Clay minerals in the agricultural surface soils in the Central United States

Clay Minerals ◽  
2001 ◽  
Vol 36 (3) ◽  
pp. 277-294 ◽  
Author(s):  
B. Velde
Keyword(s):  
United States ◽  
Clay Minerals ◽  
Agricultural Soils ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Parent Material ◽  
X Ray Diffraction ◽  
Charge Site ◽  
X Ray ◽  
Central United States

AbstractA survey of the clay fraction at the surface of 86 loam and silt loam agricultural soils from the Central United States was undertaken to observe the possible influences of climate and parent material (dominantly phyllosilicates in this study) on the clay mineralogy of the upper portions of the soils, for the most part in Mollisol–Alfisol order soils.Decomposed X-ray diffraction spectra show that the most abundant clay minerals are two disordered illite-smectite (I-S) minerals, one with ∼50% smectite layers and another, less abundant, disordered I-S phase with 20% smectite. These minerals usually co-exist in the same samples. The charge site in both of these I-S minerals is both beidellitic and montmorillonitic in the expanding layers. A relatively large proportion of these smectite layers (up to 20%) are of high charge.There seems to be a convergence in mineralogy towards mixed-layer phases formed under a range of mid-Continent climates from a range of phyllosilicate parent materials.

scholarly journals Provenance and Sedimentary Context of Clay Mineralogy in an Evolving Forearc Basin, Upper Cretaceous-Paleogene and Eocene Mudstones, San Joaquin Valley, California

Minerals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 71
Author(s):  
Andrew Hurst ◽  
Michael Wilson ◽  
Antonio Grippa ◽  
Lyudmyla Wilson ◽  
Giuseppe Palladino ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Upper Cretaceous ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Bulk Rock ◽  
X Ray Diffraction ◽  
Arc Volcanism ◽  
X Ray ◽  
Magmatic Arc ◽  
Tropical Weathering

Mudstone samples from the Moreno (Upper Cretaceous-Paleocene) and Kreyenhagen (Eocene) formations are analysed using X-ray diffraction (XRD) and X-ray fluorescence (XRF) to determine their mineralogy. Smectite (Reichweite R0) is the predominant phyllosilicate present, 48% to 71.7% bulk rock mineralogy (excluding carbonate cemented and highly bio siliceous samples) and 70% to 98% of the <2 μm clay fraction. Opal CT and less so cristobalite concentrations cause the main deviations from smectite dominance. Opal A is common only in the Upper Kreyenhagen. In the <2 μm fraction, the Moreno Fm is significantly more smectite-rich than the Kreyenhagen Fm. Smectite in the Moreno Fm was derived from the alteration of volcaniclastic debris from contemporaneous rhyolitic-dacitic magmatic arc volcanism. No tuff is preserved. Smectite in the Kreyenhagen Fm was derived from intense sub-tropical weathering of granitoid-dioritic terrane during the hypothermal period in the early to mid-Eocene; the derivation from local volcanism is unlikely. All samples had chemical indices of alteration (CIA) indicative of intense weathering of source terrane. Ferriferous enrichment and the occurrence of locally common kaolinite are contributory evidence for the intensity of weathering. Low concentration (max. 7.5%) of clinoptilolite in the Lower Kreyenhagen is possibly indicative of more open marine conditions than in the Upper Kreyenhagen. There is no evidence of volumetrically significant silicate diagenesis. The main diagenetic mineralisation is restricted to low-temperature silica phase transitions.

THE CLAY MINERALS IN SOME BRITISH COLUMBIA SUBSOILS

1962 ◽  
Vol 42 (2) ◽  
pp. 296-301 ◽  
Author(s):  
J. S. Clark ◽  
J. E. Brydon ◽  
H. J. Hortie
Keyword(s):  
British Columbia ◽  
Diffraction Analysis ◽  
Clay Minerals ◽  
Clay Mineralogy ◽  
X Ray Diffraction ◽  
The South ◽  
Parent Materials ◽  
X Ray ◽  
Northeastern Part ◽  
Montmorillonitic Clay

X-ray diffraction analysis was used to identify the clay minerals present in fourteen subsoil samples that were selected to represent some more important clay-bearing deposits in British Columbia. The clay mineralogy of the subsoils varied considerably but montmorillonitic clay minerals tended to predominate in the water-laid deposits of the south and illite in the soil parent materials of the Interior Plains region of the northeastern part of the Province.

