scholarly journals Near Unity PLQY and High Stability of Barium Thiocyanate Based All-Inorganic Perovskites and Their Applications in White Light-Emitting Diodes

Photonics ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 209
Author(s):  
Gopi Chandra Adhikari ◽  
Saroj Thapa ◽  
Yang Yue ◽  
Hongyang Zhu ◽  
Peifen Zhu
Keyword(s):  
White Light ◽  
Large Scale ◽  
Light Emitting Diode ◽  
Photophysical Properties ◽  
Environmental Stability ◽  
Color Temperature ◽  
Ambient Atmosphere ◽  
Light Emitting ◽  
Halide Perovskite ◽  
Lead Halide

All-inorganic lead halide perovskite (CsPbX3) nanocrystals (NCs) have emerged as a highly promising new generation of light emitters due to their extraordinary photophysical properties. However, the performance of these semiconducting NCs is undermined due to the inherent toxicity of lead and long-term environmental stability. Here, we report the addition of B-site cation and X-site anion (pseudo-halide) concurrently using Ba(SCN)2 (≤50%) in CsPbX3 NCs to reduce the lead and improve the photophysical properties and stability. The as-grown particles demonstrated an analogous structure with an almost identical lattice constant and a fluctuation of particle size without altering the morphology of particles. Photoluminescence quantum yield is enhanced up to near unity (~98%) by taking advantage of concomitant doping at the B- and X-site of the structure. Benefitted from the defect reductions and stronger bonding interaction between Pb2+ and SCN− ions, Ba(SCN)2-based NCs exhibit improved stability towards air and moisture compared to the host NCs. The doped NCs retain higher PLQY (as high as seven times) compared to the host NCs) when stored in an ambient atmosphere for more than 176 days. A novel 3D-printed multiplex color conversion layer was used to fabricate a white light-emitting diode (LED). The obtained white light shows a correlated color temperature of 6764 K, a color rendering index of 87, and luminous efficacy of radiation of 333 lm/W. In summary, this work proposes a facile route to treat sensitive lead halide perovskite NCs and to fabricate LEDs by using a low-cost large-scale 3-D printing method, which would serve as a foundation for fabricating high-quality optoelectronic devices for near future lighting technologies.

scholarly journals Controllable Synthesis of All Inorganic Lead Halide Perovskite Nanocrystals with Various Appearances in Multiligand Reaction System

Nanomaterials ◽  
2019 ◽  
Vol 9 (12) ◽  
pp. 1751 ◽  
Author(s):  
Chen Chen ◽  
Louwen Zhang ◽  
Tielin Shi ◽  
Guanglan Liao ◽  
Zirong Tang
Keyword(s):  
Light Emitting Diode ◽  
Dominant Role ◽  
Photophysical Properties ◽  
Reaction System ◽  
Visible Spectrum ◽  
Peanut Oil ◽  
Light Emitting ◽  
Perovskite Nanocrystals ◽  
Halide Perovskite ◽  
Lead Halide

All inorganic cesium lead halide (CsPbX3, X = Cl, Br, I) perovskite nanocrystals (PNCs) exhibit promising applications in light-emitting devices due to their excellent photophysical properties. Herein, we developed a low-cost and convenient method for the preparation of CsPbX3 PNCs in a multiligand-assisted reaction system where peanut oil is applied as a ligand source. The mixed-halide PNCs with tunable optical-band gap were prepared by mixing the single-halide perovskite solutions at room temperature. The resulting PNCs had good monodispersity, with dimensions of 8–10 nm, high photoluminescence quantum yield (96.9%), narrow emission widths (15–34 nm), and tunable emission wavelength (408–694 nm), covering the entire visible spectrum. Additionally, various morphologies of PNCs, such as nanospheres, nanocubes, and nanowires, were obtained by controlling reaction temperature and time, and the amount of oleamine with multiple ligands in peanut oil potentially playing a dominant role in the nucleation/growth processes of our PNCs. Finally, the resulting CsPbBr3 PNCs were employed to develop a white light-emitting diode (WLED), demonstrating the potential lighting applications for our method.

