scholarly journals Review of Swift Heavy Ion Irradiation Effects in CeO2

2021 ◽  
Vol 5 (2) ◽  
pp. 19
Author(s):  
William F. Cureton ◽  
Cameron L. Tracy ◽  
Maik Lang
Keyword(s):  
Heavy Ions ◽  
Defect Formation ◽  
Ion Irradiation ◽  
Ion Beam ◽  
Impurity Content ◽  
Heavy Ion ◽  
Atomic Scale ◽  
Experimental Conditions ◽  
Swift Heavy Ions ◽  
Wide Range

Cerium dioxide (CeO2) exhibits complex behavior when irradiated with swift heavy ions. Modifications to this material originate from the production of atomic-scale defects, which accumulate and induce changes to the microstructure, chemistry, and material properties. As such, characterizing its radiation response requires a wide range of complementary characterization techniques to elucidate the defect formation and stability over multiple length scales, such as X-ray and neutron scattering, optical spectroscopy, and electron microscopy. In this article, recent experimental efforts are reviewed in order to holistically assess the current understanding and knowledge gaps regarding the underlying physical mechanisms that dictate the response of CeO2 and related materials to irradiation with swift heavy ions. The recent application of novel experimental techniques has provided additional insight into the structural and chemical behavior of irradiation-induced defects, from the local, atomic-scale arrangement to the long-range structure. However, future work must carefully account for the influence of experimental conditions, with respect to both sample properties (e.g., grain size and impurity content) and ion-beam parameters (e.g., ion mass and energy), to facilitate a more direct comparison of experimental results.

Structural defects induced by heavy-ion irradiation in superconducting oxides

1993 ◽  
Vol 51 ◽  
pp. 1138-1139
Author(s):  
Yimei Zhu ◽  
H. Zhang ◽  
Z.X. Cai ◽  
R.C. Budhani ◽  
D.O. Welch ◽  
...  
Keyword(s):  
Heavy Ions ◽  
Defect Formation ◽  
Ion Irradiation ◽  
Ion Beam ◽  
Amorphous Region ◽  
Heavy Ion ◽  
Microscopy Study ◽  
Dynamical Theory ◽  
Structural Defects ◽  
Hole Density

We studied the the structure and properties of high Tc superconductors using heavy ions. While irradiation of YBa2Cu3O7-δ (hereafter denoted as 123) with 300 MeV Au+24 and 276 MeV Ag+21 ions produces columns of amorphous tracks along the ion trajectories, such defects are only created occasionally during irradiation with 236 MeV Cu+18, and are not induced with 182 MeV Si+13. A comprehensive electron microscopy study of defect formation in Bi2Sr2Ca2Cu3Ox, and in oxygen-reduced and ozone-treated 123, shows that the degree of radiation damage (the size and the shape of the defect) by the heavy ions depends on: (a) the rate at which ions lose their energy in the target; (b) crystallographic orientations with respect to the incident ion-beam (Fig.1); (c) thermal conductivity and chemical state (eg. oxygen concentration of 123) of the sample, and (d) the extent of pre-existing defects in the crystal. Calculation and simulation of the strain contrast surrounding the amorphous column using two-beam dynamical theory agree well with the observations and suggest that the reduced hole density observed in the crystal near the amorphous region is mainly due to lattice distortion.

Effect of Cascade Remnants on Freely Migrating Defects in Cu -1 % Au Alloys

1995 ◽  
Vol 396 ◽  
Author(s):  
A. Iwase ◽  
L. E. Rehn ◽  
P. M. Baldo ◽  
L. Funk
Keyword(s):  
Heavy Ions ◽  
Ion Irradiation ◽  
Ion Beam ◽  
Heavy Ion ◽  
The Other ◽  
Inert Gas ◽  
Heavy Ion Irradiation ◽  
Simultaneous Irradiation ◽  
Radiation Induced ◽  
Cu Ions

AbstractThe effects of cascade remnants on Freely Migrating Defects (FMD) were studied by measuring Radiation-Induced Segregation (RIS) in Cu-l%Au at 400°C during simultaneous irradiation with 1.5-MeV He and (400-800)-keV heavy ions (Ne, Ar or Cu). The large RIS observed during 1.5-MeV He-only irradiation was dramatically suppressed under simultaneous heavy ion irradiation. For Cu simultaneous irradiation, the suppression disappeared immediately after the Cu irradiation ceased, while for simultaneous inert gas (Ne or Ar) irradiation, the suppression persisted after the ion beam was turned off. These results demonstrate that the displacement cascades created by heavy ions introduce additional annihilation sites, which reduce the steady-state FMD concentrations. As the cascade remnants produced by Cu ions are thermally unstable at 400°C, the RIS suppression occurs only during simultaneous irradiation. On the other hand, the inert gas atoms which accumulate in the specimen apparently stabilize the cascade remnants, allowing the suppression to persist.

