scholarly journals The Sulfide/Silicate Coefficients of Nd and Sm: Geochemical “Fingerprints” for the Syn- and Epigenetic Cu-Ni-(PGE) Ores in the NE Fennoscandian Shield

Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1069
Author(s):  
Pavel Serov ◽  
Tamara Bayanova
Keyword(s):  
Partition Coefficients ◽  
Melt Inclusions ◽  
Sulfide Minerals ◽  
Fennoscandian Shield ◽  
The Other ◽  
Mineral Formation ◽  
Nd Isotope ◽  
Probable Source ◽  
Isotope Systematics ◽  
Crystallization Stage

One of the current directions of the Sm-Nd isotope systematics development is a dating of the ore process using sulfide minerals. Yet, the issue of the existence of rare earth elements (REE) in sulfides is still a matter for discussion. Sulfides from ore-bearing rocks of Proterozoic (2.53–1.98 Ga) Cu-Ni and platinum group elements (PGE) deposits of the Fennoscandian Shield were studied. It is found that the most probable source of REE in sulfide minerals from Cu-Ni-PGE complexes could be submicronic fluid inclusions, which are trapped at the mineral crystallization stage. In such a case, fluid or melt inclusions are specimens of the syngenetic parental melt, from which the base mineral formed, and these reflect a composition of the parental fluid. The mineral–rock partition coefficients for Nd and Sm can be used as “fingerprints” for individual deposits, and these are isotope-geochemical indicators of the ore-caused fluid that is syngenetic to sulfide. Moreover, the DNd/DSm ratio for various sulfide minerals can be used as a prospective geochemical tool for reconstructing a mineral formation sequence in ore complexes. On the other hand, differences in isotope compositions of sulfide neodymium could be markers of some ore-caused fluids and related to certain generations of sulfide minerals.

Non-linear dynamics, chaos, complexity and enclaves in granitoid magmas

1996 ◽  
Vol 87 (1-2) ◽  
pp. 217-223 ◽  
Author(s):  
James Flinders ◽  
John D. Clemens
Keyword(s):  
Deterministic Chaos ◽  
Interfacial Area ◽  
Two Dimensions ◽  
Mixing Processes ◽  
Nd Isotope ◽  
Natural Systems ◽  
Non Linear ◽  
The Difference ◽  
Magma System ◽  
Isotope Systematics

ABSTRACT:Most natural systems display non-linear dynamic behaviour. This should be true for magma mingling and mixing processes, which may be chaotic. The equations that most nearly represent how a chaotic natural system behaves are insoluble, so modelling involves linearisation. The difference between the solution of the linearised and ‘true’ equation is assumed to be small because the discarded terms are assumed to be unimportant. This may be very misleading because the importance of such terms is both unknown and unknowable. Linearised equations are generally poor descriptors of nature and are incapable of either predicting or retrodicting the evolution of most natural systems. Viewed in two dimensions, the mixing of two or more visually contrasting fluids produces patterns by folding and stretching. This increases the interfacial area and reduces striation thickness. This provides visual analogues of the deterministic chaos within a dynamic magma system, in which an enclave magma is mingling and mixing with a host magma. Here, two initially adjacent enclave blobs may be driven arbitrarily and exponentially far apart, while undergoing independent (and possibly dissimilar) changes in their composition. Examples are given of the wildly different morphologies, chemical characteristics and Nd isotope systematics of microgranitoid enclaves within individual felsic magmas, and it is concluded that these contrasts represent different stages in the temporal evolution of a complex magma system driven by nonlinear dynamics. If this is true, there are major implications for the interpretation of the parts played by enclaves in the genesis and evolution of granitoid magmas.

Magmatic evolution of the Gaussberg lamproite (Antarctica): volatile content and glass composition

2004 ◽  
Vol 68 (1) ◽  
pp. 83-100 ◽  
Author(s):  
E. Salvioli-Mariani ◽  
L. Toscani ◽  
D. Bersani
Keyword(s):  
High Pressure ◽  
Infrared Spectra ◽  
Melt Inclusions ◽  
Glass Composition ◽  
Relative Increase ◽  
The Other ◽  
Residual Liquid ◽  
Volatile Content ◽  
Magmatic Evolution ◽  
Ultrapotassic Rock

