scholarly journals Development of Polyoxymethylene Particles via the Solution-Dissolution Process and Application to the Powder Bed Fusion of Polymers

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1535 ◽  
Author(s):  
Maximilian A. Dechet ◽  
Ina Baumeister ◽  
Jochen Schmidt
Keyword(s):  
Thermal Properties ◽  
Size Distribution ◽  
Solubility Parameters ◽  
Dissolution Process ◽  
Powder Bed Fusion ◽  
Powder Bed ◽  
Bulk Solid ◽  
Hausner Ratio ◽  
Feedstock Material ◽  
Liquid Liquid Phase Separation

In this study, the development of a polyoxymethylene (POM) feedstock material for the powder bed fusion (PBF) of polymers is outlined. POM particles are obtained via liquid-liquid phase separation (LLPS) and precipitation, also known as the solution-dissolution process. In order to identify suitable POM solvent systems for LLPS and precipitation, in the first step, a solvent screening based on solubility parameters was performed, and acetophenone and triacetin were identified as the most promising suitable moderate solvents for POM. Cloud point curves were measured for both solvents to derive suitable temperature profiles and polymer concentrations for the solution-dissolution process. In the next step, important process parameters, namely POM concentration and stirring conditions, were studied to elucidate their effect on the product’s properties. The product particles obtained from both aforementioned solvents were characterized with regard to their morphology and size distribution, as well as their thermal properties (cf. the PBF processing window) and compared to a cryo-milled POM PBF feedstock. Both solvents allowed for precipitation of POM particles of an appropriate size distribution for PBF for polymer concentrations of at least up to 20 wt.%. Finally, a larger powder batch for application in the PBF process was produced by precipitation from the preferred solvent acetophenone. This POM powder was further analyzed concerning its flowability, Hausner ratio, and mass-specific surface area. Finally, test specimens, namely a complex gyroid body and a detailed ornament, were successfully manufactured from this feedstock powder showing appropriate bulk solid and thermal properties to demonstrate PBF processability. In summary, a processable and suitable POM PBF feedstock could be developed based on the non-mechanical solution dissolution process, which, to the authors’ best knowledge, has not been reported in previous studies.

scholarly journals Powder Reuse Cycles in Electron Beam Powder Bed Fusion—Variation of Powder Characteristics

Materials ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4602
Author(s):  
Gitanjali Shanbhag ◽  
Mihaela Vlasea
Keyword(s):  
Electron Beam ◽  
Nitrogen Content ◽  
Size Distribution ◽  
Angle Of Repose ◽  
Powder Size ◽  
Powder Bed Fusion ◽  
Powder Bed ◽  
Flow Energy ◽  
Hausner Ratio ◽  
Powder Characteristics

A path to lowering the economic barrier associated with the high cost of metal additively manufactured components is to reduce the waste via powder reuse (powder cycled back into the process) and recycling (powder chemically, physically, or thermally processed to recover the original properties) strategies. In electron beam powder bed fusion, there is a possibility of reusing 95–98% of the powder that is not melted. However, there is a lack of systematic studies focusing on quantifying the variation of powder properties induced by number of reuse cycles. This work compares the influence of multiple reuse cycles, as well as powder blends created from reused powder, on various powder characteristics such as the morphology, size distribution, flow properties, packing properties, and chemical composition (oxygen and nitrogen content). It was found that there is an increase in measured response in powder size distribution, tapped density, Hausner ratio, Carr index, basic flow energy, specific energy, dynamic angle of repose, oxygen, and nitrogen content, while the bulk density remained largely unchanged.

scholarly journals Effect of Particle Size Distribution on Laser Powder Bed Fusion Manufacturability of Copper

2021 ◽  
Author(s):  
Massimiliano Bonesso ◽  
Pietro Rebesan ◽  
Claudio Gennari ◽  
Simone Mancin ◽  
Razvan Dima ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Particle Size ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Physical And Mechanical Properties ◽  
Powder Bed Fusion ◽  
Laser Powder Bed Fusion ◽  
Powder Bed ◽  
Cooling Channels ◽  
Scan Speed

