scholarly journals Recent Development in Vanadium Pentoxide and Carbon Hybrid Active Materials for Energy Storage Devices

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3213
Author(s):  
Andrew Kim ◽  
Golap Kalita ◽  
Jong Hak Kim ◽  
Rajkumar Patel

With the increasing energy demand for portable electronics, electric vehicles, and green energy storage solutions, the development of high-performance supercapacitors has been at the forefront of energy storage and conversion research. In the past decade, many scientific publications have been dedicated to designing hybrid electrode materials composed of vanadium pentoxide (V2O5) and carbon nanomaterials to bridge the gap in energy and power of traditional batteries and capacitors. V2O5 is a promising electrode material owing to its natural abundance, nontoxicity, and high capacitive potential. However, bulk V2O5 is limited by poor conductivity, low porosity, and dissolution during charge/discharge cycles. To overcome the limitations of V2O5, many researchers have incorporated common carbon nanostructures such as reduced graphene oxides, carbon nanotubes, carbon nanofibers, and other carbon moieties into V2O5. The carbon components facilitate electron mobility and act as porous templates for V2O5 nucleation with an enhanced surface area as well as interconnected surface morphology and structural stability. This review discusses the development of various V2O5/carbon hybrid materials, focusing on the effects of different synthesis methods, V2O5/carbon compositions, and physical treatment strategies on the structure and electrochemical performance of the composite material as promising supercapacitor electrodes.

2016 ◽  
Vol 18 (46) ◽  
pp. 31361-31377 ◽  
Author(s):  
Guanhui Yang ◽  
Yu Zhang ◽  
Yanshan Huang ◽  
Muhammad Imran Shakir ◽  
Yuxi Xu

This review provided an overview of recent progress on composites of conjugated carbonyl compounds and carbon nanomaterials for energy storage.


2018 ◽  
Vol 386 ◽  
pp. 359-364
Author(s):  
Yury M. Nikolenko ◽  
Denis P. Opra ◽  
Alexander K. Tsvetnikov ◽  
Alexander Yu. Ustinov ◽  
Valery G. Kuryavyi ◽  
...  

The hydrolytic lignin derivatives have been prepared via its physical activation (high-temperature heating in vacuum) followed by chemical modification (fluorination). The obtained products were characterized using scanning electron microscopy, X-ray diffraction, transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy. It was found that the graphitized product of thermal activation up to 1000 °C at a low rate of < 2 °C/min under high vacuum shows an enhanced specific surface area (215 m2/g), that makes its potentially useful as sorbent, catalytic substrate or electrode material. To clarify the potentialities of hydrolytic lignin derivatives for energy storage and conversion, the electrochemical system with metallic lithium anode was applied. The galvanostatic discharge of battery at a current density of 100 μA/cm2between 3.0 and 0.5 V shows that the specific capacity of thermally activated derivative is equal to 845 mA·h/g, while the untreated lignin yields only 190 mA·h/g. The improve of the electrochemical performance of product originates from its graphitization, increasing electronic conductivity, and, possibly, enhanced ability to adsorb of oxygen. The fluorination of both the lignin and its thermally activated form results in higher operating voltage of battery, as seems, due to the involvement of fluorine bound to carbon in electrochemical process.


RSC Advances ◽  
2020 ◽  
Vol 10 (55) ◽  
pp. 33428-33435
Author(s):  
Xiaoyun Liu ◽  
Qian Li ◽  
Xin Zhang ◽  
Yueqiu Jiang

Rational design of electrode materials plays a significant role in potential applications such as energy storage and conversion.


MRS Advances ◽  
2017 ◽  
Vol 2 (54) ◽  
pp. 3283-3289
Author(s):  
Youning Gong ◽  
Qiang Fu ◽  
Chunxu Pan

ABSTRACTSupercapacitor is a newly-developed device for electrochemical energy storage with high power density, long life span, as well as rapid capture and storage of energy. Carbon-based materials, from carbon nanospheres, nanotubes and nanofibers to graphene, are the most commonly used electrode materials for supercapacitors. Our group has engaged in the research of carbon nanomaterials over the past decade. Herein we summarize some typical carbon nanomaterials and their synthetic routes based on our published works, which is expected to provide the theoretical and experimental basis for further applications on carbon-based energy storage devices.


Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1585 ◽  
Author(s):  
Jianhui Zhu ◽  
Amr Abdelkader ◽  
Denisa Demko ◽  
Libo Deng ◽  
Peixin Zhang ◽  
...  

Room temperature sodium-sulfur batteries have been considered to be potential candidates for future energy storage devices because of their low cost, abundance, and high performance. The sluggish sulfur reaction and the “shuttle effect” are among the main problems that hinder the commercial utilization of room temperature sodium-sulfur batteries. In this study, the performance of a hybrid that was based on nitrogen (N)-doped carbon nanospheres loaded with a meagre amount of Fe ions (0.14 at.%) was investigated in the sodium-sulfur battery. The Fe ions accelerated the conversion of polysulfides and provided a stronger interaction with soluble polysulfides. The Fe-carbon nanospheres hybrid delivered a reversible capacity of 359 mAh·g−1 at a current density of 0.1 A·g−1 and retained a capacity of 180 mAh·g−1 at 1 A·g−1, after 200 cycles. These results, combined with the excellent rate performance, suggest that Fe ions, even at low loading, are able to improve the electrocatalytic effect of carbon nanostructures significantly. In addition to Na-S batteries, the new hybrid is anticipated to be a strong candidate for other energy storage and conversion applications such as other metal-sulfur batteries and metal-air batteries.


2019 ◽  
Vol 11 (1) ◽  
Author(s):  
Hanmei Jiang ◽  
Zegao Wang ◽  
Qian Yang ◽  
Luxi Tan ◽  
Lichun Dong ◽  
...  

Abstract Metal selenides, such as NiSe2, have exhibited great potentials as multifunctional materials for energy storage and conversation. However, the utilization of pure NiSe2 as electrode materials is limited by its poor cycling stability, low electrical conductivity, and insufficient electrochemically active sites. To remedy these defects, herein, a novel NiSe2/Ti3C2Tx hybrid with strong interfacial interaction and electrical properties is fabricated, by wrapping NiSe2 octahedral crystal with ultrathin Ti3C2Tx MXene nanosheet. The NiSe2/Ti3C2Tx hybrid exhibits excellent electrochemical performance, with a high specific capacitance of 531.2 F g−1 at 1 A g−1 for supercapacitor, low overpotential of 200 mV at 10 mA g−1, and small Tafel slope of 37.7 mV dec−1 for hydrogen evolution reaction (HER). Furthermore, greater cycling stabilities for NiSe2/Ti3C2Tx hybrid in both supercapacitor and HER have also been achieved. These significant improvements compared with unmodified NiSe2 should be owing to the strong interfacial interaction between NiSe2 octahedral crystal and Ti3C2Tx MXene, which provides enhanced conductivity, fast charge transfer as well as abundant active sites, and highlight the promising potentials in combinations of MXene with metal selenides for multifunctional applications such as energy storage and conversion.


2017 ◽  
Vol 735 ◽  
pp. 189-193
Author(s):  
Priscila Tamiasso-Martinhon ◽  
Sousa Célia

Energy storage and conversion are major problems of our modern society. In the last decades, in order to minimize these problems, a growing research activity was dedicated to the development of new systems involved in this energy field. The fabrication of supercapacitors based on new materials, such as electrochemical double layer capacitor, can offer attractive potentialities. Indeed, these supercapacitors are able to provide a power density ten times higher than that supplied by batteries, and allow a larger number of charge and discharge cycles. The performance of supercapacitors highly depends on the properties of electrode materials. Ternary composites combining both capacitive and faradaic reactions can address the improvement necessary for relatively cost effective and performance of supercapacitors. Particularly, ternary nanocomposites systems of carbon nanotubes (CNTs), conducting polymer (CPs) films and metal oxide/hydroxide; CNT:CP:Metal oxide; has been proposed as potential electrodes for electrochemical supercapacitors, as alternatives to overcome the drawbacks associated with single component electrodes for the construction of high performance supercapacitors.


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