AbstractThe lamproite of Gaussberg is an ultrapotassic rock where leucite, olivine and clinopyroxene microphenocrysts occur in a glass-rich groundmass, containing microliths of leucite, clinopyroxene, apatite, phlogopite and rare K-richterite.Abundant silicate melt inclusions occur in olivine, leucite and, rarely, in clinopyroxene microphenocrysts. Raman investigations on melt inclusions showed the presence of pure CO2 in the shrinkage bubbles. On the other hand, the glass of the groundmass is CO2-poor and contains up to 0.70 wt.% of dissolved H2O, as estimated by infrared spectra. It is inferred that CO2 was released at every stage of evolution of the lamproite magma (CO2-rich shrinkage bubbles), whereas H2O was retained for longer in the liquid. At Gaussberg, CO2 seems to have a major role at relatively high pressure where it favoured the crystallization of H2O-poor microphenocrysts; the uprise of the magma to the surface decreased the solubility of CO2 and caused a relative increase in water activity. As a consequence, phlogopite and K-richterite appeared in the groundmass.The glass composition of both the groundmass and melt inclusions suggests different evolutions for the residual liquids of the investigated samples. Sample G886 shows the typical evolution of a lamproite magma, where the residual liquid evolves toward peralkaline and Na-rich composition and crystallizes K-richterite in the latest stage. Sample G895 derives from mixing/mingling of different batches of magma; effectively glasses from melt inclusions in leucite and clinopyroxene are more alkaline than those found in early crystallized olivine. Leucite and clinopyroxene crystallized early from a relatively more alkaline batch of lamproite magma and, successively, a less alkaline, olivinebearing magma batch assimilated them during its rise to the surface.

scholarly journals Ediacaran–Palaeozoic tectonic evolution of the Ossa Morena and Central Iberian zones (SW Iberia) as revealed by Sm–Nd isotope systematics

2008 ◽  
Vol 461 (1-4) ◽  
pp. 202-214 ◽  
Author(s):  
Rafael López-Guijarro ◽  
Maider Armendáriz ◽  
Cecilio Quesada ◽  
Javier Fernández-Suárez ◽  
J. Brendan Murphy ◽  
...  
Keyword(s):  
Tectonic Evolution ◽  
Nd Isotope ◽  
Isotope Systematics

scholarly journals Trace-element and Nd-isotope systematics in detrital apatite of the Po river catchment: Implications for provenance discrimination and the lag-time approach to detrital thermochronology

Lithos ◽  
2017 ◽  
Vol 290-291 ◽  
pp. 48-59 ◽  
Author(s):  
Marco G. Malusà ◽  
Jiangang Wang ◽  
Eduardo Garzanti ◽  
Zhi-Chao Liu ◽  
Igor M. Villa ◽  
...  
Keyword(s):  
Trace Element ◽  
Lag Time ◽  
Po River ◽  
Nd Isotope ◽  
River Catchment ◽  
Isotope Systematics

scholarly journals The validation of quantum chemical lipophilicity prediction of alcohols

2016 ◽  
Vol 9 (2) ◽  
pp. 89-94 ◽  
Author(s):  
Martin Michalík ◽  
Vladimír Lukeš
Keyword(s):  
Linear Correlation ◽  
Quantum Chemical ◽  
Partition Coefficients ◽  
The Other ◽  
Basis Set ◽  
Implicit Solvent ◽  
Solvent Models ◽  
Lipophilicity Prediction ◽  
Triple Zeta ◽  
Implicit Solvent Models

AbstractThe validation of octanol-water partition coefficients (logP) quantum chemical calculations is presented for 27 alkane alcohols. The chemical accuracy of predicted logPvalues was estimated for six DFT functionals (B3LYP, PBE0, M06-2X, ωB97X-D, B97-D3, M11) and three implicit solvent models. Triple-zeta basis set 6-311++G(d,p) was employed. The best linear correlation with the experimental logPvalues was achieved for the B3LYP and B97-D3 functionals combined with the SMD model. On the other hand, no linearity was found when IEF-PCM or C-PCM implicit models were employed.

Early Tertiary basalts from the Labrador Sea floor and Davis Strait region

1989 ◽  
Vol 26 (5) ◽  
pp. 956-968 ◽  
Author(s):  
D. B. Clarke ◽  
B. I. Cameron ◽  
G. K. Muecke ◽  
J. L. Bates
Keyword(s):  
Volcanic Rocks ◽  
Labrador Sea ◽  
Baffin Island ◽  
Nd Isotope ◽  
Sea Floor ◽  
West Greenland ◽  
Depleted Mantle ◽  
Davis Strait ◽  
Isotope Systematics ◽  
Seawater Exchange

Fine- to medium-grained, phyric and aphyric basalt samples from ODP Leg 105, site 647A, in the Labrador Sea show little evidence of alteration. Chemically, these rocks are low-potassium (0.01–0.09 wt.% K2O), olivine- to quartz-normative tholeiites that compare closely with the very depleted terrestrial Paleocene volcanic rocks in the Davis Strait region of Baffin Island and West Greenland. However, differences exist in the Sr–Nd isotope systematics of the two suites; the Labrador Sea samples have ε Nd values (+9.3) indicative of a more depleted source, and are higher in 87Sr/86Sr (0.7040), relative to the Davis Strait basalts (ε Nd +2.54 to +8.97; mean 87Sr/86Sr 0.7034). The higher 87Sr/86Sr in the Labrador Sea samples may reflect seawater exchange despite no petrographic evidence for significant alteration. The Labrador Sea and early Davis Strait basalts may have been derived from a similar depleted mantle source composition; however, the later Davis Strait magmas were generated from a different mantle. None of the Baffin Island, West Greenland, or Labrador Sea samples show unequivocal geochemical evidence for contamination with continental crust.

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