Effects of electron-withdrawing groups in imidazole-phenanthroline ligands and their influence on the photophysical properties of EuIII complexes for white light-emitting diodes

2017 ◽  
Vol 41 (18) ◽  
pp. 9826-9839 ◽  
Author(s):  
Boddula Rajamouli ◽  
Rachna Devi ◽  
Abhijeet Mohanty ◽  
Venkata Krishnan ◽  
Sivakumar Vaidyanathan
Keyword(s):  
Thin Film ◽  
Quantum Yield ◽  
White Light ◽  
Light Emitting Diode ◽  
Photophysical Properties ◽  
Red Light ◽  
Europium Complexes ◽  
Light Emitting ◽  
White Light Emitting Diodes ◽  
Phenanthroline Ligands

The red light emitting diode (LED) was fabricated by using europium complexes with InGaN LED (395 nm) and shown digital images, corresponding CIE color coordinates (red region) as well as obtained highest quantum yield of the thin film (78.7%).

Bluish-white-light-emitting diodes based on two-dimensional lead halide perovskite (C6H5C2H4NH3)2PbCl2Br2

2018 ◽  
Vol 112 (15) ◽  
pp. 153901 ◽  
Author(s):  
Peiqing Cai ◽  
Xiangfu Wang ◽  
Hyo Jin Seo ◽  
Xiaohong Yan
Keyword(s):  
White Light ◽  
Light Emitting Diodes ◽  
Two Dimensional ◽  
Light Emitting ◽  
Halide Perovskite ◽  
White Light Emitting Diodes ◽  
Lead Halide

scholarly journals Chromaticity Study of Curcumin Dye Extracted from Curcuma longa L. Using for UV Light down Conversion for White Light Emitting Diode

2019 ◽  
Vol 290 ◽  
pp. 183-189
Author(s):  
Mahmood Al Shafouri ◽  
Naser Mahmoud Ahmed ◽  
Zainuriah Hassan ◽  
Munirah Abdullah Almessiere
Keyword(s):  
White Light ◽  
Uv Light ◽  
Light Emitting Diode ◽  
Curcuma Longa ◽  
Color Temperature ◽  
Light Emitting ◽  
Chromaticity Coordinates ◽  
Major Factors ◽  
Color Rendering ◽  
Down Conversion

In thus study, Turmeric phosphor dye was extracted from Curcuma Longa L. via a simple technique using silica gel. The phosphor was used for light down-conversion of UV light for the manufacture white light emitting diode (WLED). The UV-LED was analyzed over 395nm wavelengths. The characteristics of the white light chromaticity were controlled by tuning the current and phosphor concentration. An optimum color rendering index (CRI) value of 63.4 was obtained. The chromaticity coordinates (CIE) and correlated color temperature (CCT) were measured for various currents and phosphor concentrations. The white phosphor exhibited CIE value of 0.355,0.338 and CCT of 4567 K. The concentration of phosphor and amount of applied current were confirmed to be major factors that control the intensity of white light emitted from the sample, where CIE and CRI of the emitted light steadily increased with the concentration of phosphor and current. Thus, phosphor concentration has a critical effect on conversion efficiency. Key words: Turmeric, phosphor, WLED, curcumin

Bright emission and high photoluminescence CsPb2Br5 NCs encapsulated in mesoporous silica with ultrahigh stability and excellent optical properties for white light-emitting diodes

2019 ◽  
Vol 7 (43) ◽  
pp. 13585-13593 ◽  
Author(s):  
Guangzhan Shao ◽  
Yi Zhao ◽  
Yanxia Yu ◽  
Haisheng Yang ◽  
Xiaodong Liu ◽  
...  
Keyword(s):  
Optical Properties ◽  
Mesoporous Silica ◽  
White Light ◽  
Light Emitting Diodes ◽  
Optoelectronic Properties ◽  
Light Emitting ◽  
Halide Perovskite ◽  
White Light Emitting Diodes ◽  
Lead Halide ◽  
Bright Emission

All-inorganic cesium lead halide perovskite CsPb2Br5 nanocrystals (NCs) have attracted tremendous attention owing to their unique optoelectronic properties.

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