scholarly journals The Occurrence of Authigenic Clay Minerals in Alkaline-Saline Lakes, Pantanal Wetland (Nhecolândia Region, Brazil)

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 718
Author(s):  
Isis Armstrong Dias ◽  
Leonardo Fadel Cury ◽  
Bruno Guimarães Titon ◽  
Gustavo Barbosa Athayde ◽  
Guilherme Fedalto ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Clay Minerals ◽  
Saline Lakes ◽  
Clay Fraction ◽  
Water Bodies ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Fine Clay ◽  
Pantanal Wetland

Mg clay minerals are usually associated with carbonates in alkaline-saline environments, precipitated from solution and/or transformation from other minerals. The aim of this research is to identify the mineralogy and geochemistry of clay minerals in different alkaline lakes in the Nhecolândia region, the southernmost region of the Pantanal wetland (Brazil). Sediment samples were analyzed by X-ray diffraction, X-ray fluorescence, scanning electron microscopy and transmission electron microscopy. Water samples were analyzed, determining their main cations and anions, in order to understand their relationship with the clays. The analyses allowed classifying the water bodies as saline, oligosaline and freshwater lakes. The sediments are composed mainly of quartz and a fine-clay fraction, dominated by illite, kaolinite and smectite. The XRD results showed illite and smectite mixed-layered in the saline lakes at Barranco Alto farm, whereas at Nhumirim farm, trioctahedral smectite was only observed in one lake. The smectite minerals were normally identified coupled with calcite at the top of the sequences, associated with exopolymeric substances (EPS) in the lakes, suggesting that these minerals are precipitating due to the physical-chemical and biological conditions of the water bodies.

Possible effects of land use on the clay mineralogy of a brown forest soil

Clay Minerals ◽  
2002 ◽  
Vol 37 (4) ◽  
pp. 663-670 ◽  
Author(s):  
D. C. Bain ◽  
D. T. Griffen
Keyword(s):  
Land Use ◽  
Clay Mineralogy ◽  
Parent Material ◽  
X Ray Diffraction ◽  
Brown Forest Soil ◽  
X Ray ◽  
Close Proximity ◽  
Diffraction Patterns ◽  
Effects Of Land Use ◽  
Brown Forest Soils

AbstractThree soil profiles classed as brown forest soils on schistose parent material, in close proximity but under different land uses, have been studied. The profile under 50 year-old Sitka spruce trees is the most acidic, the second profile under rough grassland is less acidic, and the third profile in an arable field which has been fertilized is the least acidic. The clay fractions (ς μm) of all three profiles are very similar. However, computer simulations of the X-ray diffraction patterns of clay phases using a modified version of NEWMOD revealed two possible weathering trends: (1) an increasing proportion of vermiculite in interstratified mica-vermiculite in the upper horizons of the arable and forested soils; (2) formation of high-charge corrensite by weathering of chlorite in all three profiles but least pronounced in the arable soil. The differences in clay mineralogy amongst the profiles are minor, but these two different weathering trends may be due to the effects of different land use.

scholarly journals Mineralogical Study of Levels with Magnesian Clay Minerals in the Santos Basin, Aptian Pre-Salt Brazil

Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 970
Author(s):  
Maurício Dias da Silva ◽  
Márcia Elisa Boscato Gomes ◽  
André Sampaio Mexias ◽  
Manuel Pozo ◽  
Susan Martins Drago ◽  
...  
Keyword(s):  
Clay Minerals ◽  
Clay Fraction ◽  
Total Sample ◽  
Petrographic Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Mineralogical Study ◽  
Original Rock ◽  
Mixed Layers

