adult men and women were 2.10 × 10−4, 1.80 × 10−4, and 1.03 × 10−4 during the non-heating period, respectively, and 2.52 × 10−4, 2.16 × 10−4 and 1.23 × 10−4 during the heating period, respectively. All the above carcinogenic risks exceeded the threshold ranges (10−6~10−4), and Cr posed a carcinogenic risk to all people.

2021 ◽  
Author(s):  
Shirin Akter ◽  
Mohammad Obidur Rahman ◽  
Mehedi Hasan ◽  
Saiful Islam Tushar ◽  
Mottalib Hossain Sarkar ◽  
...  

Abstract The mean concentrations of heavy metals viz: K, Ca, Mg, Ti, Fe, Co, Cu, As, Zn, Rb, Sr, Zr, Pb and Th were measured in soil samples using Energy Dispersive X-ray Fluorescence (EDXRF) technique and sampling sites as a whole were found highly contaminated by Zn, considerably contaminated by Mg and Pb, while moderately contaminated by Fe, Co, Cu, Rb, Sr, As, Rb, Y, Th. The sampling sites are moderate to strongly polluted by heavy metals according to Enrichment factors value, whereas, Pollution Load Index values for 95% of the sample sites were ≥ 1.5, indicating deterioration of soil quality. Potential Ecological risk (RI) value followed the increasing sequence of Pb > As > Co > Zn > Cu. Non-carcinogenic exposure found higher in children compared to adults,however carcinogenic risk assessment revealed that both groups (adult and children) lied within Grade II category (10− 5 to 10− 6) and considered to be at no risk.


2019 ◽  
Vol 1 (2) ◽  
pp. 16-18
Author(s):  
IBRAHIM SANI SHABANDA

Rapid industrialization and modernization of urban cities has resulted to serious environmental contamination by metals, as a result the exposed inhabitants experienced health consequences. Therefore health risk assessment through multiple pathways is required for the health safety of the population. However, few studies to date estimate the health risk of heavy metals via different pathways on urban soils.  Samples of urban soils  were collected from urban environments of Petaling Jaya, and were analysed for As, Cd, Cr, Cu and Pb. The health risks for adults as a result of ingestion, dermal and inhalation exposure were then estimated.  The results showed that the urban soils  were polluted with these metals. This could be due to anthropoenic input. The concentration of the metals in soils follows the decreasing order Pb > As > Cr > Cu and Cd. Ingestion is the main route for exposure to heavy metals. Both the carcinogenic and non-carcinogenic risk values are within the permissible limits. Adults could be vulnerable to non-carcinogenic health risk (HI) on exposure to As in urban soil.  Keyword: health risk, heavy metals, soils, dusts


PeerJ ◽  
2021 ◽  
Vol 9 ◽  
pp. e11853
Author(s):  
Xingyong Zhang ◽  
Qixin Wu ◽  
Shilin Gao ◽  
Zhuhong Wang ◽  
Shouyang He

Heavy metals are released into the water system through various natural processes and anthropogenic activities, thus indirectly or directly endangering human health. The distribution, source, water quality and health risk assessment of dissolved heavy metals (V, Mn, Fe, Co, Ni, Zn, As, Mo, Sb) in major rivers in Wuhan were analyzed by correlation analysis (CA), principal component analysis (PCA), heavy metal pollution index (HPI), hazard index (HI) and carcinogenic risk (CR). The results showed that the spatial variability of heavy metal contents was pronounced. PCA and CA results indicated that natural sources controlled Mn, Fe, Co, Ni and Mo, and industrial emissions were the dominant factor for V, Zn and Sb, while As was mainly from the mixed input of urban and agricultural activities. According to the heavy metal pollution index (HPI, ranging from 23.74 to 184.0) analysis, it should be noted that As and Sb contribute most of the HPI values. The health risk assessment using HI and CR showed that V and Sb might have a potential non-carcinogenic risk and As might have a potential carcinogenic risk to adults and children in the study area (CR value exceeded target risk 10−4). At the same time, it was worth noting that As might have a potential non-carcinogenic risk for children around QLR (HI value exceeded the threshold value 1). The secular variation of As and Sb should be monitor in high-risk areas. The results of this study can provide important data for improving water resources management efficiency and heavy metal pollution prevention in Wuhan.


2020 ◽  
Vol 71 (11) ◽  
pp. 30-38
Author(s):  
Kafeel Ahmad ◽  
Nimra Arshad ◽  
Zafar Iqbal Khan ◽  
Humayun Bashir ◽  
Sonaina Nazar ◽  
...  

