scholarly journals The Effect of the Surface Area of Carbon Black Grades on HNBR in Harsh Environments

Polymers ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 61 ◽  
Author(s):  
Winoj Balasooriya ◽  
Bernd Schrittesser ◽  
Gerald Pinter ◽  
Thomas Schwarz ◽  
Lucia Conzatti

Concerning the still rising demand for oil and gas products, the development of new reliable materials to guarantee the facility safety at extreme operating conditions is an utmost necessity. The present study mainly deals with the influence of different carbon black (CB) filled hydrogenated nitrile butadiene rubber (HNBR), which is a material usually used in sealing applications, on the rapid gas decompression (RGD) resistance in harsh environments. Therefore, RGD component level tests were conducted in an autoclave. The supporting mechanical and dynamic mechanical property analysis, the microscopic level investigations on the material and failure analysis were conducted and are discussed in this work. Under the tested conditions, the samples filled with smaller CB primary particles showed a slightly lower volume increase during the compression and decompression phases; however, they steered to a significantly lower resistance to RGD. Transmission electron micrographs revealed that the samples filled with smaller CB particles formed larger structures as well as densified filler networks including larger agglomerates and as a consequence a decrease effective matrix component around the CB particles. Apparently, at higher loading conditions, which already deliver a certain level of mechanical stresses and strains, the densified filler network, and especially a lower amount of effective matrix material composition, adversely affect the RGD resistance. SEM-based fracture analysis did not identify any influence of the CB grades tested on the crack initiation site; however, it revealed that the cracks initiated from existing voids, hard particles, or low strength matrix sites and propagated to the outer surface.

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1085
Author(s):  
Patricia Castaño-Rivera ◽  
Isabel Calle-Holguín ◽  
Johanna Castaño ◽  
Gustavo Cabrera-Barjas ◽  
Karen Galvez-Garrido ◽  
...  

Organoclay nanoparticles (Cloisite® C10A, Cloisite® C15) and their combination with carbon black (N330) were studied as fillers in chloroprene/natural/butadiene rubber blends to prepare nanocomposites. The effect of filler type and load on the physical mechanical properties of nanocomposites was determined and correlated with its structure, compatibility and cure properties using Fourier Transformed Infrared (FT-IR), X-ray Diffraction (XRD), Thermogravimetric Analysis (TGA) and rheometric analysis. Physical mechanical properties were improved by organoclays at 5–7 phr. Nanocomposites with organoclays exhibited a remarkable increase up to 46% in abrasion resistance. The improvement in properties was attributed to good organoclay dispersion in the rubber matrix and to the compatibility between them and the chloroprene rubber. Carbon black at a 40 phr load was not the optimal concentration to interact with organoclays. The present study confirmed that organoclays can be a reinforcing filler for high performance applications in rubber nanocomposites.


Polymers ◽  
2021 ◽  
Vol 13 (4) ◽  
pp. 616
Author(s):  
Ján Kruželák ◽  
Andrea Kvasničáková ◽  
Klaudia Hložeková ◽  
Rastislav Dosoudil ◽  
Marek Gořalík ◽  
...  

In the present work, composite materials were prepared by incorporation of manganese-zinc ferrite, carbon black and combination of ferrite and carbon black into acrylonitrile-butadiene rubber (NBR). For cross-linking of composites, standard sulfur-based curing system was applied. The main goal was to investigate the influence of the fillers on the physical-mechanical properties of composites. Then, the electromagnetic absorption shielding ability was investigated in the frequency range 1 MHz–3 GHz. The results revealed that composites filled with ferrite provide sufficient absorption shielding performance in the tested frequency range. On the other hand, ferrite behaves as an inactive filler and deteriorates the physical-mechanical characteristics of composites. Carbon black reinforces the rubber matrix and contributes to the improvement of physical-mechanical properties. However, composites filled with carbon black are not able to absorb electromagnetic radiation in the given frequency range. Finally, the combination of carbon black and ferrite resulted in the modification of both physical-mechanical characteristics and absorption shielding ability of hybrid composites.


2020 ◽  
Vol 39 (1) ◽  
pp. 81-90
Author(s):  
An Zhao ◽  
Xuan-Yu Shi ◽  
Shi-Hao Sun ◽  
Hai-Mo Zhang ◽  
Min Zuo ◽  
...  

2002 ◽  
Vol 21 (5) ◽  
pp. 597-606 ◽  
Author(s):  
B. Jurkowski ◽  
Y.A. Olkhov ◽  
B. Jurkowska ◽  
H. Menge

Author(s):  
K. R. Mrinal ◽  
Md. Hamid Siddique ◽  
Abdus Samad

A progressive cavity pump (PCP) is a positive displacement pump and has been used as an artificial lift method in the oil and gas industry for pumping fluid with solid content and high viscosity. In a PCP, a single-lobe rotor rotates inside a double-lobe stator. Articles on computational works for flows through a PCP are limited because of transient behavior of flow, complex geometry and moving boundaries. In this paper, a 3D CFD model has been developed to predict the flow variables at different operating conditions. The flow is considered as incompressible, single phase, transient, and turbulent. The dynamic mesh model in Ansys-Fluent for the rotor mesh movement is used, and a user defined function (UDF) written in C language defines the rotor’s hypocycloid path. The mesh deformation is done with spring based smoothing and local remeshing technique. The computational results are compared with the experiment results available in the literature. Thepump gives maximum flowrate at zero differential pressure.


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