scholarly journals Heat-Induced Acceleration of Pozzolanic Reaction Under Restrained Conditions and Consequent Structural Modification

Materials ◽  
2020 ◽  
Vol 13 (13) ◽  
pp. 2950
Author(s):  
Nankyoung Lee ◽  
Yeonung Jeong ◽  
Hyunuk Kang ◽  
Juhyuk Moon
Keyword(s):  
High Temperature ◽  
Silica Fume ◽  
High Performance ◽  
Structural Modification ◽  
Cement Hydration ◽  
Mechanical Performance ◽  
High Performance Concrete ◽  
Pozzolanic Reaction ◽  
Strength Development ◽  
Ultra High Performance Concrete

This study investigated the heat-induced acceleration of cement hydration and pozzolanic reaction focusing on mechanical performance and structural modification at the meso- and micro-scale. The pozzolanic reaction was implemented by substituting 20 wt.% of cement with silica fume, considered the typical dosage of silica fume in ultra-high performance concrete. By actively consuming a limited amount of water and outer-formed portlandite on the unreacted cement grains, it was confirmed that high-temperature curing greatly enhances the pozzolanic reaction when compared with cement hydration under the same environment. The rate of strength development from the dual reactions of cement hydration and pozzolanic reaction was increased. After the high-temperature curing, further strength development was negligible because of the limited space availability and preconsumption of water under a low water-to-cement environment. Since the pozzolanic reaction does not directly require the anhydrous cement, the reaction can be more easily accelerated under restrained conditions because it does not heavily rely on the diffusion of the limited amount of water. Therefore, it significantly increases the mean chain length of the C–S–H, the size of C–S–H globules with a higher surface fractal dimension. This finding will be helpful in understanding the complicated hydration mechanism of high-strength concrete or ultra-high performance concrete, which has a very low water-to-cement ratio.

The Pozzolanic Reaction of Silica Fume

2012 ◽  
Vol 1488 ◽  
Author(s):  
Ole M. Jensen
Keyword(s):  
Silica Fume ◽  
High Performance ◽  
Cement Hydration ◽  
Theoretical Calculations ◽  
Pozzolanic Reaction ◽  
Interfacial Transition Zone ◽  
Strength Development ◽  
Micro Structure ◽  
Cementitious Binder ◽  
Portland Cement Hydration

ABSTRACTSilica fume is a very important supplementary cementitious binder in High-Performance and Ultra High-Performance Concretes. Through its pozzolanic reaction the silica fume densifies the concrete micro-structure, in particular it strengthens the paste-aggregate interfacial transition zone. In the present paper different aspects of the pozzolanic reaction of silica fume are investigated. These include chemical shrinkage, isothermal heat development and strength development. Key data for these are given and compared with theoretical calculations, and based on presented measurements the energy of activation of the pozzolanic reaction of silica fume is estimated. The results show that the pozzolanic reaction of silica fume has notable differences from Portland cement hydration.

scholarly journals Elucidation of the Hydration Reaction of UHPC Using the PONKCS Method

Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4661
Author(s):  
Hyunuk Kang ◽  
Nankyoung Lee ◽  
Juhyuk Moon
Keyword(s):  
Heat Treatment ◽  
Silica Fume ◽  
High Performance ◽  
High Performance Concrete ◽  
Structural Evolution ◽  
Pozzolanic Reaction ◽  
Hydration Reaction ◽  
Ultra High Performance Concrete ◽  
Degree Of Hydration ◽  
Amorphous Phases

This study explored the hydration reaction of ultra-high-performance concrete (UHPC) by using X-ray diffraction (XRD), nuclear magnetic resonance (NMR), and thermogravimetric analysis (TGA) as analysis methods. The partial- or no-known crystal structure (PONKCS) method was adopted to quantify the two main amorphous phases of silica fume and C-S-H; such quantification is critical for understanding the hydration reaction of UHPC. The measured compressive strength was explained well by the degree of hydration found by the PONKCS method, particularly the amount of amorphous C-S-H. During heat treatment, the pozzolanic reaction was more intensified by efficiently consuming silica fume. After heat treatment, weak but continuous hydration was observed, in which the cement hydration reaction was dominant. Furthermore, the study discussed some limitations of using the PONKCS method for studying the complicated hydration assemblage of UHPC based on the results of TGA and NMR. Generally, the PONKCS method underestimated the content of silica fume in the early age of heat treatment. Furthermore, the structural evolution of C-S-H, confirmed by NMR, should be considered for more accurate quantification of C-S-H formed in UHPC. Nevertheless, PONKCS-based XRD could be useful for understanding and optimizing the material properties of UHPC undergoing heat treatment.

