scholarly journals Synthesis of Boron Nitride Nanotubes Using Plasma-Assisted CVD Catalyzed by Cu Nanoparticles and Oxygen

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 651
Author(s):  
Tatsuya Shiratori ◽  
Ichiro Yamane ◽  
Shoto Nodo ◽  
Ryo Ota ◽  
Takashi Yanase ◽  
...  

We found that oxidized Cu nanoparticles can catalyze the growth of boron nitride nanotubes from borazine via plasma-assisted chemical vapor deposition. The Raman spectra suggest that the formation of thin-walled nanotubes show a radial breathing mode vibration. The presence of oxygen in the plasma environment was necessary for the growth of the nanotubes, and a part of the nanotubes had a core shell structure with a cupper species inside it. In atomic resolution transmission electron microscope (TEM) images, Cu2O was found at the interface between the Cu-core and turbostratic BN-shell. The growth mechanism seemed different from that of carbon nanotube core-shell structures. Therefore, we pointed out the important role of the dynamic morphological change in the Cu2O-Cu system.

2014 ◽  
Vol 50 (33) ◽  
pp. 4371-4374 ◽  
Author(s):  
Xia Li ◽  
Nobutaka Hanagata ◽  
Xuebin Wang ◽  
Maho Yamaguchi ◽  
Wei Yi ◽  
...  

Boron nitride nanotubes@NaGdF4:Eu composites with core@shell structures were fabricated to trace and manipulate BNNTsin vitro.


2006 ◽  
Vol 21 (11) ◽  
pp. 2794-2800 ◽  
Author(s):  
Chunyi Zhi ◽  
Yoshio Bando ◽  
Chengchun Tang ◽  
Susumu Honda ◽  
Hiroaki Kuwahara ◽  
...  

Boron nitride nanotube (BNNT)/polystyrene (PS) composite films were fabricated for the first time using high-quality BNNTs synthesized via a chemical-vapor-deposition method. The composite films exhibited good transparency. Tensile tests indicated that the elastic modulus of the films was increased by ∼21% when a ∼1 wt% soluble BNNT fraction was in use. Dispersion of BNNTs in PS and interfacial interactions between them were investigated using transmission electron microscopy. The film thermal properties, such as stability to oxidation and glass transition temperatures were measured. The experimental results and simple theoretical estimates indicate that BNNTs is a promising additive material for polymeric composites.


2017 ◽  
Vol 16 (02) ◽  
pp. 1650029
Author(s):  
R. Sepahvand ◽  
S. Alihosseini ◽  
M. Adeli ◽  
P. Sasanpour

Hybrid nanomaterials consisting of functionalized fullerene and gold nanoparticle (NP) have been synthesized. Fullerene was functionalized by citric acid and used as reducing and capping agent for preparation of gold NPs. Functionalization of fullerene by use of citric acid was performed by enzymatic and thermal approaches. The core-shell structures containing gold NPs as core and fullerene as shell (gold/fullerene) were prepared. It was found that method and density of functionalization of fullerene effect final structure and therefore their physicochemical property of hybrid nanomaterial dramatically. Ultraviolet-visible (UV-Vis) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, dynamic light scattering (DLS), atomic force microscopy (AFM), transmission electron microscopy (TEM) were used to analyze the structure of the synthesized hybrid nanomaterial and also study their self-assembly and physicochemical properties. Effect of the size, structure and morphology (e.g., agglomeration) of the synthesized hybrid nanomaterial on their UV-Vis absorption behavior has been also verified by theoretical modeling.


2020 ◽  
Vol 2 (11) ◽  
pp. 4996-5014
Author(s):  
Ruth Sang Jones ◽  
Barbara Maciejewska ◽  
Nicole Grobert

This review explores the rapidly emerging field of hetero-nanotubes consisting of a carbon core and hexagonal boron nitride shell.


2007 ◽  
Vol 7 (2) ◽  
pp. 530-534 ◽  
Author(s):  
Chunyi Zhi ◽  
Yoshio Bando ◽  
Guozhen Shen ◽  
Chengchun Tang ◽  
Dmitri Golberg

Adopting a wet chemistry method, Au and Fe3O4 nanoparticles were functionalized on boron nitride nanotubes (BNNTs) successfully for the first time. X-ray diffraction pattern and transmission electron microscopy were used to characterize the resultant products. Subsequently, a method was proposed to fabricate heterojunction structures based on the particle-functionalized BNNTs. As a demonstration, BNNT-carbon nanostructure, BNNT-ZnO and BNNT-Ga2O3 junctions were successfully fabricated using the functionalized particles as catalysts.


2019 ◽  
Vol 7 (5) ◽  
pp. 1280-1291 ◽  
Author(s):  
Alaka Panda ◽  
R. Govindaraj ◽  
R. Mythili ◽  
G. Amarendra

Bismuth and iron oxides subjected to ball milling followed by controlled annealing treatments showed the formation of core–shell nanostructures with Bi2Fe4O9 as the core and a shell of BiFeO3 and Bi25FeO40 phases as deduced based on the analysis of transmission electron microscopy results.


CrystEngComm ◽  
2019 ◽  
Vol 21 (29) ◽  
pp. 4373-4386 ◽  
Author(s):  
Christian Thieme ◽  
Michael Kracker ◽  
Katrin Thieme ◽  
Christian Patzig ◽  
Thomas Höche ◽  
...  

The role of silver as a nucleating agent in BaO/SrO/ZnO/SiO2 glasses is studied with a range of microstructure-characterization techniques, such as scanning transmission electron microscopy, ultraviolet-visible spectroscopy, and X-ray diffraction.


2015 ◽  
Vol 118 (23) ◽  
pp. 234307 ◽  
Author(s):  
Aurélie Pierret ◽  
Hanond Nong ◽  
Frédéric Fossard ◽  
Brigitte Attal-Trétout ◽  
Yanming Xue ◽  
...  

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