scholarly journals 1.8 V Aqueous Symmetric Carbon-Based Supercapacitors with Agarose-Bound Activated Carbons in an Acidic Electrolyte

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1731
Author(s):  
Chih-Chung Lai ◽  
Feng-Hao Hsu ◽  
Su-Yang Hsu ◽  
Ming-Jay Deng ◽  
Kueih-Tzu Lu ◽  
...  

The specific energy of an aqueous carbon supercapacitor is generally small, resulting mainly from a narrow potential window of aqueous electrolytes. Here, we introduced agarose, an ecologically compatible polymer, as a novel binder to fabricate an activated carbon supercapacitor, enabling a wider potential window attributed to a high overpotential of the hydrogen-evolution reaction (HER) of agarose-bound activated carbons in sulfuric acid. Assembled symmetric aqueous cells can be galvanostatically cycled up to 1.8 V, attaining an enhanced energy density of 13.5 W h/kg (9.5 µW h/cm2) at 450 W/kg (315 µW/cm2). Furthermore, a great cycling behavior was obtained, with a 94.2% retention of capacitance after 10,000 cycles at 2 A/g. This work might guide the design of an alternative material for high-energy aqueous supercapacitors.

2017 ◽  
Vol 5 (28) ◽  
pp. 14619-14629 ◽  
Author(s):  
Noel Díez ◽  
Roman Mysyk ◽  
Wei Zhang ◽  
Eider Goikolea ◽  
Daniel Carriazo

One-pot synthesized superactivated carbons are used as electrodes for supercapacitors showing high gravimetric energy density in different aqueous electrolytes.


RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54662-54667 ◽  
Author(s):  
Chao Peng ◽  
Junwei Lang ◽  
Shan Xu ◽  
Xiaolai Wang

Pomelo peel as biomass-derived porous activated carbon is used for the preparation of a high energy density symmetric supercapacitor.


Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 122
Author(s):  
Renwei Lu ◽  
Xiaolong Ren ◽  
Chong Wang ◽  
Changzhen Zhan ◽  
Ding Nan ◽  
...  

Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density.


2012 ◽  
Vol 1 (3) ◽  
pp. 75 ◽  
Author(s):  
W.D.P Rengga ◽  
M. Sudibandriyo ◽  
M Nasikin

Gas storage is a technology developed with an adsorptive storage method, in which gases are stored as adsorbed components on the certain adsorbent. Formaldehyde is one of the major indoor gaseous pollutants. Depending on its concentration, formaldehyde may cause minor disorder symptoms to a serious injury. Some of the successful applications of technology for the removal of formaldehyde have been reported. However, this paper presents an overview of several studies on the elimination of formaldehyde that has been done by adsorption method because of its simplicity. The adsorption method does not require high energy and the adsorbent used can be obtained from inexpensive materials. Most researchers used activated carbon as an adsorbent for removal of formaldehyde because of its high adsorption capacity. Activated carbons can be produced from many materials such as coals, woods, or agricultural waste. Some of them were prepared by specific activation methods to improve the surface area. Some researchers also used modified activated carbon by adding specific additive to improve its performance in attracting formaldehyde molecules. Proposed modification methods on activation and additive impregnated carbon are thus discussed in this paper for future development and improvement of formaldehyde adsorption on activated carbon. Specifically, a waste agricultural product is chosen for activated carbon raw material because it is renewable and gives an added value to the materials. The study indicates that the performance of the adsorption of formaldehyde might be improved by using modified activated carbon. Bamboo seems to be the most appropriate raw materials to produce activated carbon combined with applying chemical activation method and addition of metal oxidative catalysts such as Cu or Ag in nano size particles. Bamboo activated carbon can be developed in addition to the capture of formaldehyde as well as the storage of adsorptive hydrogen gas that supports renewable energy. Keywords: adsorption; bamboo; formaldehyde; modified activated carbon; nano size particles


2020 ◽  
Vol 362 ◽  
pp. 137152
Author(s):  
Obinna Egwu Eleri ◽  
Kingsley Ugochukwu Azuatalam ◽  
Mona Wetrhus Minde ◽  
Ana Maria Trindade ◽  
Navaneethan Muthuswamy ◽  
...  

2018 ◽  
Vol 10 (28) ◽  
pp. 23748-23756 ◽  
Author(s):  
Yao Kang ◽  
Fengmei Su ◽  
Qingkai Zhang ◽  
Feng Liang ◽  
Keegan R. Adair ◽  
...  

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