Energy Loss for Swift Heavy Ions in Polymers: A New Approach for Effective Charge Parameterization

2013 ◽  
Vol 341 ◽  
pp. 129-141 ◽  
Author(s):  
Kalpana Sharma ◽  
Neetu ◽  
Anupam ◽  
Shyam Kumar
Keyword(s):  
Energy Loss ◽  
Effective Charge ◽  
Heavy Ions ◽  
Ion Irradiation ◽  
Heavy Ion ◽  
Polyethylene Naphthalate ◽  
New Approach ◽  
Swift Heavy Ions ◽  
Swift Heavy Ion ◽  
Induced Changes

t is well established that the properties of the materials can be tailored as per specific requirements as a result of swift heavy ion irradiation. This is because of the radiation damage induced changes in the properties of the materials as a result of the energy loss process of the incident ions along their trajectory. In order to correlate such induced changes with the energy loss of the impinging ions, the exact evaluation of energy loss for swift ions in different materials is extremely important. Keeping in mind the polymers as versatile materials, in the present work, we have focused on energy loss calculations for swift heavy ions with Z= 3-29 in different polymeric absorbers, e.g. Polypropylene PP (C3H6), Polycarbonate PC (C16H14O3), Polyethylene terepthalate PET (C10H8O4), Polyethylene naphthalate PEN (C7H5O2), Diethylene glycol bis (allyl carbonate) CR-39 (C12H18O7), Cellulose nitrate LR-115 (C6H9O9N2) and Polypyromellitimide KAPTON (C22H10O5N2) in the energy range 0.5-6.00 MeV/n. The present calculations have been made by employing the proper energy loss formulation applicable both at low as well as high energies, involving a new approach for effective charge parameterization without any empirical/semi-empirical means. A close agreement between these calculated and experimentally measured values has been observed. Such calculations will provide an input towards the modeling or simulation for swift heavy ion induced changes in the properties of materials.

Electron and ion irradiation-induced dissolution of mechanical twins in the intermetalic U3Si: An in situ HVEM study

1989 ◽  
Vol 47 ◽  
pp. 652-653
Author(s):  
Charles W. Allen ◽  
Robert C. Birtcher
Keyword(s):  
Elevated Temperatures ◽  
Ion Irradiation ◽  
Ion Beam ◽  
National Laboratory ◽  
Argonne National Laboratory ◽  
Heavy Ion ◽  
High Energy ◽  
Mechanical Twinning ◽  
In Situ Experiments

The uranium silicides, including U3Si, are under study as candidate low enrichment nuclear fuels. Ion beam simulations of the in-reactor behavior of such materials are performed because a similar damage structure can be produced in hours by energetic heavy ions which requires years in actual reactor tests. This contribution treats one aspect of the microstructural behavior of U3Si under high energy electron irradiation and low dose energetic heavy ion irradiation and is based on in situ experiments, performed at the HVEM-Tandem User Facility at Argonne National Laboratory. This Facility interfaces a 2 MV Tandem ion accelerator and a 0.6 MV ion implanter to a 1.2 MeV AEI high voltage electron microscope, which allows a wide variety of in situ ion beam experiments to be performed with simultaneous irradiation and electron microscopy or diffraction.At elevated temperatures, U3Si exhibits the ordered AuCu3 structure. On cooling below 1058 K, the intermetallic transforms, evidently martensitically, to a body-centered tetragonal structure (alternatively, the structure may be described as face-centered tetragonal, which would be fcc except for a 1 pet tetragonal distortion). Mechanical twinning accompanies the transformation; however, diferences between electron diffraction patterns from twinned and non-twinned martensite plates could not be distinguished.

