scholarly journals Studies of Indium Tin Oxide-Based Sensing Electrodes in Potentiometric Zirconia Solid Electrolyte Gas Sensors

Sensors ◽  
2021 ◽  
Vol 21 (7) ◽  
pp. 2345
Author(s):  
Stefan Dietrich ◽  
Mihails Kusnezoff ◽  
Alexander Michaelis

A zirconia-based potentiometric solid electrolyte gas sensor with internal solid state reference was used to study the response behavior of platinum cermet and indium tin oxide sensing electrodes. Target gases included both oxygen and carbon monoxide in nitrogen-based sample gas mixtures. It was found that with the indium tin oxide sensing electrode, the low-temperature behavior is mainly a result of incomplete equilibration due to contaminations of the electrode surface. On the other hand, some of these contaminant species have been identified as being pivotal for the higher carbon monoxide sensitivity of the indium tin oxide sensing electrode as compared to platinum cermet electrodes.

1990 ◽  
Vol 186 (2) ◽  
pp. 349-360 ◽  
Author(s):  
G. Sberveglieri ◽  
P. Benussi ◽  
G. Coccoli ◽  
S. Groppelli ◽  
P. Nelli

2021 ◽  
Author(s):  
Longfei Song ◽  
Tony Schenk ◽  
Emmanuel Defay ◽  
Sebastjan Glinsek

Highly conductive (conductivity 620 S cm−1) and transparent ITO thin films are achieved at low temperature (350 °C) through effective combustion solution processing via multistep coating. The properties show potential for next generation flexible and transparent electronics.


Author(s):  
Yong-Seok Lee ◽  
Su-Yeon Jung ◽  
Kwang-Sun Ryu

Abstract Li2(OH)0.9F0.1Cl, Li2(OH)0.9Br0.1Cl, and Li2OHCl0.8Br0.2 solid electrolytes were synthesized and compared with Li2OHCl to analyze the exact improvement mechanism for Li+ conductivity and electrochemical stability of Li2OHX-type solid electrolyte. The substituted materials exhibit improved electrochemical stability and Li+ conductivity Li2OHCl. Among these materials, Li(OH)0.9F0.1Cl has improved Li+ conductivity due to a reduction of the OH– concentration and the conductivity of Li2OHCl0.8Br0.2 was also increased compared with Li2OHCl due to the large interstitial site. In the case of Li2(OH)0.9Br0.1Cl, it had the highest Li+ conductivity and good Li+ migration by both effects because of a larger interstitial site and low OH− concentration. Furthermore, the electrochemical stability of four materials was compared due to the different structural stabilities and strengths of binary chemical bonds such as Li–X, H–X, and O–X. Comparing the Li+ conductivity of Li2(OH)0.9F0.1Cl and Li2OHCl0.8Br0.2, the Li+ conductivity is influenced by the OH− concentration unlike the other mechanisms.


2013 ◽  
Vol 13 (2) ◽  
pp. 1300-1303 ◽  
Author(s):  
Haibo Dong ◽  
Xiaoxian Zhang ◽  
Zhiqiang Niu ◽  
Duan Zhao ◽  
Jinzhu Li ◽  
...  

2009 ◽  
Vol 130 (11) ◽  
pp. 111101 ◽  
Author(s):  
Rajaram S. Mane ◽  
Wonjoo Lee ◽  
Sun-Ki Min ◽  
Soo-Hyoung Lee ◽  
Oh-Shim Joo ◽  
...  

2002 ◽  
Vol 20 (9) ◽  
pp. 897-905 ◽  
Author(s):  
Ireneusz Kocemba ◽  
Sławomir Szafran ◽  
Jacek Rynkowski ◽  
Tadeusz Paryjczak

Semiconductor gas sensors based on metal oxides have been widely accepted as an important tool for the detection of different gases in air. An understanding of all the mechanisms related to such detection is essential in order to improve the sensitivity and selectivity of these gas detectors. This paper considers the mechanism of detection by semiconductor oxide gas sensors in terms of catalytic reactions described by Rideal–Eley and Langmuir–Hinshelwood mechanisms. Some relationships were discussed between the catalytic and detection properties of SnO2 and Pt/SnO2 systems used on the one hand as catalysts of low-temperature CO oxidation and on the other hand as sensors of CO in air.


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