scholarly journals Provenance and Sedimentary Context of Clay Mineralogy in an Evolving Forearc Basin, Upper Cretaceous-Paleogene and Eocene Mudstones, San Joaquin Valley, California

Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 71
Author(s):  
Andrew Hurst ◽  
Michael Wilson ◽  
Antonio Grippa ◽  
Lyudmyla Wilson ◽  
Giuseppe Palladino ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Upper Cretaceous ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Bulk Rock ◽  
X Ray Diffraction ◽  
Arc Volcanism ◽  
X Ray ◽  
Magmatic Arc ◽  
Tropical Weathering

Mudstone samples from the Moreno (Upper Cretaceous-Paleocene) and Kreyenhagen (Eocene) formations are analysed using X-ray diffraction (XRD) and X-ray fluorescence (XRF) to determine their mineralogy. Smectite (Reichweite R0) is the predominant phyllosilicate present, 48% to 71.7% bulk rock mineralogy (excluding carbonate cemented and highly bio siliceous samples) and 70% to 98% of the <2 μm clay fraction. Opal CT and less so cristobalite concentrations cause the main deviations from smectite dominance. Opal A is common only in the Upper Kreyenhagen. In the <2 μm fraction, the Moreno Fm is significantly more smectite-rich than the Kreyenhagen Fm. Smectite in the Moreno Fm was derived from the alteration of volcaniclastic debris from contemporaneous rhyolitic-dacitic magmatic arc volcanism. No tuff is preserved. Smectite in the Kreyenhagen Fm was derived from intense sub-tropical weathering of granitoid-dioritic terrane during the hypothermal period in the early to mid-Eocene; the derivation from local volcanism is unlikely. All samples had chemical indices of alteration (CIA) indicative of intense weathering of source terrane. Ferriferous enrichment and the occurrence of locally common kaolinite are contributory evidence for the intensity of weathering. Low concentration (max. 7.5%) of clinoptilolite in the Lower Kreyenhagen is possibly indicative of more open marine conditions than in the Upper Kreyenhagen. There is no evidence of volumetrically significant silicate diagenesis. The main diagenetic mineralisation is restricted to low-temperature silica phase transitions.

THE OCCURRENCE OF CHLORITE AND VERMICULITE IN THE CLAY FRACTION OF THREE BRITISH COLUMBIA SOILS

1959 ◽  
Vol 39 (2) ◽  
pp. 246-253
Author(s):  
A. A. Theisen ◽  
G. R. Webster ◽  
M. E. Harward
Keyword(s):  
British Columbia ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Vancouver Island ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Past ◽  
Surface Samples

The clay mineralogy of surface samples from three soils on Vancouver Island which had been used in fertility experiments was determined by X-ray diffraction. Chlorite was identified as the predominant mineral in all three soils. Vermiculite was present in discrete units in the Chemainus soil and interstratified with chlorite in the Fairbridge and Merville soils. Kaolinite may also have been a constituent; this could not be determined since the use of certain criteria, proposed in the past for the identification of kaolinite in the presence of chlorite, proved unsuccessful. It was concluded that no universal criterion, which holds true in all cases, exists for distinguishing kaolinite in the presence of chlorite.

Some aspects of the genesis of an alpine humus soil

Soil Research ◽  
1973 ◽  
Vol 11 (1) ◽  
pp. 1 ◽  
Author(s):  
R Brewer ◽  
AD Haldane
Keyword(s):  
Sudden Change ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Soil Formation ◽  
Mineral Weathering ◽  
X Ray Diffraction ◽  
X Ray ◽  
Humus Soil ◽  
In Situ Weathering

An alpine humus soil profile has been examined in the field, in thin section and by X-ray diffraction. The presence of a stone line and the sudden change in characteristics across the stone line, including particle size distribution, degree of exfoliation of the micas, major mineral composition, and clay mineralogy suggest that this is a polygenetic profile consisting of two soil stratigraphic units. There has been little pedological reorganization within either unit, soil formation consisting essentially of in situ weathering, removal of soluble constituents, and accumulation of organic matter, with some biological activity, in the upper unit. It is shown that gibbsite derived from weathering of feldspar is a major component of the clay fraction, especially in the lower unit. The clay mineralogy is considered in relation to proposed mineral weathering sequences and weathering in a yellow podzolic soil.

Clay minerals in the agricultural surface soils in the Central United States

Clay Minerals ◽  
2001 ◽  
Vol 36 (3) ◽  
pp. 277-294 ◽  
Author(s):  
B. Velde
Keyword(s):  
United States ◽  
Clay Minerals ◽  
Agricultural Soils ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Parent Material ◽  
X Ray Diffraction ◽  
Charge Site ◽  
X Ray ◽  
Central United States

AbstractA survey of the clay fraction at the surface of 86 loam and silt loam agricultural soils from the Central United States was undertaken to observe the possible influences of climate and parent material (dominantly phyllosilicates in this study) on the clay mineralogy of the upper portions of the soils, for the most part in Mollisol–Alfisol order soils.Decomposed X-ray diffraction spectra show that the most abundant clay minerals are two disordered illite-smectite (I-S) minerals, one with ∼50% smectite layers and another, less abundant, disordered I-S phase with 20% smectite. These minerals usually co-exist in the same samples. The charge site in both of these I-S minerals is both beidellitic and montmorillonitic in the expanding layers. A relatively large proportion of these smectite layers (up to 20%) are of high charge.There seems to be a convergence in mineralogy towards mixed-layer phases formed under a range of mid-Continent climates from a range of phyllosilicate parent materials.