AbstractOne of the major benefits of the Laser Powder Bed Fusion (LPBF) technology is the possibility of fabrication of complex geometries and features in only one-step of production. In the case of heat exchangers in particular, this is very convenient for the fabrication of conformal cooling channels which can improve the performance of the heat transfer capability. Yet, obtaining dense copper parts printed via LPBF presents two major problems: the high reflectivity of 1 μm (the wavelength of commonly used laser sources) and the high thermal conductivity of copper that limits the maximum local temperature that can be attained. This leads to the formation of porous parts.In this contribution, the influence of the particle size distribution of the powder on the physical and mechanical properties of parts produced via LPBF is studied. Three copper powders lots with different particle size distributions are used in this study. The effect on densification from two laser scan parameters (scan speed and hatching distance) and the influence of contours scans on the lateral surface roughness is reported. Subsequently, samples manufactured with the optimal process parameters are tested for thermal and mechanical properties evaluation.

scholarly journals A novel, precipitated polybutylene terephthalate feedstock material for powder bed fusion of polymers (PBF): Material development and initial PBF processability

2021 ◽  
Vol 197 ◽  
pp. 109265
Author(s):  
Maximilian A. Dechet ◽  
Juan S. Gómez Bonilla ◽  
Moritz Grünewald ◽  
Kevin Popp ◽  
Johannes Rudloff ◽  
...  
Keyword(s):  
Powder Bed Fusion ◽  
Polybutylene Terephthalate ◽  
Powder Bed ◽  
Material Development ◽  
Feedstock Material

scholarly journals Plasma Spheroidisation of Irregular Ti6Al4V Powder for Powder Bed Fusion

Metals ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1763
Author(s):  
Nthateng Nkhasi ◽  
Willie du Preez ◽  
Hertzog Bissett
Keyword(s):  
Particle Size ◽  
Additive Manufacturing ◽  
Particle Size Distribution ◽  
Size Distribution ◽  
Metal Powder ◽  
Weight Ratio ◽  
High Strength ◽  
Powder Bed Fusion ◽  
Metal Powders ◽  
Powder Bed

Metal powders suitable for use in powder bed additive manufacturing processes should ideally be spherical, dense, chemically pure and of a specified particle size distribution. Ti6Al4V is commonly used in the aerospace, medical and automotive industries due to its high strength-to-weight ratio and excellent corrosion resistance properties. Interstitial impurities in titanium alloys have an impact upon mechanical properties, particularly oxygen, nitrogen, hydrogen and carbon. The plasma spheroidisation process can be used to spheroidise metal powder consisting of irregularly shaped particles. In this study, the plasma spheroidisation of metal powder was performed on Ti6Al4V powder consisting of irregularly shaped particles. The properties of the powder relevant for powder bed fusion that were determined included the particle size distribution, morphology, particle porosity and chemical composition. Conclusions were drawn regarding the viability of using this process to produce powder suitable for additive manufacturing.

A Combined Experimental-Numerical Method to Evaluate Powder Thermal Properties in Laser Powder Bed Fusion

2018 ◽  
Author(s):  
Bo Cheng ◽  
Brandon Lane ◽  
Justin Whiting ◽  
Kevin Chou
Keyword(s):  
Heat Transfer ◽  
Thermal Conductivity ◽  
Thermal Properties ◽  
Thermal Diffusivity ◽  
Laser Flash ◽  
Powder Layer ◽  
Powder Bed Fusion ◽  
Laser Powder Bed Fusion ◽  
Powder Bed ◽  
Powder Particles

Powder bed metal additive manufacturing (AM) utilizes a high-energy heat source scanning at the surface of a powder layer in a pre-defined area to be melted and solidified to fabricate parts layer by layer. It is known that powder bed metal AM is primarily a thermal process and further, heat conduction is the dominant heat transfer mode in the process. Hence, understanding the powder bed thermal conductivity is crucial to process temperature predictions, because powder thermal conductivity could be substantially different from its solid counterpart. On the other hand, measuring the powder thermal conductivity is a challenging task. The objective of this study is to investigate the powder thermal conductivity using a method that combines a thermal diffusivity measurement technique and a numerical heat transfer model. In the experimental aspect, disk-shaped samples, with powder inside, made by a laser powder bed fusion (LPBF) system, are measured using a laser flash system to obtain the thermal diffusivity and the normalized temperature history during testing. In parallel, a finite element model is developed to simulate the transient heat transfer of the laser flash process. The numerical model was first validated using reference material testing. Then, the model is extended to incorporate powder enclosed in an LPBF sample with thermal properties to be determined using an inverse method to approximate the simulation results to the thermal data from the experiments. In order to include the powder particles’ contribution in the measurement, an improved model geometry, which improves the contact condition between powder particles and the sample solid shell, has been tested. A multi-point optimization inverse heat transfer method is used to calculate the powder thermal conductivity. From this study, the thermal conductivity of a nickel alloy 625 powder in powder bed conditions is estimated to be 1.01 W/m·K at 500 °C.

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