The increasing pollution in most industrialized area is a really attention seeking issue now a days. Air pollution caused by vehicular smoke contains handsome percentages of heavy metals like cadmium. Cadmium like other heavy metals accumulated in the bodies of living systems found around roads. Among the living system cadmium accumulate up to alarming rate like in soil, plants and animals. Therefore, this study was conducted in order to evaluate the possible risk of the Cadmium on the soil, forage and buffalos. The study was done in the area of Sargodha district, Punjab, Pakistan. There were six sites selected for study on accumulation of Cd in the forages, soil and the Buffalo blood. The Cd content in soil samples was highest in sample collected from site III. The Cd content was highest in the forage sample collected from site IV and in the blood samples, and the bioaccumulation factor was highest in the samples collected from site V. The positive and non-significant correlation was found when soil and forage was correlated, unlike the correlation found between blood and forage which was found negative non-significant. The samples from site III showed high daily intake of metals, health risk index, and pollution load index. This study will bring attention towards the development of the strategies in order to be safe from the toxic effects of cadmium.


2021 ◽  
Author(s):  
Zhengwu Cui ◽  
Yang Wang ◽  
Rui Yu ◽  
Yong Yu ◽  
Nana Luo

Abstract 124 road dust samples were collected from an urban area of Shenyang, a typical heavily industrial city in Northeast China, to study the concentration, pollution level, source, spatial distribution, and health risk of heavy metals. The average concentrations of Cd, Cr, Cu, Mn, Ni, Pb, and Zn were 1.802, 132.1, 60.33, 778.3, 54.80, 86.73, and 391.2 mg/kg, respectively. The levels of metal pollution ranged from minimal to extremely high, with average levels in the ranked order: Mn < Ni < Cr < Cu < Pb < Zn < Cd, indicating that the road dust was heavily polluted by Cd, Zn, and Pb. Source identification results demonstrated that Cr, Mn, and Ni had mixed sources including industrial emissions and weathering of soil, pavements, and building materials, while Cu, Pb, and Zn mainly originated from traffic and industrial activities, and Cd had a complex mixture of sources (with various anthropogenic sources). Hotspots of heavy metal pollution levels were closely correlated with local anthropogenic activities, such as industrial discharge, traffic-related exhaust emissions, and agricultural activities. Furthermore, health risk assessment revealed significant non-carcinogenic risks for children from multiple metals, and the carcinogenic risk assessment identified significant risks for children from Cd, with ingestion being the main exposure pathway for carcinogenic and non-carcinogenic risk for adults and children. However, no health risk was observed due to dermal and inhalation exposure pathways.


Author(s):  
Mahdi Sadeghi ◽  
Mina Noroozi

Introduction: Contamination of water with heavy metals has turned into a health concern, particularly in the developing countries. In this study, concentration of heavy metals and associated carcinogenic and non- carcinogenic risk was investigated in water samples collected from Gonbad-e Kavus, a high-risk area for cancer. Materials and Methods: Samples were collected from Gorgan River, Golestan reservoir and wells around villages with high prevalence in 2018. Samples were analysed through inductively coupled plasma mass spectrometry. After determining the concentration of heavy metals in water samples from different sources, health risk assessment was carried out according to the Environmental Protection Agency.  Results: Arsenic in samples 6-9 was higher than 10 µg/L, calcium and magnesium in sample 5 was higher than 200 mg/L and 150 mg/L respectively, and sodium in all samples was higher than 50 mg/L.  According to the findings, these concentrations were higher than the maximum allowed limit in most water samples. Hazard quotient (HQ) in samples 8 and 9 were associated with arsenic and health risk in sample 1 was related to antimony. Furthermore, since all samples contained high amounts of lithium, water from this area better should not be consumed by children older than one year. Conclusion: Given the high rate of arsenic contamination, consumption of water in the study area could be health threatening for all individuals and is not recommended for children. This highlights the need for taking immediate actions to review the water treatment process and ensure safety of the drinking water in this area.


2018 ◽  
Vol 6 (1) ◽  
pp. 108 ◽  
Author(s):  
Ram Proshad ◽  
Md. Saiful Islam ◽  
Tapos Kormoker

This study was conducted to assess the ecological risk of heavy metals in soils collected from the industrial vicinity of Tangail district in Bangladesh. In this study, the levels of six heavy metals namely chromium (Cr), nickel (Ni), copper (Cu), arsenic (As), cadmium (Cd), and lead (Pb) in 15 sampling sites around the industrial vicinity of Tangail district in Bangladesh were assessed. The mean concentration of Cr, Ni, Cu, As, Cd and Pb in studied soils were 11.56, 23.92, 37.27, 6.11, 2.01, and 17.46 mg/kg, respectively. Certain indices, including the enrichment factor (EF), contamination factor (Cif), geoaccumulation index (Igeo), pollution load index (PLI), toxic unit analysis, and principal component analysis (PCA) were used to assess the ecological risk. The enrichment factor of all the studied metals for all sampling sites were in the descending order of Cd > Cu > As > Pb >Ni > Cr. The contamination factor values revealed that the studied soils were highly impacted by Cd. The pollution load index (PLI) values of Cd were higher than 1, indicating the progressive deterioration of soil due to Cd contamination. In the context of potential ecological risk (PER), soils from all sampling sites showed moderate to very high potential ecological risk.