SUSTAINABLE ULTRA-HIGH-PERFORMANCE GLASS CONCRETE FOR INFRASTRUCTURES

2017 ◽  
Vol 4 (1) ◽  
Author(s):  
Arezki Tagnit-Hamou ◽  
Nancy A. Soliman
Keyword(s):  
High Performance ◽  
Glass Powder ◽  
Mechanical Performance ◽  
High Performance Concrete ◽  
Low Cost ◽  
Research Work ◽  
High Strength ◽  
Quartz Powder ◽  
Ultra High Performance Concrete ◽  
Powder Particles

This paper presents research work on the development of a green type of ultra-high-performance concrete using ground glass powders with different degrees of fineness (UHPGC). This article presents the development of an innovative, low-cost, and sustainable UHPGC through the use of glass powder to replace cement, and quartz powder particles. An UHPGC with a compressive strength (fc) of up to 220 MPa was prepared and its fresh, and mechanical properties were investigated. The test results indicate that the fresh UHPGC properties were improved when the cement and quartz powder were replaced with non-absorptive glass powder particles. The strength improvement can be attributed to the glass powder’s pozzolanicity and to its mechanical performance (very high strength and elastic modulus of glass). A case study of using this UHPGC is presented through the design and construction of a footbridge. Erection of footbridge at University of Sherbrooke Campus using UHPGC is also presented as a full-scale application.

Influence of Cold Weather on Compressive Strength in High Performance with Silica Fume

2014 ◽  
Vol 627 ◽  
pp. 445-448 ◽  
Author(s):  
Young Il Jang ◽  
Wan Shin Park ◽  
Sun Woong Kim ◽  
Song Hui Yun ◽  
Hyun Do Yun ◽  
...  
Keyword(s):  
Compressive Strength ◽  
Silica Fume ◽  
High Performance ◽  
Mechanical Performance ◽  
High Performance Concrete ◽  
Weather Condition ◽  
Weather Conditions ◽  
Cold Weather ◽  
Binder Ratio ◽  
Hot Weather

This paper addresses the influence of cold weather on the compressive strength of high performance concrete with silica fume under different curing days. Test variables of this study are weather condition (5°C, -5°C and-15°C) and different curing days (7days and 28 days). In this work, the specimen was designed a water-binder ratio of 0.34. One batches of concrete were prepared for each mixing hour, and the compressive strength of cylindrical concrete specimens was measured after 7 and 28 days. Test results for concrete compressive strength show that the concrete’s best mechanical performance occurred when there was the least difference between ambient temperature and concrete temperature, that is, during the later hours of the day in hot weather conditions.

Material Properties of Ultra - High Performance Concrete in Extreme Conditions

2016 ◽  
Vol 711 ◽  
pp. 157-162 ◽  
Author(s):  
David Citek ◽  
Milan Rydval ◽  
Stanislav Rehacek ◽  
Jiří Kolísko
Keyword(s):  
Mechanical Properties ◽  
High Temperature ◽  
Material Properties ◽  
High Performance ◽  
High Performance Concrete ◽  
High Strength ◽  
Accurate Information ◽  
Extreme Conditions ◽  
Ultra High Performance Concrete ◽  
Freeze Thaw

The Ultra High Performance Concrete (UHPC) is a very promising material suitable for application in special structures. However, the knowledge of performance of this relatively new material is rather limited. The exceptional mechanical properties of UHPC allow for a modification of the design rules, which are applicable in ordinary or high strength concrete. This paper deals in more detail with impact of thermal stress on bond properties between prestressing strands and UHPC and an influence of high temperature to final material properties of different UHPC mixtures. Specimens in the first experimental part were subjected to the cycling freeze-thaw testing. The relationship between bond behavior of both type of material (UHPC and ordinary concrete) and effect of cycling freeze-thaw tests was investigated. The second part of experimental work was focused on mechanical properties of UHPC exposure to the high temperature (Tmax = 200°C to Tmax = 1000°C). Tested mechanical properties were compressive and flexural strengths, the fracture properties will be presented in the next paper. The obtained experimental data serve as a basis for further systematic experimental verification and more accurate information about the significantly higher material properties of UHP(FR)C and its behavior in extreme conditions.

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