scholarly journals Comparison of short-range order in irradiated dysprosium titanates

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Roman Sherrod ◽  
Eric C. O’Quinn ◽  
Igor M. Gussev ◽  
Cale Overstreet ◽  
Joerg Neuefeind ◽  
...  
Keyword(s):  
Long Range ◽  
Short Range ◽  
Structural Model ◽  
Ion Irradiation ◽  
Function Analysis ◽  
Ion Beam ◽  
Structural Response ◽  
Heavy Ion ◽  
Range Order ◽  
Radiation Resistant

AbstractThe structural response of Dy2TiO5 oxide under swift heavy ion irradiation (2.2 GeV Au ions) was studied over a range of structural length scales utilizing neutron total scattering experiments. Refinement of diffraction data confirms that the long-range orthorhombic structure is susceptible to ion beam-induced amorphization with limited crystalline fraction remaining after irradiation to 8 × 1012 ions/cm2. In contrast, the local atomic arrangement, examined through pair distribution function analysis, shows only subtle changes after irradiation and is still described best by the original orthorhombic structural model. A comparison to Dy2Ti2O7 pyrochlore oxide under the same irradiation conditions reveals a different behavior: while the dysprosium titanate pyrochlore is more radiation resistant over the long-range with smaller degree of amorphization as compared to Dy2TiO5, the former involves more local atomic rearrangements, best described by a pyrochlore-to-weberite-type transformation. These results highlight the importance of short-range and medium-range order analysis for a comprehensive description of radiation behavior.

Ion beam-mixing effects in nearly lattice-matched AlInN/GaN heterostructures by swift heavy ion irradiation

2012 ◽  
Vol 167 (7) ◽  
pp. 506-511 ◽  
Author(s):  
G. Devaraju ◽  
S. V.S. Nageswara Rao ◽  
N. Srinivasa Rao ◽  
V. Saikiran ◽  
T. K. Chan ◽  
...  
Keyword(s):  
Ion Irradiation ◽  
Ion Beam ◽  
Heavy Ion ◽  
Ion Beam Mixing ◽  
Swift Heavy Ion Irradiation ◽  
Heavy Ion Irradiation ◽  
Mixing Effects ◽  
Swift Heavy Ion ◽  
Lattice Matched

scholarly journals Dislocation Loop Generation Differences between Thin Films and Bulk in EFDA Pure Iron under Self-Ion Irradiation at 20 MeV

Metals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 2000
Author(s):  
Marcelo Roldán ◽  
Fernando José Sánchez ◽  
Pilar Fernández ◽  
Christophe J. Ortiz ◽  
Adrián Gómez-Herrero ◽  
...  
Keyword(s):  
Thin Films ◽  
Computational Models ◽  
Defect Formation ◽  
Ion Irradiation ◽  
Damage Zone ◽  
High Energy ◽  
Model Material ◽  
Dislocation Nucleation ◽  
Dislocation Loops ◽  
Experimental Conditions

In the present investigation, high-energy self-ion irradiation experiments (20 MeV Fe+4) were performed on two types of pure Fe samples to evaluate the formation of dislocation loops as a function of material volume. The choice of model material, namely EFDA pure Fe, was made to emulate experiments simulated with computational models that study defect evolution. The experimental conditions were an ion fluence of 4.25 and 8.5 × 1015 ions/cm2 and an irradiation temperature of 350 and 450 °C, respectively. First, the ions pass through the samples, which are thin films of less than 100 nm. With this procedure, the formation of the accumulated damage zone, which is the peak where the ions stop, and the injection of interstitials are prevented. As a result, the effect of two free surfaces on defect formation can be studied. In the second type of experiments, the same irradiations were performed on bulk samples to compare the creation of defects in the first 100 nm depth with the microstructure found in the whole thickness of the thin films. Apparent differences were found between the thin foil irradiation and the first 100 nm in bulk specimens in terms of dislocation loops, even with a similar primary knock-on atom (PKA) spectrum. In thin films, the most loops identified in all four experimental conditions were b ±a0<100>{200} type with sizes of hundreds of nm depending on the experimental conditions, similarly to bulk samples where practically no defects were detected. These important results would help validate computational simulations about the evolution of defects in alpha iron thin films irradiated with energetic ions at large doses, which would predict the dislocation nucleation and growth.

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