scholarly journals Reuse of Textile Waste to Production of the Fibrous Antibacterial Membrane with Filtration Potential

Nanomaterials ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 50
Author(s):  
Alena Opálková Šišková ◽  
Pavel Pleva ◽  
Jakub Hrůza ◽  
Jaroslava Frajová ◽  
Jana Sedlaříková ◽  
...  

Wasted synthetic fabrics are a type of textile waste source; the reuse of them brings environmental protection and turns waste into a valuable material. In this work, the used nylon (polyamide) stockings were transmuted into a fine fibrous membrane via an electrospinning process. In addition, the safety antibacterial agent, monoacylglycerol (MAG), was incorporated into a recycled fibrous membrane. The results revealed that the neat, recycled polyamide (rPA) fibers with a hydrophobic surface could be converted into hydrophilic fibers by blending various amounts of MAG with rPA solution prior to electrospinning. The filtration efficiency and air/water vapor permeability of the two types of produced membranes, neat rPA, and rPA/MAG, were tested. Their filtration efficiency (E100) was more than 92% and 96%, respectively. The membranes were classified according to Standard EN1822, and therefore, the membranes rPA and rPA/MAG were assigned to the classes E10 and E11, respectively. The air permeability was not affected by the addition of MAG, and water vapor permeability was slightly enhanced. Based on the obtained data, prepared rPA/MAG fibrous membranes can be evaluated as antifouling against both tested bacterial strains and antimicrobial against S. aureus.

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Jinshu Liu ◽  
Xiaoyan Ma ◽  
Wenzhao Shi ◽  
Jianwei Xing ◽  
Chaoqun Ma ◽  
...  

Abstract Baicalin, an active flavonoid ingredient of Scutellaria baicalensis Georgi, was extracted by heat reflux extraction and showed the same significance UV absorption property with standard baicalin. Active films were prepared from polyvinyl alcohol (PVA) containing baicalin extract by casting method. The effect of baicalin extracts on the UV-blocking, optical, antioxidant property, water vapor permeability, swelling and mechanical properties of the films were studied. UV–vis transmittance spectra showed that PVA films incorporated with baicalin extract blocked ultraviolet light range from 280–400 nm even with low concentration of baicalin (0.5 wt%) and maintain the high transparency in visible spectrum. The outstanding UV-blocking properties of PVA films incorporated with baicalin extract were also confirmed by Rhodamine B degradation. Baicalin conferred antioxidant properties to PVA films as determined by DPPH radical scavenging activity. Due to the interaction between hydroxy groups of baicalin and PVA molecule, water vapor permeability, swelling and elongation at break of the films were decreased accompanied with the increasing in tensile strength and Young’s modulus. FTIR reveal that the interaction between PVA molecules was significant changed by the introduction of baicalin. These results suggest that PVA film incorporated with baicalin extract can be used for the development of functional protective film.


Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 602
Author(s):  
Carmen Rodica Pop ◽  
Teodora Emilia Coldea ◽  
Liana Claudia Salanţă ◽  
Alina Lăcrămioara Nistor ◽  
Andrei Borşa ◽  
...  

Kefiran is an exopolysaccharide classified as a heteropolysaccharide comprising glucose and galactose in equimolar quantities, and it is classified as a water-soluble glucogalactan. This work aimed to investigate the effect of different extraction conditions of kefiran on the structural and physical properties of the edible films obtained. Fourier-transform infrared spectroscopy and scanning electron microscopy were performed, together with a determinations of moisture content, solubility, water vapor permeability and degree of swelling. The kefiran films presented values of the water vapor permeability between 0.93 and 4.38 × 10−11 g/m.s.Pa. These results can be attributed to the development of a more compact structure, where glycerol had no power to increase the free volume and the water vapor diffusion through their structure. The possible conformational changes in the kefiran film structure, due to the interspersing of the plasticizers and water molecules that they absorb, could be the reason for producing flexible kefiran films in the case of using glycerol as a plasticizer at 7.5% w/w. Moreover, it was observed that the extraction conditions are a significant factor in the properties of these films and their food technology applications.


Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3090
Author(s):  
Anita Ptiček Siročić ◽  
Ana Rešček ◽  
Zvonimir Katančić ◽  
Zlata Hrnjak-Murgić

The studied samples were prepared from polyethylene (PE) polymer which was coated with modified polycaprolactone (PCL) film in order to obtain bilayer films. Thin PCL film was modified with casein/aluminum oxide compound to enhance vapor permeability as well as mechanical and thermal properties of PE/PCL films. Casein/aluminum oxide modifiers were used in order to achieve some functional properties of polymer film that can be used in various applications, e.g., reduction of water vapor permeability (WVTR) and good mechanical and thermal properties. Significant improvement was observed in mechanical properties, especially in tensile strength as well as in water vapor values. Samples prepared with aluminum oxide particles indicated significantly lower values up to 60%, and samples that were prepared with casein and 5% Al2O3 showed the lowest WVTR value.


Author(s):  
Grégoire David ◽  
Laurent Heux ◽  
Stéphanie Pradeau ◽  
Nathalie Gontard ◽  
Hélène Angellier-Coussy

Abstract This paper aims at investigating the potential of vine shoots (ViSh) upcycling as fillers in novel poly(3-hydroxybutyrate-3-hydroxyvalerate) (PHBV) based biocomposites. ViSh particles of around 50 µm (apparent median diameter) were obtained combining dry grinding processes, and mixed with PHBV using melt extrusion. Thermal stability and elongation at break of biocomposites were reduced with increasing contents of ViSh particles (10, 20 and 30 wt%), while Young’s modulus and water vapor permeability were increased. It was shown that a surface gas-phase esterification allowed to significantly increase the hydrophobicity of ViSh particles (increase of water contact angles from 59° to 114°), leading to a reduction of 27% in the water vapor permeability of the biocomposite filled with 30 wt% of ViSh. The overall mechanical performance was not impacted by gas-phase esterification, demonstrating that the interfacial adhesion between the virgin ViSh particles and the PHBV matrix was already good and that such filler surface treatment was not required in that case. It was concluded that ViSh particles can be interestingly used as low cost fillers in PHBV-based biocomposites to decrease the overall cost of materials.


2009 ◽  
Vol 4 (3) ◽  
pp. 442-449 ◽  
Author(s):  
Yuhua Zhang ◽  
Masatoshi Ishida ◽  
Yutaka Kazoe ◽  
Yohei Sato ◽  
Norihisa Miki

2018 ◽  
Vol 105 ◽  
pp. 637-644 ◽  
Author(s):  
M.K.S. Monteiro ◽  
V.R.L. Oliveira ◽  
F.K.G. Santos ◽  
E.L. Barros Neto ◽  
R.H.L. Leite ◽  
...  

Author(s):  
Nan Chen ◽  
Yanchun Li ◽  
Jianbo Qu ◽  
Jian-Yong Wang

The traditional thick coating on split leather does not have the ability to breathe like full grain leather.  The air and water vapor permeabilities of full grain leather are well known properties due to its fiber woven structure. Simulating the fiber morphology and weaving structure of the dermis or grain layer is very important to construct a top surface layer for split leather. In this paper, a PU (polyurethane) foam layer is put first on the split to enhance the adhesion of a second application of a superfine fibrous PU resin. This foam uses well-known waterborne polyurethane foaming technology. This dried foam has good breathability because of high porosity. A superfine fiber membrane is next put atop of the foam layer by using an electro-spun polyurethane resin. This second resin imitates collagen fibers in the network structure of the leathers’ grain layer. Thus, this resultant electrospun fiber biomimetics membrane simulated the grain layer of natural leather. SEM showed the morphology and structure of this electrospun fiber biomimetic membrane to be like that of the grain layer of natural leather. The porosity and apparent density were basically the same as the grain of leather, which were 63.65% and 583.878 kg/m3 respectively. The air and water vapor permeability of the biomimetics membrane were also as high as 2250 mL·cm-2·h-1 and 8753.02 μg·cm-2·h-1 respectively. Therefore, the biomimetics membrane largely restored the ability to breathe of split leather. Thus, this method simulates the performance and structure of full grain leather and is a novel method for industrial production


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