The object of this study is magnesian clay minerals present in carbonate rocks of the post-rift phase of the pre-salt in the Santos Basin. These rocks developed in an Aptian-age alkaline lacustrine environment. This study summarizes the formation of clay minerals associated with different lithotypes in a range of 19 m and a depth of more than 5100 m. They were characterized from petrographic analysis by optical microscopy, X-ray diffraction (total sample and clay fraction), and modeling by Newmod®; and examined and analyzed by scanning electron microscopy. An approach based on identifying lithotypes and characterization of microsites allowed us to understand the occurrence of different clay minerals. Kerolite was the most abundant mineral in the sampled range. It occurs in lamellar aggregates under greater preservation of the original rock lamination and in association with spherulites and shrubs. The Stv/Ker mixed layers occurs in the same association, and formed finer unlaminated aggregates associated with the more intense dolomitization and silicification processes. Saponite occurs associated with detrital minerals forming clayey levels intercalated with microcrystalline carbonates. Fluids with a high Mg/Si and pH < 9 favor the precipitation of kerolite. The increase in pH during diagenesis may be responsible for the formation of Stv/Ker mixed layers.

WEATHERING OF CLAY MINERALS IN PODZOLS FROM THE APPALACHIAN HIGHLANDS

1974 ◽  
Vol 54 (4) ◽  
pp. 395-401 ◽  
Author(s):  
C. R. DE KIMPE
Keyword(s):  
Heat Treatment ◽  
Clay Minerals ◽  
Clay Fraction ◽  
Heat Treatments ◽  
X Ray Diffraction ◽  
X Ray ◽  
Early Stages ◽  
Mineralogical Properties

The clay fraction from various horizons of two Podzols sampled in the Appalachian Highlands was analyzed by X-ray diffraction and by a quantitative mineralogical procedure. Different cation saturation and heat treatments made it possible to detect differences in the mineralogical properties of the clays of the Ae horizon, but did not cause appreciable differences in the spectra of B and C horizon samples. In the Ae horizon, the clays were shown to have properties of both vermiculites and smectites. The paragonite-like structure induced by Na-saturation and moderate heat treatment is characteristic of minerals in the early stages of weathering from dioctahedral illites.

Clay Mineralogy of Selected Clays from the English Wealden

1962 ◽  
Vol 99 (2) ◽  
pp. 128-136 ◽  
Author(s):  
R. W. Tank
Keyword(s):  
Clay Minerals ◽  
Mixed Layer ◽  
Mineral Assemblage ◽  
Depositional Environment ◽  
Clay Mineralogy ◽  
Source Area ◽  
Parent Material ◽  
X Ray ◽  
Layer Structures ◽  
Clay Mineral Assemblage

AbstractX-ray analyses of selected samples from the argillaceous subdivisions of the English Wealden indicate that illite, kaolinite, and mixed-layer structures are present in variable amounts. The clay mineral assemblage is thought to reflect parent material, weathering conditions in the source area, and possibly some degrading of the illite structure by the action of active waters in the depositional environment. The specific clay minerals are tentatively correlated with the palaeogeographical framework proposed by Allen (1954). It is suggested that the kaolinite was derived mainly from the Palaeozoic uplands, and the bulk of the illite and mixed-layer structures from the marginal Jurassic lowland.

ETUDE COMPARATIVE DE SOLS DES LAURENTIDES, QUEBEC

1975 ◽  
Vol 55 (3) ◽  
pp. 363-379 ◽  
Author(s):  
B. MUTWEWINGABO ◽  
C. R. DE KIMPE ◽  
G. A. BOURBEAU ◽  
R. W. BARIL ◽  
P. LAJOIE
Keyword(s):  
Particle Size ◽  
Clay Fraction ◽  
Parent Material ◽  
The Other ◽  
Quebec City ◽  
X Ray Diffraction ◽  
X Ray ◽  
High Bulk Density ◽  
Diffraction Patterns ◽  
High Bulk

Five profiles were sampled in the till deposits of the Laurentides Hills. Two were obtained at Duchesnay, near Quebec City and three north of Montreal, including two profiles of the Gatineau and one of the Sainte-Agathe series of soils. Results of the particle-size distribution, morphological and mineralogical analyses suggested that the parent material was similar in all profiles. A high bulk density, about 2.00 g/cm3, was observed in the fragic horizon. Maximum weathering was found in the A horizons resulting in the formation of montmorillonite and kaolinite. The X-ray diffraction patterns obtained for the samples from Duchesnay were better defined than those obtained from the other profiles. In addition to illite, chlorite and vermiculite, two types of interstratified minerals were observed: illite–montmorillonite in the Podzolic-B and illite–vermiculite in the fragic horizons. High values, up to about 700 meq/100 g were obtained for the Al interlayers in the clay fraction. These profiles were classified as fragic ferro-humic Podzols (Sainte-Agathe and the profiles from Duchesnay) and fragic humo-ferric Podzols (Gatineau). The concept of fragic horizon in the soils from the Laurentides is discussed.