THE CLAY MINERALS IN SOME BRITISH COLUMBIA SUBSOILS

1962 ◽  
Vol 42 (2) ◽  
pp. 296-301 ◽  
Author(s):  
J. S. Clark ◽  
J. E. Brydon ◽  
H. J. Hortie
Keyword(s):  
British Columbia ◽  
Diffraction Analysis ◽  
Clay Minerals ◽  
Clay Mineralogy ◽  
X Ray Diffraction ◽  
The South ◽  
Parent Materials ◽  
X Ray ◽  
Northeastern Part ◽  
Montmorillonitic Clay

X-ray diffraction analysis was used to identify the clay minerals present in fourteen subsoil samples that were selected to represent some more important clay-bearing deposits in British Columbia. The clay mineralogy of the subsoils varied considerably but montmorillonitic clay minerals tended to predominate in the water-laid deposits of the south and illite in the soil parent materials of the Interior Plains region of the northeastern part of the Province.

Temperature-induced structural phase transitions in RERhSn (RE = Y, Gd-Tm, Lu)

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Simon Engelbert ◽  
Rolf-Dieter Hoffmann ◽  
Jutta Kösters ◽  
Steffen Klenner ◽  
Rainer Pöttgen
Keyword(s):  
Rare Earth ◽  
Phase Transitions ◽  
Driving Force ◽  
Room Temperature ◽  
Structural Phase ◽  
Structural Phase Transitions ◽  
Line Broadening ◽  
X Ray Diffraction ◽  
Temperature Dependent ◽  
X Ray

Abstract The structures of the equiatomic stannides RERhSn with the smaller rare earth elements Y, Gd-Tm and Lu were reinvestigated on the basis of temperature-dependent single crystal X-ray diffraction data. GdRhSn crystallizes with the aristotype ZrNiAl at 293 and 90 K. For RE = Y, Tb, Ho and Er the HP-CeRuSn type (approximant with space group R3m) is already formed at room temperature, while DyRhSn adopts the HP-CeRuSn type below 280 K. TmRhSn and LuRhSn show incommensurate modulated variants with superspace groups P31m(1/3; 1/3; γ) 000 (No. 157.1.23.1) (γ = 3/8 for TmRhSn and γ = 2/5 for LuRhSn). The driving force for superstructure formation (modulation) is a strengthening of Rh–Sn bonding. The modulation is expressed in a 119Sn Mössbauer spectrum of DyRhSn at 78 K through line broadening.

X-ray diffraction study of phase transitions in iron(II) trisnioximate hexadecylboronate clathrochelate complex

2001 ◽  
Vol 46 (5) ◽  
pp. 758-770 ◽  
Author(s):  
I. I. Vorontsov ◽  
K. A. Potekhin ◽  
M. Yu. Antipin ◽  
Ya. Z. Voloshin ◽  
A. I. Stash ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Diffraction Study ◽  
X Ray Diffraction ◽  
X Ray

Late Mesozoic—Cenozoic clay mineral successions of southern Iran and their palaeoclimatic implications

Clay Minerals ◽  
2005 ◽  
Vol 40 (2) ◽  
pp. 191-203 ◽  
Author(s):  
F. Khormali ◽  
A. Abtahi ◽  
H. R. Owliaie
Keyword(s):  
Electron Microscopy ◽  
Upper Cretaceous ◽  
Sedimentary Rocks ◽  
X Ray Diffraction ◽  
Humid Climate ◽  
X Ray ◽  
Late Mesozoic ◽  
Southern Iran ◽  
Transmission Electron

AbstractClay minerals of calcareous sedimentary rocks of southern Iran, part of the old Tethys area, were investigated in order to determine their origin and distribution, and to reconstruct the palaeoclimate of the area. Chemical analysis, X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and thin-section studies were performed on the 16 major sedimentary rocks of the Fars and Kuhgiluyeh Boyerahmad Provinces.Kaolinite, smectite, chlorite, illite, palygorskite and illite-smectite interstratified minerals were detected in the rocks studied. The results revealed that detrital input is possibly the main source of kaolinite, smectite, chlorite and illite, whilein situneoformation during the Tertiary shallow saline and alkaline environment could be the dominant cause of palygorskite occurrences in the sedimentary rocks.The presence of a large amount of kaolinite in the Lower Cretaceous sediments and the absence or rare occurrence of chlorite, smectite, palygorskite and illite are in accordance with the warm and humid climate of that period. Smaller amounts of kaolinite and the occurrence of smectite in Upper Cretaceous sediments indicate the gradual shift from warm and humid to more seasonal climate. The occurrence of palygorskite and smectite and the disappearance of kaolinite in the late Palaeocene sediments indicate the increase in aridity which has probably continued to the present time.

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