Author(s):  
U. U. Ubong ◽  
I. O. Ekwere ◽  
E. E. Ikpe

This study evaluates the physico-chemical parameters and heavy metals in water, sediments and Tympanotonus fuscatus obtained from three sample sites along Iko River in Eastern Obolo LGA, AkwaIbom State. The heavy metal analysis results on Pb, Cd and Ni in sediments and Tympanotonus fuscatus were used to estimate the human health and ecological risk assessment of the study area. The human health risk assessment tools utilized in this study were estimated dietary intake (EDI), total hazard quotient (THQ) and hazard index (HI) while sediment pollution parameters evaluated were contamination factor (CF), contamination degree (CD), pollution load index (PLI) and geoaccumulation index (Igeo). Results obtained showed that EDI of Cd in periwinkle in the study sites ranged from 0.2 – 6.4 µg/kg-bw/day and exceeded the provisional tolerable dietary intake (PTDI), while EDI for Pb (0.0004 – 2.6 µg/kg-bw/day) and Ni (0.32 – 2 µg/kg-bw/day) was within the limit for all sites, except Ni in site II (34 µg/kg-bw/day) which was higher than the PTDI of 5 µg/kg-bw/day. The THQ of Cd in all sites was greater than 1, while Pb and Ni generally recorded THQ < 1. The hazard index (HI) was as follows: site I (2.36), sites II (24.44) and site III (6.5), highlighting a potential hazardous effect to humans as a result of the consumption of Tympanotonus fuscatus obtained from site II and III. The sediment pollution assessment revealed that the contamination factor (CF) and geoaccumulation index, Igeo of Cd were far above the permissible limits while Pb and Ni were mostly within limits. The estimated contamination degree (CD) and pollution load index (PLI) showed a high degree of pollution, which can be mainly attributed to the high degree of Cd contamination in the sediment. Therefore, the area under investigation is highly polluted and the periwinkle obtained from Iko river in the study area is unfit for human consumption.


Author(s):  
Xinyu Han ◽  
Shuai Li ◽  
Zezheng Li ◽  
Xiaochen Pang ◽  
Yuzhai Bao ◽  
...  

To explore the mass concentration levels and health risks of heavy metals in the air in dense traffic environments, PM2.5 samples were collected at three sites in the city of Kunming in April and October 2013, and January and May 2014. Ten heavy metals––V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb––were analyzed by ICP–MS, and the results showed PM2.5 concentrations significantly higher in spring and winter than in summer and autumn, especially for Zn and Pb. The concentration of heavy metals on working days is significantly higher, indicating that vehicle emissions are significant contributors. An enrichment factor analysis showed that Cr, Mn, Ni, Cu, Zn, As, Cd and Pb come mainly from anthropogenic sources, while V and Co may be both anthropogenic and natural. The correlation and principal component analysis (PCA) showed that Ni, Cu, Zn, Cd and Pb mainly come from vehicles emissions and metallurgical industries; Cr and Mn, from vehicles emissions and road dust; and As, mainly from coal combustion. The health risk assessment shows that the non-carcinogenic risk thresholds of the heavy metals in PM2.5 to children and adult men and women are all less than 1. The carcinogenic risk of Cr for men and women in traffic-intensive areas exceeds 10−4, reaching 1.64 × 10−4 and 1.4 × 10−4, respectively.


Author(s):  
Fei Wang ◽  
Kai Song ◽  
Xuelian He ◽  
Yue Peng ◽  
Dan Liu ◽  
...  

The shallow weathering fissure groundwater in the red-bed area of Southwest China is usually the only drinking water source for most rural residents. In this study, a typical landfill with surrounding residents drinking unpurified groundwater in red-bed area was selected and water quality detection, groundwater numerical simulation and human health risk assessment were used to identify and assess groundwater pollution in the region. The chemical type evolved from HCO3-SO4-Ca-Mg and HCO3-SO4-Ca to Na-Ca-Cl-HCO3 contaminated by the landfill. Na+ and Cl− were selected as factors for rapid identification of groundwater pollution. Subsequent analyses using these factors showed that the leachate pollution plume boundary was 190 m downstream of the landfill. Analysis of the redox conditions revealed that the area from the landfill to 5 m downstream was the reduction zone, while the area beyond 5 m was the oxidation zone. The migration and attenuation patterns of inorganic salts (such as SO42−) and heavy metals (such as Fe and Mn) in the oxidation and reduction zones differed obviously. Meanwhile, the organic pollutants in the leachate were reduced and decomposed into organic acids, which caused the groundwater 80 m downstream of the landfill to become weakly acidic (pH ranged from 6.51 to 6.83), and promoted re-entry of adsorbed heavy metals (such as Pb) into the groundwater. The groundwater risk assessment based on human health revealed that lead, manganese, chlorobenzene, dichloroethane and chloroform constituted a major health threat to the residents. The rank of non-carcinogenic risk was lead >manganese, and the maximum area of non-carcinogenic risk was 15,485 m2. The total carcinogenic risk caused by organic pollutants was 7.9 × 10−6, and the area of the carcinogenic risk zone was 11,414 m2. Overall, the results of this study provide a scientific basis for management of drinking water and groundwater remediation in the red-bed area with low permeability.


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