scholarly journals ÍNDICE DE CRISTALINIDADE DA ILITA E CARACTERIZAÇÃO DOS ARGILOMINERAIS DA FORMAÇÃO PIMENTA BUENO – BACIA DOS PARECIS

2016 ◽  
Author(s):  
Jéssica Melanya Sisti de Paiva ◽  
Gislaine Amorés Battilani ◽  
Rubia Ribeiro Viana ◽  
Maurício José dos Reis
Keyword(s):  
Clay Minerals ◽  
Clay Fraction ◽  
X Ray Diffraction ◽  
Average Width ◽  
X Ray ◽  
Kübler Index ◽  
Half Height ◽  
Intracratonic Basins ◽  
Bottom To Top

ResumoA Bacia dos Parecis é uma das maiores bacias intracratônicas brasileiras e poucos são os estudos relacionados à sua gênese. A Formação Pimenta Bueno, objeto desse estudo, é constituída, da base para o topo, de calcários, folhelhos, siltitos e arenitos. O presente estudo tem como principal objetivo estimar o provável estágio diagenético/metamórfico em que essas rochas foram submetidas, por meio do estudo de difratogramas de raios-X da fração argila e dos parâmetros do Índice de Kübler (Índice de Cristalinidade da Ilita). Os resultados indicam que essas rochas encontram-se na Epizona e, a média das medidas da largura a meia altura (FWHM) é de 0,16°. A análise de difratometria de raios – X indicou a presença de clorita, ilita, pirofilita, caulinita e esmectita (montmorilonita). Além das espécies bem definidas, identificou-se, também, argilominerais interestratificados de ilita/esmectita e clorita/esmectita.Palavras Chave: Cristalinidade da ilita; Bacia dos Parecis; Formação Pimenta Bueno.AbstractINDEX CRYSTALLINITY OF ILLITE AND CHARACTERIZATION CLAY MINERALS OF PIMENTA BUENO FORMATION – PARECIS BASIN. The Parecis basin is one of the largest Brazilian intracratonic basins and few are the studies related to its genesis. Pimenta Bueno Formation, object of this study, is represented, from bottom to top, by limestones, shales, siltstones and sandstones. To achieve the objectives of this study, knowing the diagenetic stage and / or metamórphic degree to which were subjected the Parecis Basin rocks, were developed diffraction studies of X-ray of the clay fraction, followed by the calculation of the Kübler Index parameters (crystallinity of iIlita). The results indicated that these rocks are at the Epizone and the average width measured at half height (FWHM) is 0.16 °. The X-ray diffraction indicated the presence of the chlorite, illite, pyrophyllite, kaolinite and smectite (montmorillonite). Likewise were identified interstratified phases of Illite/ smectite and chlorite / smectite.Keywords: Crystallinity of Ilita; Parecis Basin; Pimenta Bueno Formation.

THE OCCURRENCE OF CHLORITE AND VERMICULITE IN THE CLAY FRACTION OF THREE BRITISH COLUMBIA SOILS

1959 ◽  
Vol 39 (2) ◽  
pp. 246-253
Author(s):  
A. A. Theisen ◽  
G. R. Webster ◽  
M. E. Harward
Keyword(s):  
British Columbia ◽  
Clay Fraction ◽  
Clay Mineralogy ◽  
Vancouver Island ◽  
X Ray Diffraction ◽  
X Ray ◽  
The Past ◽  
Surface Samples

The clay mineralogy of surface samples from three soils on Vancouver Island which had been used in fertility experiments was determined by X-ray diffraction. Chlorite was identified as the predominant mineral in all three soils. Vermiculite was present in discrete units in the Chemainus soil and interstratified with chlorite in the Fairbridge and Merville soils. Kaolinite may also have been a constituent; this could not be determined since the use of certain criteria, proposed in the past for the identification of kaolinite in the presence of chlorite, proved unsuccessful. It was concluded that no universal criterion, which holds true in all cases, exists for distinguishing kaolinite in the presence of chlorite.

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